Battery electrode assembly and fabrication method therefor

• US 7,179,562 B2
• Filed: 07/29/2003
• Issued: 02/20/2007
• Est. Priority Date: 02/14/2003
• Status: Expired due to Fees

• Current Assignee: Quallion, LLC (EnerSys)
• Original Assignee: Quallion, LLC (EnerSys)
• Inventors: Zolotnik, Vladimir, Ulloa, Jose A., Pal, Alex Z., Wong, Joseph, Gusev, Vladimir
• Primary Examiner(s): Maples; John S.
• Application Number:
  US10/630,541
• Publication Number:
  US 20040161669A1
• Time in Patent Office: 1,302 Days
• Field of Search: None
• US Class Current: 429/211
• CPC Class Codes: H01M 50/534 characterised by the material of the leads or tabs
• CPC Class Codes: H01M 50/536 characterised by the method of fixing the leads to the electrodes, e.g. by welding
• CPC Class Codes: H01M 50/54 Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/49114 including adhesively bonding

Abstract

An electrode assembly and construction method therefor for use in small high performance batteries suitable for implantable medical device applications. The electrode assembly comprises a stack of precisely aligned planar elements including alternately arranged positive and negative planar electrodes having a planar separator interposed between adjacent electrodes. Each electrode is preferably formed of a thin metal substrate carrying active material on front and rear faces. The peripheral edge of each electrode defines an active area and a tab extending therefrom. The front and rear faces of the active area each carries a layer of active material. The faces of the tab area are preferably bare. The positive electrode tabs are located at a first position along the peripheral edge whereas the negative tabs are located at a second position spaced from said first position. Each tab carries a clip to form a reinforcing strip adjacent each tab face. Alignment holes are formed in the clips and tabs.

Claims

1. A battery comprising:

a battery case defining an interior volume; and

an electrode assembly mounted in the interior volume, the electrode assembly includes a plurality of metal reinforcing strips and a plurality of planar elements, the plurality of planar elements includes a plurality of positive electrodes, a plurality of negative electrodes, and a plurality of separators;

each of the positive electrodes includes

a metal substrate having a peripheral edge defining an active area and a tab extending from the active area,

a layer of positive active material on the active area of the positive electrodes;

each of the negative electrodes includes

a metal substrate having a peripheral edge defining an active area and a tab extending from the active area,

a layer of negative active material on the active area of the negative electrodes;

the tab of each positive electrode and the tab of each negative electrode having a face attached to one of the reinforcing strip such that each reinforcing strip is attached to a single one of the tabs;

the plurality of planar elements are arranged in a stack of alternating positive and negative electrodes with a separator between adjacent electrodes; and

the positive electrode tabs are aligned to form a positive tab column and the negative electrode tabs are aligned to form a negative tab column that spaced apart from the positive tab column, including a plurality of clips that each includes an integral metal piece having first and second portions bent around a foldline; and

wherein each of the clips is mounted on an electrode tab with the clip first portion attached to a front face of the tab and the second portion attached to a rear face of the tab such that the first portion and the second portion each serve as one of the metal reinforcing strips.

2. The battery of claim 1, wherein each clip on the positive electrode tabs is sufficiently thick to abut a clip on an adjacent tab along the positive tab column;

and wherein

each clip on the negative electrode tabs is sufficiently thick to abut a clip on an adjacent tab along the negative tab column.

3. The battery of claim 1, wherein each clip has a first alignment hole and a second alignment hole extending through the first portion of the clip, the second portion of the clip, and the tab between the first portion of the clip and the second portion of the clip, the first alignment hole being spaced apart from the second alignment hole.

4. The battery of claim 3, wherein each of the clips is trimmed to define a reference edge;

and wherein

the first alignment hole and the second alignment hole in each clip is referenced to the reference edge.

5. The battery of claim 3, wherein the alignment holes are circular.

6. The battery of claim 3, wherein the alignment holes are noncircular.

7. The battery of claim 3, further comprising;

registration pins extending through the first alignment holes and the second alignment holes.

8. The battery of claim 3, wherein the foldline of each clip includes an interior foldline and an exterior foldline, and the interior foldline is positioned adjacent to an outer edge of the tab to which the clip is attached.

