Electrically switchable polymer-dispersed liquid crystal materials including switchable optical couplers and reconfigurable optical interconnects

• US 7,198,737 B2
• Filed: 01/27/2006
• Issued: 04/03/2007
• Est. Priority Date: 07/29/1998
• Status: Expired due to Fees

• Current Assignee: Leidos, Inc. (Leidos Holdings, Inc.)
• Original Assignee: Science Applications International Corporation
• Inventors: Tondiglia, Vince P., Sutherland, Richard L., Epling, Bob, Natarajan, Lalgudi V., Bunning, Timothy J., Brandelik, Donna M.
• Primary Examiner(s): Wu; Shean C
• Application Number:
  US11/340,681
• Publication Number:
  US 20060159864A1
• Time in Patent Office: 431 Days
• Field of Search: 252/582, 349/201, 349/202, 359/15, 359/566, 359/569, 359/320, 359/321, 385/15, 385/16, 385/17, 385/26, 385/36, 385/37, 430/20
• US Class Current: 252/582
• CPC Class Codes: C09K 2323/00 Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
• CPC Class Codes: G02B 5/32 Holograms used as optical elements
• CPC Class Codes: G02B 6/2713 cascade of polarisation selective or adjusting operations
• CPC Class Codes: G02B 6/2931 Diffractive element operating in reflection
• CPC Class Codes: G02B 6/29311 Diffractive element operating in transmission
• CPC Class Codes: G02B 6/29314 by moving or modifying the diffractive element, e.g. deforming
• CPC Class Codes: G02B 6/29395 configurable, e.g. tunable or reconfigurable switching G02B6/35
• CPC Class Codes: G02F 1/13342 Holographic polymer dispersed liquid crystals
• CPC Class Codes: G02F 2201/305 diffraction grating
• CPC Class Codes: G03H 1/0005 Adaptation of holography to specific applications holographic optical element G02B5/32; holographic scanner G02B26/106; recognition using holographic mask G06V10/88; holographic memories G11B7/0065, G11C13/042
• CPC Class Codes: G03H 1/02 Details of features involved during the holographic process; Replication of holograms without interference recording
• CPC Class Codes: G03H 1/0248 Volume holograms
• CPC Class Codes: G03H 2001/026 Recording materials or recording processes G03H2226/11 takes precedence; corresponding details, see subgroups of G03H2260/00
• CPC Class Codes: G03H 2001/0264 Organic recording material
• CPC Class Codes: G03H 2001/2615 in physical contact, i.e. layered holograms
• CPC Class Codes: G03H 2260/12 Photopolymer
• CPC Class Codes: G03H 2260/33 Having dispersed compound

Abstract

A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. A method for preparing a switchable grating can comprise the steps of placing a mixture between a first and second slide, wherein the mixture has a photopolymerizable monomer, a second phase material, a photoinitiator dye, and a chain extender or cross-linker. The mixture is exposed to a laser and optical intensity pattern is applied to induce photopolymerization. A method for recording slanted reflection gratings can comprise the steps of placing a sample between a first and second glass prism, the sample comprising a polymerizable monomer, a liquid crystal, a chain-extending monomer, a coinitiator, and a photoinitiator. An incident light is split into two beams, wherein the beams enter the sample from opposite sides. The first and second prism are rotated to adjust the slant of the grating.

Claims

1. A method for preparing a switchable grating, the method comprising the steps of:

placing a mixture between a first and second slide, wherein the mixture comprises;

a photopolymerizable monomer;

a second phase material;

a photoinitiator dye; and

a chain extender or cross-linker;

exposing the mixture to a laser; and

applying an optical intensity pattern to induce photopolymerization.

2. The method of claim 1, wherein the slides are indium-tin-oxide coated glass slides.

3. The method of claim 1, wherein the slides are separated by spacers.

4. The method of claim 1, wherein the laser is an argon ion laser.

5. The method of claim 1, wherein the mixture further comprises a surfactant.

6. The method of claim 1, wherein the photopolymerizable monomer or second phase material is substantially miscible.

7. The method of claim 1, wherein the second phase material is a liquid crystal.

8. The method of claim 3, wherein the spacers have a thickness of approximately 15–

100 μ

m.

