Hydrogen/hydrogen peroxide fuel cell

• US 7,241,521 B2
• Filed: 11/17/2004
• Issued: 07/10/2007
• Est. Priority Date: 11/18/2003
• Status: Active Grant

• Current Assignee: George H. Miley, IHJ Holdings Limited
• Original Assignee: NPL Associates, Inc.
• Inventors: Luo, Nie, Miley, George
• Primary Examiner(s): Yuan; Dah-Wei
• Assistant Examiner(s): Parsons; Thomas H.
• Application Number:
  US10/990,695
• Publication Number:
  US 20050136310A1
• Time in Patent Office: 965 Days
• Field of Search: 429/13, 429/17, 429/19, 429/30, 429/33, 429/34, 429/38, 429/40
• US Class Current: 429/421
• CPC Class Codes: B63G 8/08 Propulsion schnorkels B63G8/36; nuclear propulsion B63H21/18; submerged exhausting apparatus F01N13/12
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 2250/20 Fuel cells in motive systems, e.g. vehicle, ship, plane
• CPC Class Codes: H01M 4/8605 Porous electrodes
• CPC Class Codes: H01M 4/9016 Oxides, hydroxides or oxygenated metallic salts
• CPC Class Codes: H01M 4/92 Metals of platinum group H01M4/94 , H01M4/9058 take precedence
• CPC Class Codes: H01M 4/921 Alloys or mixtures with metallic elements
• CPC Class Codes: H01M 8/04029 Heat exchange using liquids
• CPC Class Codes: H01M 8/04186 of liquid-charged or electrolyte-charged reactants
• CPC Class Codes: H01M 8/04216 characterised by the choice for a specific material, e.g. carbon, hydride, absorbent
• CPC Class Codes: H01M 8/04291 Arrangements for managing water in solid electrolyte fuel cell systems H01M8/04119 takes precedence
• CPC Class Codes: H01M 8/186 by electrolytic decomposition of the electrolytic solution or the formed water product
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02T 90/40 Application of hydrogen technology to transportation, e.g. using fuel cells

Abstract

One embodiment of the present invention includes a technique of performing a catalytic oxidation reaction at an anode to provide hydrogen ions from molecular hydrogen and a catalytic reduction reaction at a cathode to provide hydroxyl ions from liquid hydrogen peroxide. Passage of the molecular hydrogen to a reaction region is impeded with a proton exchange membrane and passage of the hydrogen peroxide to the reaction region is impeded with an ion-selective arrangement. Electric potential is generated between the anode and the cathode to provide electric power from a reaction of the hydrogen ions and the hydroxyl ions in the reaction region. In one variation, a regeneration technique is also provided.

Claims

1. An apparatus, comprising:

a first source to supply hydrogen;

a second source to supply hydrogen peroxide;

a fuel cell, including;

an anode subassembly coupled to the first source, the anode subassembly including an anode with a first catalyst and a proton exchange membrane to convert at least a portion of molecular hydrogen from the first source into hydrogen ions, the proton exchange membrane being selective to the passage of hydrogen ions therethrough relative top molecular hydrogen;

a cathode subassembly coupled to the source of hydrogen peroxide, the cathode subassembly including a cathode with a second catalyst and an ion-selective arrangement to convert at least a portion of liquid hydrogen peroxide from the second source into hydroxyl ions, said ion-selective arrangement comprising an ion-selective membrane and a molecular sieve layer, said ion-selective membrane being selective to the passage of hydroxyl ions therethrough relative to hydrogen peroxide molecules; and

a reaction region separating the anode subassembly and the cathode subassembly and being positioned between the proton exchange membrane and the ion selective-arrangement to receive hydrogen ions from the anode subassembly and hydroxyl ions from the cathode subassembly,

wherein the fuel cell is effective to generate an electric potential between the anode and the cathode to provide electrical power by reaction of the hydrogen ions and the hydroxyl ions when in the reaction region.

2. The apparatus of claim 1, wherein said first source comprises a hydrogen gas generator.

3. The apparatus of claim 1, wherein said first source includes at least one hydride.

4. The apparatus of claim 3, wherein said at least one hydride comprises a metallic hydride.

5. The apparatus of claim 1, wherein said anode and/or said cathode comprise a porous, electrically conductive substrate.

6. The apparatus of claim 1, wherein said first catalyst comprises platinum, palladium, or an alloy including platinum and/or palladium.

7. The apparatus of claim 1, wherein said second catalyst comprises iron, palladium or an alloy including iron and/or palladium.

8. The apparatus of claim 1, wherein said second catalyst comprises a metal oxide.

9. The apparatus of claim 1, wherein said molecular sieve layer is positioned between said ion-selective membrane and said cathode.

10. A method, comprising:

performing a catalytic oxidation reaction at an anode to convert molecular hydrogen to hydrogen ions;

performing a catalytic reduction reaction at a cathode to convert liquid hydrogen peroxide to hydroxyl ions;

impeding passage of the molecular hydrogen to a reaction region relative to hydrogen ions with a proton exchange membrane;

impeding passage of the hydrogen peroxide to the reaction region relative to the hydroxyl ions with an ion-selective arrangement; and

generating an electric potential between the anode and the cathode to provide electric power from a reaction of the hydrogen ions and the hydroxyl ions in the reaction region.

