Single-wall carbon nanotubes from high pressure CO
First Claim
1. A composition of matter comprising single wall carbon nanotubes wherein at least 95% of said single wall carbon nanotubes have a diameter in the range of 0.6 nm to 0.8 nm.
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Abstract
The present invention discloses the process of supplying high pressure (e.g., 30 atmospheres) CO that has been preheated (e.g., to about 1000° C.) and a catalyst precursor gas (e.g., Fe(CO)5) in CO that is kept below the catalyst precursor decomposition temperature to a mixing zone. In this mixing zone, the catalyst precursor is rapidly heated to a temperature that results in (1) precursor decomposition, (2) formation of active catalyst metal atom clusters of the appropriate size, and (3) favorable growth of SWNTs on the catalyst clusters. Preferably a catalyst cluster nucleation agency is employed to enable rapid reaction of the catalyst precursor gas to form many small, active catalyst particles instead of a few large, inactive ones. Such nucleation agencies can include auxiliary metal precursors that cluster more rapidly than the primary catalyst, or through provision of additional energy inputs (e.g., from a pulsed or CW laser) directed precisely at the region where cluster formation is desired. Under these conditions SWNTs nucleate and grow according to the Boudouard reaction. The SWNTs thus formed may be recovered directly or passed through a growth and annealing zone maintained at an elevated temperature (e.g., 1000° C.) in which tubes may continue to grow and coalesce into ropes.
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8 Claims
- 1. A composition of matter comprising single wall carbon nanotubes wherein at least 95% of said single wall carbon nanotubes have a diameter in the range of 0.6 nm to 0.8 nm.
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4. A product made by a process comprising:
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(a) providing a gas stream comprising CO at superatmospheric pressure; (b) providing a gaseous catalyst precursor stream comprising a gaseous catalyst precursor comprising atoms of a transition metal selected from the group consisting of Group VI metals, Group VIII metals and mixtures thereof, said gaseous catalyst precursor stream being provided at a temperature below the decomposition temperature of said catalyst precursor; (c) heating said gas stream comprising CO to a temperature that is at least above the decomposition temperature of said catalyst precursor and is sufficient to form single wall carbon nanotubes; (d) mixing said heated gas stream comprising CO with said gaseous catalyst precursor stream into a reaction mixture in a mixing zone to rapidly heat said catalyst precursor to a temperature that is (i) above the decomposition temperature of said catalyst precursor, (ii) sufficient to promote the formation of catalyst metal atom clusters and (iii) sufficient to promote the initiation and growth of single wall carbon nanotubes; and (e) forming solid products comprising the single wall carbon nanotubes that are in a resulting gaseous stream, wherein at least 99% of atoms of the solid products are atoms of the single wall carbon nanotubes.
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5. A product made by a process comprising:
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(a) providing a gas stream comprising CO at superatmospheric pressure; (b) providing a gaseous catalyst precursor stream comprising a gaseous catalyst precursor comprising atoms of a transition metal selected from the group consisting of Group VI metals, Group VIII metals and mixtures thereof, said gaseous catalyst precursor stream being provided at a temperature below the decomposition temperature of said catalyst precursor; (c) heating said gas stream comprising CO to a temperature that is at least above the decomposition temperature of said catalyst precursor and is sufficient to form single wall carbon nanotubes; (d) mixing said heated gas stream comprising CO with said gaseous catalyst precursor stream into a reaction mixture in a mixing zone to rapidly heat said catalyst precursor to a temperature that is (i) above the decomposition temperature of said catalyst precursor; (ii) sufficient to promote the formation of catalyst metal atom clusters and (iii) sufficient to promote the initiation and growth of single wall carbon nanotubes; and (e) forming solid products comprising the single wall carbon nanotubes that are in a resulting gaseous stream, wherein at least 95% of said single wall carbon nanotubes have a diameter in the range of 0.6 nm to 0.8 nm.
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6. A product made by a process comprising:
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(a) providing a CO gas stream comprising CO, wherein said CO gas stream is at a superatmospheric pressure; (b) providing a gaseous catalyst precursor stream comprising a catalyst precursor; (c) mixing the CO gas stream and the gaseous catalyst precursor stream to form a reaction mixture, wherein said mixing step occurs under reaction conditions to form single wall carbon nanotubes; and (d) reacting said reaction mixture to form carbon products in tubular form, wherein at least 99% atom % of the carbon products in tubular form are single wall carbon nanotubes. - View Dependent Claims (7, 8)
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Specification