Adhesives comprising olefin polymers

• US 7,199,180 B1
• Filed: 03/14/1997
• Issued: 04/03/2007
• Est. Priority Date: 03/14/1996
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.), H.B. Fuller Licensing & Financing, Inc.
• Original Assignee: The Dow Chemical Company (Dow, Inc.), H.B. Fuller Licensing & Financing, Inc.
• Inventors: Bunnelle, William L., Finlayson, Malcolm F., Yalvac, Selim, Rickey, Cynthia L., Speth, David R., Malcolm, David B., Simmons, Eugene R., Kroll, Mark S., Parikh, Deepak R., Kauffman, Thomas F., Keehr, Michael S., Knutson, Keith C., Allen, Jimmy D.
• Primary Examiner(s): Mulcahy; Peter D.
• Application Number:
  US08/973,779
• Time in Patent Office: 3,672 Days
• Field of Search: 524/579, 524/271, 524/274, 524/482, 524/484, 524/485, 524/486, 524/487, 524/505, 524/522, 524/523, 524/524, 524/528, 524/570
• US Class Current: 524/570
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C08F 210/14 Monomers containing five or more carbon atoms
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: C08F 2500/02 Low molecular weight, e.g. <100,000 Da.
• CPC Class Codes: C08F 2500/03 Narrow molecular weight distribution, i.e. Mw/Mn < 3
• CPC Class Codes: C08F 2500/08 Low density, i.e. < 0.91 g/cm3
• CPC Class Codes: C08F 2500/12 Melt flow index or melt flow ratio
• CPC Class Codes: C08K 5/0008 Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
• CPC Class Codes: C08K 5/0016 Plasticisers
• CPC Class Codes: C08L 23/04 Homopolymers or copolymers of ethene
• CPC Class Codes: C08L 23/0853 Vinylacetate
• CPC Class Codes: C08L 23/0869 Acids or derivatives thereof
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C09J 123/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C09J 2423/00 Presence of polyolefin
• CPC Class Codes: C09J 7/35 Heat-activated

Abstract

Disclosed are adhesives and processes for preparing the same, comprising at least one first homogeneous ethylene/α-olefin interpolymer, and optionally at least one tackifier, and optionally at least one plasticizer. The claimed adhesives are useful as adhesives such as are employed in various applications, such as in masking tape, clear office tape, labels, decals, bandages, decorative and protective sheets (such as shelf and drawer liners), floor tiles, sanitary napkin/incontinence device placement strips, sun control films, the joining of gaskets to automobile windows, packaging, bookbinding, construction of nonwoven articles, and insulation bonding.

Claims

1. A pressure sensitive adhesive comprising:

(a) from 5 to 95 weight percent of at least one interpolymer, which is a homogeneous ethylene/α

-olefin interpolymer, characterized as having a density from 0.850 to 0.885 g/cm³ and a weight average molecular weight (Mw) of less than 20,000;

(b) from 0 to 95 weight percent of at least one tackifier;

(c) from 0 to about 90 weight percent of at least one plasticizer; and

(d) from 0 to 90 weight percent of at least one wax;

wherein the sum of components (b), (c), and (d) comprises 5 to 95 weight percent of said adhesive composition, wherein said adhesive is characterized as having a storage modulus (G′

), at 25°

C., of less than 1×

10⁷ dynes/cm² (1 MPa), and a glass transition temperature (T_g) from −

65°

C. to 30°

C., and

wherein the α

-olefin is randomly distributed within the ethylene/α

-olefin interpolymer.

2. The adhesive of claim 1, wherein the glass transition temperature ranges from 0 to 30°

C.

3. The adhesive of claim 1, wherein the ethylene/α

-olefin interpolymer is prepared from at least one C₃–

C₂₀ α

-olefin, selected from the group consisting of propylene, isobutylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 4-methyl-1-pentene, and 1-octene.

4. The adhesive of claim 1, where the at least one interpolymer has a density of 0.870 g/cm³ or less.

5. The adhesive of claim 1, wherein the at least one tackifier is provided in an amount greater than 5 weight percent, and wherein the softening point of the tackifier ranges from being flowable at ambient temperature to about 130°

C.

6. The adhesive of claim 1, wherein the at least one plasticizer is provided in an amount totaling less than 30 weight percent, and is

(a) a phthalate, natural oil, paraffinic oil, naphthenic oil, aromatic oil, or

(b) a cyclohexane dimethanol dibenzoate compound, or

(c) a mixture of (a) and (b).