11. The method of claim 10, wherein said proton exchange membrane comprises a perfluorinated sulfonic acid polymer.

12. The method of claim 10, wherein said proton exchange membrane comprises an aromatic polyimide polymer.

13. A method, comprising:

performing a catalytic oxidation reaction at an anode to convert a hydride to hydrogen ions;

impeding passage of the hydride to a cathode relative to hydrogen ions with a proton exchange membrane; and

generating an electric potential between the anode and the cathode to provide electric power by a catalytic reduction reaction at the cathode to convert liquid hydrogen peroxide, hydrogen ions, and electrons to water.

14. The method of claim 13, wherein said hydride comprises a metallic hydride.

15. The method of claim 13, wherein said hydride comprises a chemical hydride.

16. The method of claim 13, wherein said proton exchange membrane further impedes passage of liquid hydrogen peroxide to the anode.

17. An apparatus, comprising:

a first source to supply a hydride;

a second source to supply hydrogen peroxide;

a fuel cell, including;

a discharge anode coupled to the first source and a first catalyst to convert at least a portion of the hydride from the first source to hydrogen ions,

a discharge cathode and a second catalyst to convert at least a portion of the hydrogen peroxide from the second source to hydroxyl ions, and

a proton exchange membrane separating the discharge anode and the discharge cathode and being selective to passage of hydrogen ions therethrough relative to the hydride, the hydrogen ions passing through the proton exchange membrane reacting with the hydroxyl ions to provide electrical power to an electrical load when electrically coupled to the discharge anode and the discharge cathode;

a first regeneration electrode coupled to the first source and a third catalyst;

a second regeneration electrode coupled to the second source and a fourth catalyst;

an electrical energy source coupled to the first regeneration electrode and the second regeneration electrode to selectively generate a first electric potential between the first regeneration electrode and the discharge anode and a second electric potential between the second regeneration electrode and the discharge cathode to provide regenerated hydride and regenerated hydrogen peroxide.

18. The apparatus of claim 17, wherein the first regeneration electrode and said proton exchange membrane are separated by the discharge anode.

19. The apparatus of claim 17, wherein said second regeneration electrode and said proton exchange membrane are separated by said discharge cathode.

20. The apparatus of claim 17, wherein at least one of the discharge anode and the discharge cathode comprise a porous, electrically conductive substrate, and the substrate is hydrophilic.

21. The apparatus of claim 17, wherein at least one of the discharge anode and the discharge cathode comprise an ion-conducting polymer.

22. The apparatus of claim 17, wherein the first catalyst includes a platinum alloy or essentially comprises platinum, and the second catalyst consists of at least one of iron, an iron alloy, palladium, a palladium alloy, and an alloy including iron and palladium.

23. The apparatus of claim 17, wherein said proton exchange membrane further comprises a molecular sieve structure to provide at least a partial barrier to hydrogen peroxide.

24. The apparatus of claim 17, wherein the third catalyst comprises indium.

25. The apparatus of claim 17, wherein the fourth catalyst comprises platinum or glassy carbon.

26. The apparatus of claim 17, further comprising:

means for regulating the amount of hydride supplied to the discharge anode from the first source; and

means for recycling water generated at the discharge cathode for supply to the discharge anode.

27. The apparatus of claim 17, further comprising a spacecraft or a submersible underwater vehicle carrying the first source, the second source, and the fuel cell.

28. The apparatus of claim 17, further comprising a first plate with groove to receive an aqueous solution including at least part of the hydride, and a second plate includes grooves to receive a flow of at least part of the hydrogen peroxide, the first plate and the second plate being positioned opposite one another.

29. A method, comprising:

(a) discharging electricity from a fuel cell by;

performing a first catalytic oxidation reaction with a discharge anode of the fuel cell to generate hydrogen ions from a source material,

passing at least a portion of the hydrogen ions through a proton exchange membrane of the fuel cell, and

performing a first catalytic reduction reaction with a discharge cathode of the fuel cell to generate hydroxyl ions from hydrogen peroxide, the hydrogen ions and the hydroxyl ions reacting to generate an electric potential between the discharge anode and the discharge cathode to provide the electricity; and

(b) recharging the fuel cell with an electric power source by;

performing a second catalytic reduction reaction at a first regeneration electrode with the electric power source to provide regenerated source material, and

performing a second catalytic oxidation reaction at a second regeneration electrode with the electric power source to provide regenerated hydrogen peroxide.

30. The method of claim 29, wherein at least one of the discharge anode and the discharge cathode comprise a porous, electrically conductive substrate.

31. The method of claim 29, wherein the hydride comprises a metallic hydride.

32. The method of claim 29, which includes at least partially powering at least one of an underwater submersible vehicle and a space craft with the electricity.

33. The method of claim 29, which includes performing the discharging after the recharging.

34. The method of claim 29, wherein performing the second catalytic reduction reaction includes establishing a first electric potential between the discharge anode and the first regeneration electrode.

35. The method of claim 34, wherein performing the second catalytic oxidation reaction includes establishing a second electric potential between the discharge cathode and the second regeneration electrode.

36. The method of claim 29, wherein the third catalyst comprises indium.

37. The method of claim 29, wherein the fourth catalyst comprises platinum or glassy carbon.