System and method for dissolving gases in liquids

• US 7,255,332 B2
• Filed: 05/25/2005
• Issued: 08/14/2007
• Est. Priority Date: 05/25/2004
• Status: Active Grant

• Current Assignee: The Board of Trustees of the University of Arkansas (University of Arkansas System)
• Original Assignee: The Board of Trustees of the University of Arkansas (University of Arkansas System)
• Inventors: Osborn, Gregory Scott, Matlock, Marty D., Teltschik, Shandi S.
• Primary Examiner(s): BUSHEY, CHARLES S
• Application Number:
  US11/137,856
• Publication Number:
  US 20050279713A1
• Time in Patent Office: 811 Days
• Field of Search: 261/28, 261/37, 261/77, 261/78.2, 261/115, 261/119.1, 261/124, 261/122.1, 210/221.2, 210/760
• US Class Current: 261/28
• CPC Class Codes: B01F 23/23 by introducing gases into liquid media, e.g. for producing aerated liquids
• CPC Class Codes: B01F 23/234 Surface aerating
• CPC Class Codes: B01F 23/237611 Air
• CPC Class Codes: B01F 23/454 by injecting a mixture of liquid and gas
• CPC Class Codes: B01F 25/31331 Perforated, multi-opening, with a plurality of holes
• CPC Class Codes: B01F 25/32 wherein the additional components are added in a by-pass of the main flow
• CPC Class Codes: C02F 1/70 by reduction C02F1/4676 takes precedence
• CPC Class Codes: C02F 1/72 by oxidation C02F1/4672 takes precedence
• CPC Class Codes: C02F 1/727 using pure oxygen or oxygen rich gas
• CPC Class Codes: C02F 1/74 with air aeration of stretches of water C02F7/00
• CPC Class Codes: C02F 1/763 Devices for the addition of such compounds in gaseous form
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 2101/305 Endocrine disruptive agents
• CPC Class Codes: C02F 2101/306 Pesticides
• CPC Class Codes: C02F 2103/007 Contaminated open waterways, rivers, lakes or ponds
• CPC Class Codes: C02F 2103/343 from the pharmaceutical industry, e.g. containing antibiotics
• CPC Class Codes: C02F 2209/02 Temperature
• CPC Class Codes: C02F 2209/22 O2
• CPC Class Codes: C02F 2303/04 Disinfection
• CPC Class Codes: C02F 7/00 Aeration of stretches of water
• CPC Class Codes: Y02W 10/10 : Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y02W 10/37 : using solar energy

Abstract

Apparatus and methods for dissolving a gas into a liquid comprises a saturation tank, a high pressure liquid pump in fluid communication with the tank, and a pressurized gas source in communication with a regulated gas head space of the saturation tank. The saturation tank comprises a pressure vessel for containing the liquid and has a regulated gas head space above the liquid, contains at least one liquid spray nozzle that permits passage of liquid into the pressure vessel, and an outlet for the liquid containing dissolved gas. Upon passing the gas-containing liquid into a second fluid, the gas is released in the form of microbubbles. The microbubbles aid in flocculation of suspended particles and promote dissolution of the gas in the second fluid. Preferred gases for use with the apparatus are oxygen, air, and ozone. Anticipated uses include treatment of rivers, streams, and ponds in natural or industrial settings, as well as smaller scale applications.

Claims

1. A method of dissolving a gas in a liquid comprising:

(a) pressurizing an enclosed vessel with the gas, wherein the gas enters the vessel at near ambient pressure and is pressurized via a closed system injection of liquid until a desired higher pressure is attained therein;

(b) spraying a first portion of the liquid into the vessel containing the gas under conditions effective to dissolve the gas in the liquid;

(c) passing the first portion of liquid containing dissolved gas from the vessel into a chamber that is provided with a plurality of orifices and which is immersed in a second portion of the liquid; and

(d) discharging the first liquid portion containing dissolved gas through the chamber orifices into the second liquid portion.

2. The method of claim 1, wherein said pressurizing is conducted with a gas selected from the group consisting of air, oxygen, ozone, hydrogen, nitrogen, nitrous oxide, and carbon dioxide.

3. The method of claim 1, wherein said spraying is performed with a liquid primarily, comprising water.

4. The method of claim 1, wherein said spraying is performed until the first portion of liquid is dissolved with gas to 95% of saturation at the enclosed vessel pressure.

5. The method of claim 1, wherein the gas is separated on-site from ambient air prior to being pressurized into the vessel.

6. The method of claim 1, wherein said pressurizing is conducted with ozone gas.

7. The method of claim 1, wherein the gas is provided by on-site generation.

8. The method of claim 1, wherein the liquid is provided by a water tap located in a residence or industrial site and liquid is transferred into the vessel under tap pressure.

9. The method of claim 1, which is performed in continuous mode.

10. The method of claim 1, wherein the liquid is sprayed into the vessel under pressure provided by a high pressure liquid pump.

11. The method of claim 1, wherein fluid flow into the vessel from a high pressure pump is controlled via feedback from sensors indicating water capacity within the saturation tank.

12. The method of claim 1, wherein said discharging of liquid containing dissolved gas is effective to:

(i) enhance microbe growth and respiration rate in waste water treatment, fermentation processes, food synthesis and manufacturing, or solid waste treatment;

(ii) promote physical flotation of matter suspended in the liquid;

(iii) quench anaerobic biological activity in the liquid;

(iv) produce nanobubbles (10-100 nm diameter);

(v) foam a polymer;

(vi) create a biorefuge for attracting or sustaining fish populations;

(vii) sterilize a body of water;

(viii) facilitate surface freezing while aerating/oxygenating during cold weather;

(ix) to control odor, antibiotic residuals, and/or bacterial loads in sewage transport conduits;

(x) improve the quality of water entering, transducing, or exiting a dam;

(xi) improving aerobic digestion efficiency and/or odor control in a wastewater treatment pond (lagoon);

(xii) respond to a pollutant spill into an environmental water body;

(xiii) isolate and/or treat a plume of pollution;

(xiv) disinfect and reduce organic carbon in drinking water;

(xv) control aerobic and anaerobic conditions in biological processes associated with pharmaceuticals and biotechnology;

(xvi) deliver hydrogen or other gases to create and control aerobic and anaerobic conditions in biological processes associated with in situ waste treatment in groundwater;

(xvii) deliver hydrogen or other gases to create and control aerobic and anaerobic conditions in biological processes associated with in situ waste treatment in surface waters;

(xviii) deliver a high concentration of dissolved oxygen to enhance biological oxidation of organic carbon and nitrogen removal within wastewater treatment facilities;

(xix) oxidize sediment in situ for enhanced bioremediation of contaminants sorbed to and associated with river, lake, and estuarine sediments;

(xx) enhance oxygen treatment of refractory pollutants such as antibiotic residuals, endocrine disruptors, pesticides, and similar chemicals;

(xxi) enhance ozone treatment of refractory pollutants such as antibiotic residuals, endocrine disruptors, pesticides, and similar chemicals;

(xxii) inject supersaturated stream of oxygen, ozone, hydrogen or other gases for direct treatment or enhancing treatment of groundwater to remove pollutants;

(xxiii) increase the rate of BOD removal because of improved treatment rate from smaller bubble size;

or (xxiv) increase the thickness of the aerobic layer in sediment for increase storage capacity of phosphorus or other water pollutants.