Warewashing composition for use in automatic dishwashing machines, comprising a zinc ion and aluminum ion corrosion inhibitor

• US 7,196,044 B2
• Filed: 06/25/2004
• Issued: 03/27/2007
• Est. Priority Date: 07/02/2003
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Smith, Kim R., Man, Victor F., Olson, Keith E., Lentsch, Steven E., Bartelme, Michael J., Baum, Burton M., Kestell, Howie, Everson, Terence P.
• Primary Examiner(s): BOYER, CHARLES I
• Application Number:
  US10/877,049
• Publication Number:
  US 20050020464A1
• Time in Patent Office: 1,005 Days
• Field of Search: 510/220, 510/224, 510/225, 510/227, 510/233, 510/367, 510/379, 510/439, 510/441, 510/445, 510/485, 510/508, 510/514, 510/521
• US Class Current: 510/225
• CPC Class Codes: C11D 17/0052 Cast detergent compositions
• CPC Class Codes: C11D 3/0073 Anticorrosion compositions
• CPC Class Codes: C11D 3/02 Inorganic compounds ; Elemental compounds
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/12 Water-insoluble compounds
• CPC Class Codes: C11D 3/2075 Carboxylic acids-salts thereof

Abstract

A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.

Claims

1. A warewashing detergent composition comprising:

(a) a cleaning agent comprising about 0.5 wt. % to about 20 wt. % surfactant based on the weight of the detergent composition;

(b) an alkaline source in an amount effective to provide a use composition having a pH of at least about 8 and obtained by diluting the warewashing detergent composition with water, and wherein the alkaline source comprises at least one of sodium hydroxide, potassium hydroxide, or mixtures thereof; and

(c) a corrosion inhibitor in an amount sufficient for reducing corrosion of glass, the corrosion inhibitor comprising;

(i) a source of aluminum ion;

(ii) a source of zinc ion; and

(iii) wherein the source of aluminum ion and the source of zinc ion are present in amounts sufficient to provide a use composition having a weight ratio of zinc ion to aluminum ion of at least about 2;

1, and wherein the composition is provided as a solid as a result of extrusion or casting, and wherein the warewashing detergent composition comprises a block having a size of at least about 5 grams.

2. A warewashing detergent composition according to claim 1, wherein the source of aluminum ion and the source of zinc ion are present in amounts sufficient to provide a use composition having a weight ratio of zinc ion to aluminum ion of about 20:

1 to about 3;

1.

3. A warewashing detergent composition according to claim 1, wherein the source of aluminum ion and the source of zinc ion are present in amounts sufficient to provide a use composition having a weight ratio of zinc ion to aluminum ion of about 15:

1 to about 4;

1.

4. A warewashing detergent composition according to claim 1, wherein the detergent composition comprises about 0.5 wt. % to about 25 wt. % of the corrosion inhibitor.

5. A warewashing detergent composition according to claim 1, wherein the surfactant comprises at least one of an anionic surfactant, a nonionic surfactant, a cationic surfactant, or a zwitterionic surfactant.

6. A warewashing detergent composition according to claim 1, wherein the alkaline source further comprises at least one metal carbonate, or a mixture thereof.

7. A warewashing detergent composition according to claim 6, wherein the metal cabonate comprises at least one of sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, sodium sesquicarbonate, potassium sesquicarbonate, or mixtures thereof.

8. A warewashing detergent composition according to claim 1, the source of aluminum ion comprises at least one of sodium aluminate, aluminum bromide, aluminum chlorate, aluminum chloride, aluminum iodide, aluminum nitrate, aluminum sulfate, aluminum acetate, aluminum formate, aluminum tartrate, aluminum lactate, aluminum oleate, aluminum bromate, aluminum borate, aluminum potassium sulfate, aluminum zinc sulfate, aluminum phosphate, aluminum oxide, aluminum silicate, or mixtures thereof.

9. A warewashing detergent composition according to claim 1, wherein the source of aluminum ion comprises a component characterized by the United States Food and Drug Administration as a direct or indirect food additive.

10. A warewashing detergent composition according to claim 1, wherein the source of aluminum ion comprises particles having an average particle size of less than about 500 nanometers.

11. A warewashing detergent composition according to claim 1, wherein the source of zinc ion comprises at least one of zinc chloride, zinc sulfate, zinc nitrate, zinc iodide, zinc thiocyanate, zinc fluorosilicate, zinc dichioniate, zinc chlorate, sodium zincate, zinc gluconate, zinc acetate, zinc benzoate, zinc citrate, zinc lactate, zinc formate, zinc bromate, zinc bromide, zinc fluoride, zinc fluosilicate, zinc salicylate, zinc oxide, zinc aluminate, zinc silicate, or mixtures thereof.

12. A warewashing detergent composition according to claim 1, wherein the source of zinc ion comprises a component characterized by the United States Food and Drug Administration as a direct or indirect food additive.

13. A warewashing detergent composition according to claim 1, wherein the source of zinc ion comprises particles having an average particle size of less than about 500 nanometers.

14. A warewashing detergent composition according to claim 1, wherein the warewashing detergent composition further comprises about 0.1 wt. % to about 70 wt. % chelating/sequestering agent.

15. A warewashing detergent composition according to claim 1, wherein the warewashing detergent composition further comprises about 0.1 wt. % to about 60 wt. % bleaching agent.

16. A warewashing detergent composition according to claim 1, wherein the warewashing detergent composition further comprises about 1 wt. % to about 20 wt. % detergent filler.

