Spectrometer system for optical reflectance measurements

• US 7,245,373 B2
• Filed: 04/25/2005
• Issued: 07/17/2007
• Est. Priority Date: 04/26/2004
• Status: Active Grant

• Current Assignee: Reflectance Medical Inc. (Foxconn Technology Co., Ltd.), Nirstat, LLC, University Of Massachusetts
• Original Assignee: Nirstat, LLC, University Of Massachusetts
• Inventors: Soller, Babs R., Parker, Michael S., Phillipps, Patrick G.
• Primary Examiner(s): EVANS, FANNIE L
• Application Number:
  US11/113,347
• Publication Number:
  US 20050259254A1
• Time in Patent Office: 813 Days
• Field of Search: 356/323, 356/325, 356/326, 356/328
• US Class Current: 356/325
• CPC Class Codes: G01J 3/0218 using optical fibers
• CPC Class Codes: G01J 3/0229 using masks, aperture plates, spatial light modulators or spatial filters, e.g. reflective filters
• CPC Class Codes: G01J 3/0232 using shutters
• CPC Class Codes: G01J 3/08 Beam switching arrangements
• CPC Class Codes: G01J 3/10 Arrangements of light sources specially adapted for spectrometry or colorimetry
• CPC Class Codes: G01J 3/108 for measurement in the infrared range
• CPC Class Codes: G01N 21/274 Calibration, base line adjustment, drift correction
• CPC Class Codes: G01N 21/35 using infrared light G01N21/39 takes precedence
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 21/3563 for analysing solids; Preparation of samples therefor
• CPC Class Codes: G01N 21/3577 for analysing liquids, e.g. polluted water
• CPC Class Codes: G01N 21/49 within a body or fluid
• CPC Class Codes: G01N 2201/08 Optical fibres; light guides

Abstract

A spectrometer system includes a thermal light source for illuminating a sample, where the thermal light source includes a filament that emits light when heated. The system additionally includes a spectrograph for measuring a light spectrum from the sample and an electrical circuit for supplying electrical current to the filament to heat the filament and for controlling a resistance of the filament. The electrical circuit includes a power supply that supplies current to the filament, first electrical components that sense a current through the filament, second electrical components that sense a voltage drop across the filament, third electrical components that compare a ratio of the sensed voltage drop and the sensed current with a predetermined value, and fourth electrical components that control the current through the filament or the voltage drop across the filament to cause the ratio to equal substantially the predetermined value.

Claims

1. A spectrometer system comprising:

a thermal light source for illuminating a sample, wherein the thermal light source comprises a filament that emits light when heated;

a spectrograph for measuring a light spectrum from the sample;

an electrical circuit for supplying electrical current to the filament to heat the filament and for controlling a resistance of the filament, the electrical circuit comprising;

a power supply that supplies current to the filament;

first electrical components that sense a current through the filament;

second electrical components that sense a voltage drop across the filament;

third electrical components that compare a ratio of the sensed voltage drop and the sensed current with a predetermined value; and

fourth electrical components that control the current through the filament or the voltage drop across the filament to cause the ratio to equal substantially the predetermined value.

2. The system of claim 1, wherein the first electrical components comprise a sense resistor, wherein a voltage across the sense resistor is proportional to the current through the filament.

3. The system of claim 1, wherein the second electrical components comprise a differential amplifier that generates a signal proportional to a voltage drop across the filament.

4. The system of claim 1, wherein the third electrical components comprise a differential amplifier that compares a signal indicative of a current through the filament with a signal indicative of a voltage drop across the filament.

5. The system of claim 4, further comprising a voltage divider that multiples a ratio between the signal indicative of the current through the filament and the signal indicative of the voltage drop across the filament by a conversion factor.

6. The system of claim 1, wherein the fourth electrical components comprise a transistor adapted for driving the filament with a current to ensure a substantially constant filament temperature.

7. The system of claim 1, further comprising fifth electrical components that gradually ramp up the current supplied to the filament when the power to the filament is turned on.

8. The system of claim 7, wherein the fifth electrical components comprise a low pass filter.

9. The system of claim 7, further comprising sixth electrical components that limit the current supplied to the filament below a maximum value.

10. A method of controlling a spectrum of light emitted from a heated filament, the method comprising:

supplying electrical current from a power supply to heat the filament;

sensing a current flowing through the filament;

sensing a voltage drop across the filament;

comparing a ratio of the sensed voltage drop and the sensed current with a predetermined value; and

controlling the current or the voltage drop to cause the ratio to equal the predetermined value.

