Soft, flexible composition and method for making same

• US 7,250,129 B2
• Filed: 04/30/2004
• Issued: 07/31/2007
• Est. Priority Date: 05/22/1995
• Status: Expired due to Fees

• Current Assignee: Playtex Products Incorporated (Edgewell Personal Care Company)
• Original Assignee: Playtex Products Incorporated (Edgewell Personal Care Company)
• Inventors: Williams, Karla E, Zwick, Paul D
• Primary Examiner(s): Heitbrink; Jill L.
• Application Number:
  US10/836,309
• Publication Number:
  US 20050070645A1
• Time in Patent Office: 1,187 Days
• Field of Search: 264/328.17, 264/330
• US Class Current: 264/328.17
• CPC Class Codes: A61F 13/26 Means for inserting tampons , i.e. applicators
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes

Abstract

There is provided a composition comprising a unique polymeric compound that provides a soft, flexible product. There is also provided a unique polymeric tampon applicator that is soft and flexible. When used as a tampon applicator barrel, the barrel is more comfortable and has improved ease of insertion. The polymeric compound primarily comprises a thermoplastic resin and a block copolymer that exhibit unique load, energy and modulus of elasticity properties. The polymeric compound should also include a plasticizer and a compatibilizer/flow modifier, and may include a slip/mold release agent, an antioxidant, and even a pigment. There is also provided a method for making the polymeric compound that will be formed into a product, such as an applicator or applicator barrel in which all of the above ingredients, except for the thermoplastic resin, are combined and formed into soft pellets. The soft resin pellets are then dry blended with pellets of the thermoplastic resin. The mixture of the thermoplastic resin pellets and the soft resin pellets are then melted and injection molded into the desired shape. There is thus provided a method of making a soft, polymeric tampon applicator or tampon applicator barrel.

Claims

1. A method for making a tampon applicator barrel having a soft, flexible supporting structure comprising the steps of:

providing an elastomeric composition with at least two styrene-butadiene-styrene block copolymers;

melting said elastomeric composition thereby forming a melted resin;

extruding said melted resin into a plurality of soft pellets;

dry blending said plurality of soft pellets with a plurality of pellets comprising low density polyethylene to form a pellet mixture;

melting said pellet mixture to form a polymeric compound; and

molding said polymeric compound to a desired shape to form the tampon applicator barrel.

2. The method of claim 1, wherein said at least two styrene-butadiene-styrene block copolymers is at least three styrene-butadiene-styrene block copolymers.

3. The method of claim 1, wherein said at least two styrene-butadiene-styrene block copolymers each have a different percentage by weight of styrene present in amounts sufficient to adjust an elasticity of said composition.

4. The method of claim 2, wherein said at least three styrene-butadiene-styrene block copolymers each have a different percentage by weight of styrene present in amounts sufficient to adjust an elasticity of said composition.

5. The method of claim 1, wherein said elastomeric composition further comprises one or more compounds selected from the group consisting of plasticizer, compatibilizer/flow modifier, slip/mold release agent, antioxidant, and any combinations thereof.

6. The method of claim 2, wherein at least one of said at least three styrene-butadiene-styrene block copolymers has about 29 wt. % styrene.

7. The method of claim 2, wherein at least one of said at least three styrene-butadiene-styrene block copolymers has about 31 wt. % styrene.

8. The method of claim 2, wherein at least one of said at least three styrene-butadiene-styrene block copolymers has about 43 wt. % styrene.

9. The method of claim 2, wherein said at least three styrene-butadiene-styrene block copolymers has a first styrene-butadiene-styrene block copolymer with about 29 wt. % styrene, a second styrene-butadiene-styrene block copolymer with about 31 wt. % styrene, and a third styrene-butadiene-styrene block copolymer with about 43 wt. % styrene.

10. The method of claim 1, wherein said at least two styrene-butadiene-styrene block copolymers are present in an amount about 16.5 wt. % to about 49.8 wt. %, based on the total weight of the composition.

11. The method of claim 1, wherein said low density polyethylene is present in an amount about 25 wt. % to about 75 wt. %, based on the total weight of the composition.

12. The method of claim 5, wherein said compatibilizer/flow modifier is an ethylene copolymer.

13. The method of claim 5, wherein said compatibilizer/flow modifier is ethylene methyl acrylate.

14. The method of claim 5, wherein said compatibilizer/flow modifier is present in an amount about 2.9 wt. % to about 8.6 wt. %, based on the total weight of the composition.

15. The method of claim 5, wherein said plasticizer is mineral oil.

16. The method of claim 5, wherein said plasticizer is present in an amount about 5 wt. % to about 15 wt. %, based on the total weight of the composition.

17. The method of claim 5, wherein said slip/mold release agent is stearyl erucamide.

18. The method of claim 5, wherein said antioxidant is selected from the group consisting of tetrakis [methylene(3,5-di-tert-butyl-4-hydroxyhydrocinnamate)] methane, tris(2,4-di-tert-butyl phenyl) phosphite, and any combinations thereof.

19. The method of claim 5, wherein said antioxidant is present in an amount about 0.05 wt. % to about 0.15 wt. %, based on the total weight of the composition.