9. The method of claim 3, wherein the spacers have a thickness of approximately 10–

20 μ

m.

10. The method of claim 1, wherein the photoinitiator is selected from the group consisting of N-phenylglycine, triethylene amine, triethanolamine, and N,N-dimethyl-2,6-diisopropyl aniline.

11. The method of claim 1, wherein the chain extender is a vinyl monomer.

12. The method of claim 1, wherein the chain extender is selected from the group consisting of N-vinyl pyrrolidone, N-vinyl pyridine, acrylonitrile, and N-vinyl carbazole.

13. The method of claim 5, wherein the surfactant is selected from the group consisting of octanoic acid, heptanoic acid, hexanoic acid, dodecanoic acid, and decanoic acid.

14. The method of claim 1, wherein the photopolymerizable monomer comprises a liquid crystalline bifunctional acrylate.

15. The method of claim 1, further comprising the step of placing a mirror behind the second slide, wherein the distance of the mirror from the mixture is shorter than the coherence length of the laser.

16. The method of claim 1, wherein the photopolymerizable monomer is selected from the group consisting of triethyleneglycol diacrylate, trimethylolpropanetriacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate, and pentaerythritol pentaacrylate.

17. The method of claim 1, wherein the second phase material has a negative dielectric anisotropy.

18. The method of claim 1, wherein the second phase material has a positive dielectric anisotropy.

19. The method of claim 1, wherein the second phase material has a positive dielectric anisotropy below a cross-over frequency and a negative dielectric anisotropy above the cross-over frequency.

20. The method of claim 1, wherein the cross-over frequency is approximately 1–

10 kHz.

21. The method of claim 1, further comprising the step of exposing the mixture to a magnetic field.

22. A method for recording slanted reflection gratings, the method comprising the steps of:

placing a sample between a first and second glass prism;

the sample comprising;

a polymerizable monomer;

a liquid crystal;

a chain-extending monomer;

a coinitiator; and

a photoinitiator;

splitting an incident light into two beams, wherein the beams enter the sample from opposite sides; and

rotating the first and second prism to adjust the slant of the grating.

23. The method of claim 22, further comprising the step of placing neutral density filters in optical contact with a back face of the first or second prism.

24. The method of claim 22, wherein the sample is placed between the hypotenuses of the first and second glass prism.

25. A method for forming a slanted grating, the method comprising the steps of:

directing overlapping first and second incident beams through a prism assembly towards a sample,

wherein the angle of incidence of the first beam is different from the angle of incidence of the second beam and wherein the incident beams enter the sample from the same side,

wherein the prism assembly comprises a first and a second prism and is substantially disposed on the surface of the sample, and

wherein the sample comprises;

a polymerizable monomer;

a liquid crystal;

a chain-extending monomer;

a coinitiator; and

a photoinitiator.

26. The method of claim 25, wherein the second beam is directed along a normal to the sample.

27. The method of claim 25, wherein the first beam is directed along a normal to the first prism and the second beam is directed along a normal to the second prism.

28. The method of claim 25, wherein the prism assembly comprises two right angle prisms.

29. The method of claim 25, further comprising an index matching fluid between the two prisms and between the prism assembly and the sample.

30. The method of claim 25, further comprising the step of placing neutral density filters in optical contact with the back faces of the first and second prisms.

31. A transmission grating comprising:

a plurality of alternating polymer planes and polymer dispersed liquid crystal planes disposed perpendicular to the front surface of the transmission grating; and

an optical axis disposed perpendicular to the plurality of alternating polymer planes and polymer dispersed liquid crystal planes;

wherein the combined thickness of a polymer plane and a polymer dispersed liquid crystal plane is substantially less than an optical wavelength.

32. The transmission grating of claim 31, wherein a symmetry axis of the polymer dispersed liquid crystal planes is disposed in a direction substantially parallel to the front surface of the transmission grating and substantially perpendicular to the polymer planes and polymer dispersed liquid crystal planes.