17. A warewashing detergent composition according to claim 1, wherein the warewashing detergent composition further comprises about 0.01 wt. % and about 3 wt. % defoaming agent.

18. A warewashing detergent composition according to claim 1, wherein the warewashing detergent composition further comprises about 0.5 wt. % to about 10 wt. % anti-redeposition agent.

19. A warewashing detergent composition according to claim 1, wherein the warewashing detergent composition further comprises about 5 wt. % to about 60 wt. % water.

20. A warewashing detergent composition according to claim 1, wherein the warewashing detergent composition further comprises about 0.1 wt. % to about 10 wt. % water.

21. A warewashing detergent composition according to claim 1, wherein the warewashing detergent composition comprises a black having a size of at least about 50 grams.

22. A warewashing detergent composition according to claim 1, further comprising a water-soluble packaging material enclosing the warewashing detergent composition.

23. A warewashing detergent composition according to claim 22, wherein the water-soluble packaging material comprises polyvinyl alcohol.

24. A warewashing detergent composition according to claim 23, wherein the warewashing detergent composition is provided within the water-soluble packaging material in an amount sufficient to provide a unit dose for application in a dishwashing machine.

25. A method for using a warewashing detergent composition, the method comprising:

(a) diluting a warewashing detergent composition provided as a solid as a result of extrusion or casting with water at a dilution ratio of water to warewashing detergent composition of at least about 20;

1 to form a use composition, wherein the warewashing detergent composition comprises;

(i) a cleaning agent comprising about 0.5 wt. % to about 20 wt. % surfactant based on the weight of the detergent composition;

(ii) an alkaline source in an amount effective to provide a use composition having a pH of at least about 8, wherein the alkaline source comprises at least one of sodium hydroxide, potassium hydroxide, or mixtures thereof;

(iii) a corrosion inhibitor in an amount sufficient for reducing corrosion of glass, the corrosion inhibitor comprising a source of zinc ion and a source of aluminum ion in amounts sufficient to provide a use composition comprising zinc ion and aluminum ion at a weight ratio of zinc ion to aluminum ion of at least about 2;

1; and

(b) washing ware with thc use composition in an automatic dishwashing machine.

26. A method according to claim 25, wherein the water diluting to warewashing detergent composition comprises water having a total dissolved solids content of greater than about 200 ppm.

27. A method according to claim 25, wherein the use composition comprises a free calcium ion concentration of greater than about 200 ppm.

28. A process according to claim 25, wherein the amount of the source of zinc ion and the amount of the source of aluminum ion is sufficient to provide a weight ratio of zinc ion to aluminum ion of about 20:

1 to about 3;

1.

29. A process according to claim 25, wherein the amount of the source of zinc ion and the amount of the source of aluminum ion is sufficient to provide a weight ratio of zinc ion to aluminum ion of about 15:

1 to about 4;

1.

30. A process according to claim 25, wherein the detergent composition comprises about 0.5 wt. % to about 25 wt. % of the corrosion inhibitor.

31. A process according to claim 25, wherein the surfactant comprises at least one of an anionic surfactant, a nonionic surfactant, a cationic surfactant, and a zwitterionic surfactant.

32. A process according to claim 25, the source of aluminum ion comprises at least one of sodium aluminate, aluminum bromide, aluminum chlorate, aluminum chloride, aluminum iodide, aluminum nitrate, aluminum sulfate, aluminum acetate, aluminum formate, aluminum tartrate, aluminum lactate, aluminum oleate, aluminum bromate, aluminum borate, aluminum potassium sulfate, aluminum zinc sulfate, aluminum phosphate, aluminum oxide, aluminum silicate, or mixtures thereof.

33. A process according to claim 26, wherein the source of aluminum ion comprises a component characterized by the United States Food and Drug Administration as a direct or indirect food additive.

34. A process according to claim 25, wherein the source of aluminum ion comprises particles having an average particle size of less than about 500 nanometers.

35. A process according to claim 25, wherein the source of zinc ion comprises at least one of zinc chloride, zinc sulfate, zinc nitrate, zinc iodide, zinc thiocyanate, zinc fluorosilicate, zinc dichromate, zinc chlorate, sodium zincate, zinc gluconate, zinc acetate, zinc benzoate, zinc citrate, zinc lactate, zinc formate, zinc bromate, zinc bromide, zinc fluoride, zinc fluosilicate, zinc salicylate, zinc oxide, zinc silicate, or mixtures thereof.

36. N process according to claim 25, wherein the source of zinc ion comprises a component characterized by the United States Food and Drug Administration as a direct or indirect food additive.

37. A process according to claim 25, wherein the source of zinc ion comprises particles having an average particle size of less than about 500 nanometers.

38. A method for using a detergent composition, the method comprising:

(a) diluting a detergent composition provided as a solid as a result of extrusion or casting with water at a dilution ratio of water to detergent composition of at least about 20;

1 to form a use composition, wherein the detergent composition comprises;

(i) a cleaning agent comprising about 0.5 wt. % to about 20 wt. % surfactant based on the weight of the detergent composition;

(ii) a corrosion inhibitor in an amount sufficient for reducing corrosion of glass, the corrosion inhibitor comprising a source of zinc ion and a source of aluminum ion in amounts sufficient to provide a use composition comprising zinc ion and aluminum ion at a weight ratio of zinc ion to aluminum ion of at least about 2;

1; and

(iii) an alkaline source comprising at least one of sodium hydroxide, potassium hydroxide, or mixtures thereof; and

(b) washing a hard surface with the use composition, wherein the hard surface comprises at least one of a window or a mirror.