11. The method of claim 10, further comprising compensating for a temperature-dependent change in a resistance of electrical connectors that supply current to the filament by introducing an additional temperature-dependent change in an electrical connection between the power supply and the filament.

12. The method of claim 10, further comprising driving the filament with a current controlled to ensure a substantially constant filament temperature.

13. The method of claim 10, further comprising gradually ramping up the current supplied to the filament when the power to the filament is turned on.

14. The method of claim 10, further comprising:

shining the light on a sample;

collecting light scattered from the sample;

analyzing the collected light in a spectrograph to measure properties of the sample; and

outputting one or more of the measured properties from the spectrograph.

15. A spectrometer system comprising:

a light source;

a spectrograph;

an first optical beam path for guiding light from the light source to a sample;

a second optical beam path for guiding light from the light source to the spectrograph;

a third optical beam path for guiding light reflected from the sample to the spectrograph;

a shutter for blocking and unblocking the light in the first beam path from the sample and for blocking and unblocking light in the second beam path from the spectrograph; and

a processor adapted for analyzing light spectra from light guided into the spectrograph and adapted for correcting the spectra for a dark current in the system based on spectra recorded when both the first and second optical beam paths are blocked and adapted for correcting the spectra for temporal changes in the spectrum of the light source based on a plurality of spectra recorded at different times when light is guided into the spectrograph along the second beam path.

16. The spectrometer system of claim 15, wherein the first optical beam path comprises a first optical fiber and the second optical beam path comprises a second optical fiber that is optically shielded from the first optical fiber.

17. The spectrometer system of claim 15, further comprising:

a memory adapted for storing an initial lamp spectrum and a later lamp spectrum recorded from light guided to the spectrograph through the second beam path, wherein the later lamp spectrum is recorded at a time later than the initial lamp spectrum, and adapted for storing an initial reference spectrum recorded from light guided through the first optical beam path to a reference sample, scattered by the reference sample having a known reflectance spectrum, and guided to the spectrograph from the sample through the third optical beam path, and

wherein the processor is further adapted for correcting a spectrum of light that has been guided to a test sample from the light source and scattered from the sample to the spectrograph, wherein the correction is based on the initial lamp spectrum, the later lamp spectrum, and the initial reference spectrum.

18. The spectrometer system of claim 15, wherein the light source comprises a filament that emits light when heated, and wherein the spectrometer system further comprises an electrical circuit for supplying electrical current to the filament to heat the filament and for controlling a resistance of the filament, the electrical circuit comprising:

a power supply that supplies current to the filament;

first electrical components that sense a current through the filament;

second electrical components that sense a voltage drop across the filament;

third electrical components that compare a ratio of the sensed voltage drop and the sensed current with a predetermined value; and

fourth electrical components that control the current through the filament or the voltage drop across the filament to cause the ratio to equal substantially the predetermined value.

19. The spectrometer system of claim 18, wherein the fourth electrical components are adapted for driving the filament with a current controlled to ensure a substantially constant filament temperature.

20. A method for correcting a spectrum measured by a spectrometer system having a spectrograph and a light source for illuminating a sample with light output from the light source, the method comprising:

recording a reference spectrum, Ro(λ

), from a reference sample having a known reflectivity spectrum when light from the light source is shined on the reference sample;

recording an initial lamp spectrum, Lo(λ

), of the light output from the light source at an initial time when light from the light source is shined into the spectrograph;

recording a subsequent lamp spectrum, Lt(λ

), of the light output from the light source at a time later than the initial time when light from the light source is shined into the spectrograph;

recording a spectrum from a test sample, S(λ

);

correcting the spectrum from the test sample using data from the reference spectrum, the initial lamp spectrum, and the subsequent lamp spectrum, to produce a corrected spectrum; and

outputting the corrected spectrum.

21. The method of claim 20, wherein the reference sample reflects approximately 100% of light directed at the reference sample over a predetermined wavelength range.

22. The method of claim 20, wherein correcting the spectrum includes multiplying the spectrum, S(λ

), by Ro(λ

)* (Lt(λ

)/Lo(λ

)).

23. The method of claim 20, wherein light from the light source is directed toward the reference sample, the test sample, or the spectrograph depending on a position of a shutter that is adapted to selectively block light from reaching the reference sample, the test sample, or the test sample.

24. The method of claim 23, wherein the position of the shutter can be changed by rotating the shutter about an axis.