Catalyst composition II
First Claim
1. A transition metal catalyst compound for oligomerization of an unsaturated monomer represented by the formula:
- LMX2 or the formula (LMX2)2 whereineach M is independently a Group 7, 8, 9 or 10 transition metal;
each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms, and at least two terminal nitrogen atoms are substituted with one C3–
C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3–
C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; and
each X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
1 Assignment
0 Petitions
Accused Products
Abstract
This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3–C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3–C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
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Citations
163 Claims
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1. A transition metal catalyst compound for oligomerization of an unsaturated monomer represented by the formula:
- LMX2 or the formula (LMX2)2 wherein
each M is independently a Group 7, 8, 9 or 10 transition metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms, and at least two terminal nitrogen atoms are substituted with one C3–
C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3–
C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; andeach X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38)
- LMX2 or the formula (LMX2)2 wherein
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39. A process to oligomerize an unsaturated monomer comprising contacting the monomer with a catalyst system comprising a transition metal catalyst compound combined with an activator, where the combination is selected from the group consisting of:
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[bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]cobalt dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]cobalt dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]cobalt dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dibromide/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dibromide/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dibromide/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dibromide/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dimethyl/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dimethyl/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dimethyl/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dimethyl/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]iron dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]iron dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]iron dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]iron dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]iron dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]iron dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]iron dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]iron dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]iron dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]iron dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]iron dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]iron dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]manganese dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]manganese dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]manganese dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]manganese dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]manganese dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]manganese dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]manganese dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,4,6-triethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]nickel dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]nickel dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]nickel dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]nickel dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]nickel dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]nickel dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]copper dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]copper dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]copper dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]copper dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]copper dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]copper dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]copper dichloride/methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]copper dichloride/methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]copper dichloride/methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]cobalt dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]cobalt dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dibromide/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dibromide/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dibromide/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dibromide/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dimethyl/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dimethyl/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dimethyl/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dimethyl/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]iron dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]iron dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]iron dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]manganese dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]manganese dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,4,6-triethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]nickel dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]nickel dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]copper dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]copper dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]copper dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]copper dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]copper dichloride/modified methylalumoxane, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]copper dichloride/modified methylalumoxane, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]copper dichloride/modified methylalumoxane, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]copper dichloride/modified methylalumoxane, and [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]copper dichloride/modified methylalumoxane.
-
- 40. A transition metal catalyst compound for oligomerization of an unsaturated monomer is represented by the formula:
- 76. A transition metal catalyst compound for oligomerization of an unsaturated monomer represented by the formula:
- 112. A transition metal catalyst compound for ologomerization of an unsaturated monomer represented by the formula:
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146. A transition metal catalyst compound for oligomerization of an unsaturated monomer selected from the group consisting of
[bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]cobalt dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]cobalt dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]cobalt dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]cobalt dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]cobalt dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]cobalt dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]cobalt dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]cobalt dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dibromide, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dibromide, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]cobalt dibromide, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]cobalt dibromide, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]cobalt dibromide, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]cobalt dibromide, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dibromide, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dibromide, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dibromide, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]cobalt dibromide, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]cobalt dibromide, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]cobalt dibromide, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]cobalt dibromide, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]cobalt dimethyl, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]cobalt dimethyl, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]cobalt dimethyl, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]cobalt dimethyl, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]cobalt dimethyl, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]cobalt dimethyl, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]cobalt dimethyl, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]cobalt dimethyl, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]cobalt dimethyl, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]cobalt dimethyl, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]cobalt dimethyl, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]cobalt dimethyl, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]cobalt dimethyl, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]iron dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]iron dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]iron dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]iron dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]iron dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]iron dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]iron dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]iron dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]iron dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]iron dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]iron dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]iron dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]iron dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]manganese dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]manganese dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]manganese dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]manganese dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]manganese dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]manganese dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]manganese dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]manganese dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]manganese dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]manganese dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]manganese dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]manganese dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride, [bis(N-2,4,6-triethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]manganese dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)amine]nickel dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)amine]nickel dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)amine]nickel dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)amine]nickel dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)amine]nickel dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)amine]nickel dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)methylamine]nickel dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)methylamine]nickel dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)methylamine]nickel dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)methylamine]nickel dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)methylamine]nickel dichloride, [bis(N-2,6-diethylphenyl-2-aminoethyl)methylamine]nickel dichloride, [bis(N-2,6-dimethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride, [bis(N-2,4,6-trimethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride, [bis(N-2,6-diisopropylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride, [bis(N-2,4,6-triisopropylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride, [bis(N-2,6-diisopropyl-4-methylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride, and [bis(N-2,6-diethylphenyl-2-aminoethyl)(2-picolyl)amine]nickel dichloride.
Specification