7. The adhesive of claim 1, further comprising from 3 to 70 weight percent of at least one second polymer, which is an ethylene homopolymer or an interpolymer of ethylene with at least one C₃–

C₂₀ α

-olefin, and wherein the at least one second polymer has;

(i) a density of from 0.910 to 0.970 g/cm³,

(ii) a number average molecular weight, as determined by gel permeation chromatography, of less than 6,000; and

wherein the at least one tackifier is provided in an amount from 0 to 70 weight percent.

8. The adhesive of claim 1, wherein the adhesive further comprises a modifying or extending composition, selected from the group consisting of wax, styrenic block copolymers, polyamides, interpolymers or ionomers of ethylene and mixtures thereof.

9. The adhesive of claim 8, wherein the modifying or extending composition is selected from the group consisting of ethylene/acrylic acid, ethylene/methyl acrylate, ethylene/isobutyl acrylate, ethylene/n-butyl acrylate, ethylene/methyl methacrylate copolymers and mixtures thereof.

10. The adhesive of claim 1, further comprising a polyethylene having molecular weight of greater than 3,000.

11. The adhesive of claim 10, wherein the amount of the polyethylene ranges from about 20 to about 60 weight percent.

12. The adhesive of claim 1, wherein the homogeneous ethylene/α

-olefin interpolymer is an interpolymer of ethylene, having greater than 30 weight percent, as determined by mass balance, of an α

-olefin comonomer having from 3 to 20 carbon atoms.

15. The adhesive of claim 1, wherein the ethylene/α

-olefin interpolymer is a copolymer of ethylene and one α

-olefin.

16. The adhesive of claim 1, wherein the ethylene/α

-olefin interpolymer comprises 9.1 to 12.5 mole percent of the α

-olefin.

17. The adhesive of claim 1, wherein the adhesive comprises 10 to 75 weight percent of at least one tackifier.

18. The adhesive of claim 1, wherein the adhesive comprises 10 to 50 weight percent of at least one plasticizer (solid).

19. The adhesive of claim 17, wherein the adhesive comprises 10 to 50 weight percent of at least one plasticizer (solid).

20. The adhesive of claim 1, wherein the composition further comprises at least one additive selected from the group consisting of antioxidants, antiblock additives, pigments and fillers.

21. The adhesive of claim 1, wherein the composition further comprises at least one antioxidant.

22. The adhesive of claim 17, wherein the composition further comprises at least one additive selected from the group consisting of antioxidants, antiblock additives, pigments and fillers.

23. The adhesive of claim 17, wherein the composition further comprises at least one antioxidant.

24. The adhesive of claim 18, wherein the composition further comprises at least one additive selected from the group consisting of antioxidants, antiblock additives, pigments and fillers.

25. The adhesive of claim 19, wherein the composition further comprises at least one additive selected from the group consisting of antioxidants, antiblock additives, pigments and fillers.

13. A pressure sensitive adhesive consisting essentially of:

(a) from 5 to 95 weight percent of a least one homogeneous ethylene/α

-olefin interpolymer having a density from 0.850 to 0.885 g/cm³ and a weight average molecular weight (Mw) of less than 20,000;

(b) from 0 to 95 weight percent of at least one tackifier;

(c) from 0 to 95 weight percent of at least one plasticizer;

(d) from 0 to 95 percent of at least one wax;

(e) at least one antioxidant; and

wherein the sum of component (b), (c), and (d) comprises 5 to 95 percent of the adhesive composition, and wherein said adhesive is characterized as having a storage modulus (G′

), at 25°

C., of less than 1×

10⁷ dynes/cm² (1 MPa), and a glass transition temperature (T_g) from −

65°

C. to 30°

C., and

wherein the α

-olefin is randomly distributed within the ethylene/α

-olefin interpolymer.

14. A pressure sensitive adhesive consisting essentially of:

(a) from 5 to 95 weight percent of at least one interpolymer, which is a homogeneous ethylene/α

-olefin interpolymer, characterized as having a density from 0.850 to 0.885 g/cm³ and a weight average molecular weight (Mw) of less than 20,000;

(b) from 0 to 95 weight percent of at least one tackifier;

(c) from 0 to about 90 weight percent of at least one plasticizer; and

(d) from 0 to 90 weight percent of at least one wax; and

wherein the sum of components (b), (c), and (d) comprises 5 to 95 weight percent of said adhesive composition, and wherein said adhesive is characterized as having a storage modulus (G′

), at 25°

C., of less than 1×

10⁷ dynes/cm² (1 MPa) and a glass transition temperature (T_g) from −

65°

C. to 30°

C., and

wherein the α

-olefin is randomly distributed within the ethylene/α

-olefin interpolymer.