9. The battery of claim 8, wherein each clip on the positive electrode tabs is sufficiently thick to abut a clip on an adjacent tab along the positive tab column;

and wherein

each clip on the negative electrode tabs is sufficiently thick to abut a clip on an adjacent tab along the negative tab column.

10. The battery of claim 9, wherein a first weld bonds together the clips attached to the positive electrode tabs;

and wherein

a second weld bonds together the clips attached to the negative.

11. The battery of claim 9, wherein each clip includes an opening extending from the interior foldline to the exterior foldline such that a portion of the tab to which the clip is attached is exposed through the opening;

and wherein

the first weld bonds together the portions of the positive electrode tabs that are exposed through the openings; and

the second weld bonds together the portions of the negative electrode tabs that are exposed through the openings.

12. The battery of claim 1, wherein each separator in the stack has a tab bridging the spacing between the tab on a positive electrode adjacent to the separator and the tab a negative electrode adjacent to the separator.

13. The battery of claim 1, wherein first alignment holes and second alignment holes extend through each of the positive electrode tabs and through each of the reinforcing strips attached to the positive electrode tabs;

the first alignment holes are aligned in the positive tab column;

the second alignment holes are aligned in the positive tab column;

third alignment holes and fourth alignment holes extend through each of the negative electrode tabs and through each of the reinforcing strips attached to the negative electrode tabs;

the third alignment holes are aligned in the negative tab column; and

the fourth alignment holes are aligned in the negative tab column.

14. The battery of claim 13, further comprising:

registration pins extending through the first alignment holes, the second alignment holes, the third alignment holes, and the fourth alignment holes.

15. The battery of claim 13, wherein

fifth alignment holes and sixth alignment holes extend through a tab included in each separator;

each separator tab bridges the spacing between tabs on a positive electrode adjacent to the separator and a negative electrode adjacent to the separator; and

the fifth alignment holes are aligned with the second alignment holes; and

the sixth alignment holes are aligned with the third alignment holes.

16. The battery of claim 15, wherein each separator tab is compressed between reinforcing strips in the positive tab column and between reinforcing strips in the negative tab column.

17. The battery of claim 1, wherein each of the metal substrates has a thickness within a range of 5 to 30 microns and each of the active material layers has a thickness within a range of 30 to 120 microns.

18. The battery of claim 17, wherein each of the separators has a thickness within a range of 20 to 30 microns.

19. The battery of claim 18, wherein the reinforcing strips on each positive electrode tab are sufficiently thick to abut reinforcing strips on an adjacent positive electrode tab in the stack;

and wherein

the reinforcing strips on each negative electrode tab are sufficiently thick to abut reinforcing strips on an adjacent negative electrode tab in the stack.

20. A battery, comprising:

an electrode assembly that includes a stack of planar elements, the planar elements include a plurality of alternately arranged positive electrodes and negative electrodes and means for separating adjacent electrodes;

each of the electrodes including a substrate defining an active area and a tab extending therefrom;

each tab having a first reinforcing strip attached to a front face of the tab and a second reinforcing strip attached to a rear face of the tab such that each first reinforcement strip is attached to a single one of the tabs and each second reinforcement strip is attached to a single one of the tabs;

the tabs of the positive electrodes in the stack being aligned to form a positive tab column;

the tabs of the negative electrodes in the stack being aligned to form a negative tab column extending parallel to and displaced from the positive tab column; and

wherein

a first weld bonds together the positive electrode tab reinforcing strips; and

a second weld bonds together the negative electrode tab reinforcing strips.

21. A method of fabricating an electrode assembly, comprising

forming a plurality of positive electrodes each including

a substrate defining a substrate active area and a tab extending from the active area, and

a positive active material on the active area of the positive electrodes;

forming a plurality of negative electrodes each including

a substrate defining a substrate active area and a tab extending from the active area, and

a negative active material on the active area of the negative electrodes;

attaching a first reinforcing strip to a front face of each of the tabs such that each first reinforcing strip is attached to a single one of the tabs;

attaching a second reinforcing strip to a rear face of each of the tabs such that each second reinforcing strip is attached to a single one of the tabs;

forming first and second alignment holes through each of the reinforcing strips;

alternately stacking the positive and negative electrodes together with separators interposed between adjacent electrodes to align positive electrode tabs along a first column and negative electrode tabs along a second column;

welding together the reinforcing strips attached to the positive electrode tabs; and

welding together the reinforcing stripe attached to the negative electrode tabs.