Multi-layer golf ball with reaction injection molded polyurethane component

• US 7,182,701 B2
• Filed: 11/19/2003
• Issued: 02/27/2007
• Est. Priority Date: 06/01/1993
• Status: Expired due to Fees

• Current Assignee: Callaway Golf Company
• Original Assignee: Callaway Golf Company
• Inventors: Sullivan, Michael J., Kennedy, Thomas J. III, Keller, Viktor, Risen, William M. Jr., Tzivanis, Michael John
• Primary Examiner(s): TRIMIEW, RAEANN
• Application Number:
  US10/716,683
• Publication Number:
  US 20040072629A1
• Time in Patent Office: 1,196 Days
• Field of Search: 473/373, 473/374, 473/376, 473/378
• US Class Current: 473/374
• CPC Class Codes: A63B 37/0003 Golf balls
• CPC Class Codes: A63B 37/0031 Hardness
• CPC Class Codes: A63B 37/0033 Thickness
• CPC Class Codes: A63B 37/0052 Liquid cores
• CPC Class Codes: A63B 37/0075 Three piece balls, i.e. cover, intermediate layer and core
• CPC Class Codes: A63B 37/0078 Coefficient of restitution
• CPC Class Codes: A63B 37/0082 Density; Specific gravity
• CPC Class Codes: A63B 37/02 Special cores balls with finger holes A63B37/0001, golf ball cores A63B37/005
• CPC Class Codes: A63B 37/12 Special coverings , i.e. outer layer material balls with finger holes A63B37/0001, golf ball covers A63B37/0023
• CPC Class Codes: C08L 23/08 Copolymers of ethene C08L23/16 takes precedence
• CPC Class Codes: C08L 23/0876 Neutralised polymers, i.e. ionomers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/18 Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• CPC Class Codes: C08L 75/04 Polyurethanes

Abstract

Disclosed herein is a multi-layer golf ball having a soft outer cover. The golf ball has a core, one or more mantle or inner cover layers with a Shore D hardness of 60 or more, and an outer cover with a Shore D hardness of 53 or less. In a particularly preferred form of the invention, the inner and/or outer cover layers comprise a reaction injection molded polyurethane. The golf ball of the invention has exceptionally soft feel and high spin rates on short shots of 80 yards or less and, particularly, 40 yards or less, while maintaining good distance and average spin on full shots.

Claims

1. A golf ball comprising:

a core;

an inner cover layer disposed on the core, the inner cover layer having a Shore D hardness of at least 60, and

an outer cover layer disposed on the inner core layer,

wherein the outer cover layer comprises a reaction product of one or more reactive components selected from the group consisting of i) polyether-polyols, polyester-polyols, polyamine, and materials with an active hydrogen, and ii) one or more isocyanate-containing constituents, and wherein the outer cover layer is comprised of a relatively soft, low modulus material having a flexural modulus of from about 1,000 psi to about 10,000 psi.

2. The golf ball of claim 1, wherein the golf ball exhibits a PGA compression of 100 or less and a coefficient of restitution of at least 0.750.

3. The golf ball according to claim 1, wherein the outer cover layer has a Shore D hardness of less than 53.

4. The golf ball according to claim 1, wherein the inner cover layer comprises of thermoplastic material.

5. The golf ball according to claim 1, wherein the inner cover layer comprises an ionomer resin.

6. The golf ball according to claim 1, wherein the inner cover layer has a Shore D hardness of from about 60 to about 85.

7. The golf ball according to claim 1, wherein the outer cover layer has a Shore D hardness of from about 30 to about 50.

8. The golf ball according to claim 1, wherein the inner cover layer comprises at least one member selected from the group consisting of polycarbonates, reaction-injection-molded polyurethanes, styrene-butadiene elastomers and combinations thereof.

9. The golf ball according to claim 1, wherein the inner cover layer has a thickness of from about 0.01 to about 0.15 inches and the outer cover layer has a thickness of from about 0.01 to about 0.15 inches.

10. The golf ball according to claim 1, wherein the core is selected from the group consisting of a solid core and a liquid filled core.

11. A golf ball comprising:

a core,

a first inner cover layer formed about said core,

a second inner cover layer formed about said first inner cover layer, said second inner cover layer including at least 50 weight percent of at least one material selected from the group consisting of ionomer resins, polycarbonates, reaction-injection-molded polyurethanes, styrene-butadiene elastomers and combinations thereof, and

an outer cover layer formed over the second inner cover layer, the outer cover layer comprising a reaction product of one or more reactive components selected from the group consisting of i) polyether-polyols, polyester-polyols, polyamine, and materials with an active hydrogen, and ii) one or more isocyanate-containing constituents, the golf ball having a PGA compression of 100 or less and a coefficient of restitution of at least 0.750, and wherein the outer cover layer is comprised of a relatively soft, low modulus material having a flexural modulus of from about 1,000 psi to about 10 ,000 psi.

12. The golf ball according to claim 11, wherein the second inner cover material is thermoplastic.

13. The golf ball according to claim 11, wherein the second inner cover material is a thermoset.

14. The golf ball according to claim 11, wherein the second inner cover material layer comprises a styrene-butadiene elastomer.

15. The golf ball of claim 11, wherein the outer cover layer has a Shore D hardness of less than 53.

16. The golf ball according to claim 15, wherein the outer cover layer has a Shore D hardness of from about 30 to about 50.