In situ sterilization and decontamination system using a non-thermal plasma discharge

• US 7,192,553 B2
• Filed: 11/04/2002
• Issued: 03/20/2007
• Est. Priority Date: 12/15/1999
• Status: Expired due to Term

• Current Assignee: Stevens Institute Of Technology, PlasmaSol Corp. (Stryker Corporation)
• Original Assignee: Stevens Institute Of Technology, PlasmaSol Corp. (Stryker Corporation)
• Inventors: Babko-Malyi, Sergei, Crowe, Richard, Korfiatis, George
• Primary Examiner(s): JASTRZAB, KRISANNE MARIE
• Application Number:
  US10/287,771
• Publication Number:
  US 20030132100A1
• Time in Patent Office: 1,597 Days
• Field of Search: 422/22, 422/23, 422/28, 422/29
• US Class Current: 422/23
• CPC Class Codes: A61L 2/14 Plasma, i.e. ionised gases
• CPC Class Codes: A61L 9/22 Ionisation
• CPC Class Codes: B01D 2257/91 Bacteria; Microorganisms
• CPC Class Codes: B01D 2259/818 Employing electrical discharges or the generation of a plasma
• CPC Class Codes: B01D 53/323 by electrostatic effects or by high-voltage electric fields
• CPC Class Codes: F24F 8/20 by sterilisation
• CPC Class Codes: H05H 1/2406 using dielectric barrier discharges, i.e. with a dielectric interposed between the electrodes
• CPC Class Codes: H05H 1/2443 the plasma fluid flowing through a dielectric tube
• CPC Class Codes: H05H 2245/15 Ambient air; Ozonisers

Abstract

A sterilization and decontamination system in which a non-thermal plasma discharge device is disposed upstream of a suspension media (e.g., a filter, electrostatic precipitator, carbon bed). The plasma discharge device generates a plasma that is emitted through apertures (e.g., capillaries or slits) in the primary dielectric. Plasma generated active sterilizing species when exposed to contaminants or undesirable particulate matter is able to deactivate or reduce such matter in contaminated fluid stream and/or on objects. Thus, the undesirable contaminants in the fluid to be treated are first reduced during their exposure to the plasma generated active sterilizing species in the plasma region of the discharge device. Furthermore, the plasma generated active sterilizing species are carried downstream to suspension media and upon contact therewith deactivate the contaminants collected on the suspension media itself. Advantageously, the suspension media may be cleansed in situ. To increase the sterilization efficiency an additive, free or carrier gas (e.g., alcohol, water, dry air) may be injected into the apertures defined in the primary dielectric. These additives increase the concentration of plasma generated active sterilizing agents while reducing the byproduct of generated undesirable ozone pollutants. Downstream of the filter the fluid stream may be further treated by being exposed to a catalyst media or additional suspension media to further reduce the amount of undesirable particulate matter.

Claims

1. A method of sterilizing or decontaminating an object using a plasma discharge device comprising the steps of:

introducing an additive fluid into the plasma discharge device, wherein the additive fluid is a mixture comprising an organic vapor and air;

producing a plasma generated active sterilizing species from the additive fluid;

emitting the plasma generated active sterilizing species from the plasma discharge device; and

exposing the object to the emitted active sterilizing species downstream from the plasma discharge device.

2. The method in accordance with claim 1, wherein the plasma discharge device has a dielectric having at least one aperture defined therethrough and an electrode disposed proximate and in fluid communication with the at least one aperture, and the additive fluid is introduced into the plasma discharge device by injecting it into the aperture of the dielectric.

3. The method in accordance with claim 1, wherein the plasma discharge device has a capillary dielectric, slit dielectric, barrier discharge, or corona discharge configuration.

4. The method in accordance with claim 1, wherein the organic vapor comprise alcohol.

5. The method in accordance with claim 4, wherein the alcohol is ethanol or methanol.

6. The method in accordance with claim 1, wherein the object is a fluid, suspension media, food product, ventilation duct, or medical instrument.

7. The method in accordance with claim 6, wherein the object is a suspension media comprising at least one of a filter, electrostatic precipitator, or carbon bed.

8. The method in accordance with claim 1, wherein the plasma discharge device comprises a porous electrode.

16. The method in accordance with claim 7, further comprising the step of cleansing the particulate matter collected in the suspension media with the plasma generated active sterilizing species.

9. A method of sterilizing or decontaminating a fluid to be treated using a plasma discharge device, comprising the steps of:

introducing an additive fluid to the plasma discharge device, wherein the additive fluid comprises an organic compound;

flowing the fluid to be treated through the plasma discharge device;

producing a plasma generated active sterilizing species from the additive fluid and the fluid to be treated by operation of the plasma discharge device;

exposing contaminants in the fluid to be treated to the plasma generated active sterilizing species;

flowing the plasma generated active sterilizing species and the fluid to be treated downstream toward a suspension media;

collecting particulate matter from the fluid to be treated in the suspension media; and

exposing the particulate matter collected in the suspension media with to the plasma generated active sterilizing species.

10. The method in accordance with claim 9, further comprising the step of subjecting the fluid to be treated after passing through the suspension media to a catalyst media.

11. The method in accordance with claim 9, wherein the suspension media comprises at least one of a filter, electrostatic precipitator, or carbon bed.

12. The method in accordance with claim 10, wherein the suspension media comprises at least one of a filter, electrostatic precipitator, or carbon bed.

13. The method in accordance with claim 9, wherein the organic compound is an alcohol.

14. The method in accordance with claim 13, wherein the alcohol is ethanol or methanol.

15. The method in accordance with claim 9, wherein the plasma discharge device comprises a porous electrode.

17. A method of producing active sterilizing species comprising the steps of:

introducing an additive fluid into a plasma discharge device, wherein the plasma discharge device is adapted to receive the additive fluid, and wherein the additive fluid is a mixture comprising an organic vapor and air;

producing a plasma generated active sterilizing species from the additive fluid by operation of the plasma discharge device; and

emitting the plasma generated active sterilizing species from the plasma discharge device.

18. The method in accordance with claim 17, wherein the organic vapor is an alcohol.

19. The method in accordance with claim 18, wherein the alcohol is ethanol or methanol.

20. The method in accordance with claim 17, wherein the plasma discharge device has at least one of a capillary dielectric configuration, a slit dielectric, barrier discharge, and corona discharge configuration.

21. The method in accordance with claim 17, further comprising the step of exposing an object to the emitted active sterilizing species downstream from the plasma discharge device.

22. The method in accordance with claim 17, wherein the plasma discharge device comprises a porous electrode.