Dental mill blanks

• US 7,255,562 B2
• Filed: 12/21/2001
• Issued: 08/14/2007
• Est. Priority Date: 01/08/1999
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Carufel, Roger J., Cummings, Kevin M., Rusin, Richard P.
• Primary Examiner(s): Lewis; Ralph A.
• Application Number:
  US10/027,278
• Publication Number:
  US 20020090525A1
• Time in Patent Office: 2,062 Days
• Field of Search: 433/212.1, 433/213, 433/223
• US Class Current: 433/223
• CPC Class Codes: A61C 13/0022 Blanks or green, unfinished dental restoration parts
• CPC Class Codes: A61K 6/887 Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: A61K 6/891 Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: A61K 6/893 Polyurethanes
• CPC Class Codes: C08L 33/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C08L 75/16 having terminal carbon-to-carbon unsaturated bonds

Abstract

A dental mill blank comprising a resin and a filler, wherein the blank is fabricated such that it passes a Thermal Shock Test. The mill blank is substantially free of cracks and discontinuities. Further, the blank may have superior cuttability and hardness.

Claims

1. A method of making a dental mill blank suitable for the oral environment comprising:

mixing a paste comprising a resin and a filler,

adding a fluoride releasing material to the pastes,

shaping the paste into a desired configuration,

minimizing material discontinuities from the paste,

curing the paste into a blank, and

heating the blank to a temperature at or above the Tg of the resin for a time sufficient to relieve internal stresses in the blank, wherein the cured mill blank, when immersed in liquid nitrogen for about two minutes, does not explode and no cracks are observed upon visual inspection.

2. A method of making a dental prosthetic comprising:

mixing a paste comprising a resin and a filler,

shaping the paste into a desired blank configuration,

minimizing material discontinuities from the paste,

curing the paste into a blank,

heating the blank to a temperature at or above the Tg of the resin for a time sufficient to relieve internal stresses in the blank, and

carving the blank into a desired shape and morphology, wherein the blank is substantially free of cracks and when immersed in liquid nitrogen for about two minutes, does not explode and no cracks are observed upon visual inspection.

3. The method of claim 2 wherein the heating comprises heating the blank in an oven, and wherein the oven temperature is increased at a rate of no more than about 5°

C. per minute.

4. The method of claim 2 further comprising adding additional material to the carved blank.

5. The method of claim 2 further comprising attaching the carved blank to tooth or bone structure.

6. The method of claim 2 further comprising:

manually changing the morphology of the carved blank, and

finishing the outer surface of the carved blank.

7. The method of claim 2 further comprising attaching a handle to the cured paste after curing and before carving, wherein the carving is performed by a milling machine.

8. The method of claim 2 wherein the carving is performed by a hand-held instrument.

9. The method of claim 2 further comprising adding a fluoride releasing material to the paste.

10. The method of claim 2 wherein the resin is made from a material comprising a free radically curable monomer, oligomer, or polymer.

11. The method of claim 10 wherein the material is selected from the group consisting of 2,2-bis[4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl]propane (bisGMA), triethyleneglycol dimethacrylate (TEGDMA), 2,2-bis[4-(2-methacryloyloxyethoxy)-phenyl]propane (bisEMA), 2-hydroxy ethyl methacrylate (HEMA), urethane dimethacrylate (UDMA), and any combinations thereof.

12. The method of claim 2 wherein the resin is made from a material comprising a cationically curable monomer, oligomer, or polymer.

13. The method of claim 12 wherein the material is selected from the group consisting of diglycidyl ether of bisphenol A, 3,4-epoxycyclohexylmethyl-3-4-epoxy cyclohexene carboxylate, bisphenol F epoxides, and polytetrahydrofuran.

14. The method of claim 2 wherein the resin is made from a material comprising a free radically curable monomer, oligomer, or polymer and a cationically curable monomer, oligomer, or polymer.

15. The method of claim 2 wherein the resin is made from a material comprising a monomer, oligomer, or polymer comprising both a free radically curable functionality and a cationically curable functionality.

16. The method of claim 2 wherein the filler is selected from the group consisting of barium glass, quartz, and zirconia-silica.

17. The method of claim 2 wherein the filler is derived from a sol-gel process.

18. The method of claim 2 wherein the blank is capable of being further hardened by an additional curing process.

19. The method of claim 2 wherein shaping the paste is performed using a mold, the method further comprising:

trimming excess paste material from the mold, and

removing the cured paste from the mold.

20. The method of claim 2 wherein curing comprises a system selected from the group consisting of heat, light, microwave, e-beam, and chemical cure.

21. The method of claim 2 wherein the filler is at least about 50% by weight of the total weight of the mill blank.

22. The method of claim 2 wherein the filler is at least about 65% by weight of the total weight of the mill blank.

23. The method of claim 2 wherein the filler is at least about 80% by weight of the total weight of the mill blank.