Tungsten oxide/titanium dioxide photocatalyst for improving indoor air quality

• US 7,255,831 B2
• Filed: 05/30/2003
• Issued: 08/14/2007
• Est. Priority Date: 05/30/2003
• Status: Expired due to Fees

• Current Assignee: Carrier Corporation (Carrier Global Corporation)
• Original Assignee: Carrier Corporation (Carrier Global Corporation)
• Inventors: Hay, Stephen O., Vanderspurt, Thomas H., Obee, Timothy N., Schmidt, Wayde R., Sangiovanni, Joseph J., Wei, Di
• Primary Examiner(s): JASTRZAB, KRISANNE MARIE
• Application Number:
  US10/449,752
• Publication Number:
  US 20040241040A1
• Time in Patent Office: 1,537 Days
• Field of Search: 422/24, 422/186.3, 204/158.2, 313/112, 313/573
• US Class Current: 422/4
• CPC Class Codes: B01D 2255/802 Photocatalytic
• CPC Class Codes: B01D 53/8668 Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
• CPC Class Codes: B01D 53/885 Devices in general for catalytic purification of waste gases
• CPC Class Codes: B01J 21/063 Titanium; Oxides or hydroxides thereof
• CPC Class Codes: B01J 23/6527 Tungsten
• CPC Class Codes: B01J 35/39 Photocatalytic properties
• CPC Class Codes: B01J 35/56 Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
• CPC Class Codes: B01J 37/0215 Coating
• CPC Class Codes: B01J 37/0244 Coatings comprising several layers

Abstract

A tungsten oxide/titanium dioxide photocatalyst coating oxidizes contaminants in the air that adsorb onto the coating into water, carbon dioxide, and other substances. The tungsten oxide forms a monolayer on the titanium dioxide. When photons of the ultraviolet light are absorbed by the tungsten oxide/titanium dioxide photocatalyst coating, an electron is promoted from the valence band to the conduction band, producing a hole in the valence band. The holes in the valence band react with water applied on the tungsten oxide/titanium dioxide photocatalyst coating, forming reactive hydroxyl radicals. When a contaminant in the air is adsorbed onto the tungsten oxide/titanium dioxide photocatalyst, the hydroxyl radical attacks the contaminant, abstracting a hydrogen atom from the contaminant. The hydroxyl radical oxidizes the contaminant, producing water, carbon dioxide, and other substances. The tungsten oxide/titanium dioxide photocatalytic coating has low sensitivity to humidity variations.

Claims

1. An air purification system comprising:

a substrate;

a metal oxide/titanium dioxide photocatalytic coating including a monolayer of tungsten oxide on titanium dioxide, the monolayer of tungsten oxide having a thickness no greater than one molecular unit, and said photocatalytic coating is applied on said substrate; and

a light source to activate said tungsten oxide/titanium dioxide photocatalytic coating, and said tungsten oxide/titanium dioxide photocatalytic coating oxidizes contaminants in an air flow that are adsorbed onto said tungsten oxide/titanium dioxide photocatalytic coating when activated by said light source.

2. The air purification system as recited in claim 1 wherein said substrate is an array of voids separated by a solid.

3. The air purification system as recited in claim 2 wherein said substrate is one of aluminum and an aluminum alloy.

4. The air purification system as recited in claim 2 further including a plurality of substrates and a plurality of ultraviolet light sources, and said plurality of substrates and said plurality of ultraviolet light sources alternate.

5. The air purification system as recited in claim 1, further including a particle filter to block dust in said air flow.

6. The air purification system as recited in claim 1 further including a fan that draws said air flow into said air purification system.

7. The air purification system as recited in claim 1 further including a housing, the coated substrate and light source are in said housing, and said housing is lined with a reflective material.

8. The air purification system as recited in claim 1 wherein said light source is an ultraviolet light source.

9. The air purification system as recited in claim 8 wherein said ultraviolet light source generates light in the range of 180 nanometers to 400 nanometers.

10. The air purification system as recited in claim 1 wherein said coating has a loading between 0.01 mg/cm² and 1.7 mg/cm².

11. The air purification system as recited in claim 1, further comprising a HVAC system that includes said substrate, said metal oxide/titanium dioxide photocatalytic coating, and said light source.

12. The air purification system as recited in claim 1 wherein titanium dioxide of said tungsten oxide/titanium dioxide photocatalytic coating contains a rutile crystal phase.

13. The air purification system as recited in claim 1 wherein said monolayer of tungsten oxide entirely covers said titanium dioxide.

23. The air purification system as recited in claim 1 wherein said monolayer of tungsten oxide comprises less than 6 mol % of said photocatalytic coating.

24. The air purification system as recited in claim 1 wherein said metal oxide/titanium dioxide photocatalytic coating comprises a pH about 1.7.

25. The air purification system as recited in claim 1 wherein said monolayer of tungsten oxide on titanium dioxide is a reaction product of ammonium paratungstate and titanium dioxide.

26. The air purification system as recited in claim 1 wherein said titanium dioxide comprises approximately 20% of the rutile crystal phase and approximately 80% of the anatase crystal phase.

27. The air purification system as recited in claim 1 wherein said coating has a loading between 0.5 mg/cm² and 1.0 mg/cm².

14. An air purification system comprising:

a substrate;

a metal oxide/titanium dioxide photocatalytic coating including monolayer tungsten oxide on titanium dioxide, and said photocatalytic coating is applied on said substrate, wherein said monolayer of tungsten oxide partially covers said titanium dioxide; and

a light source to activate said tungsten oxide/titanium dioxide photocatalytic coating, and said tungsten oxide/titanium dioxide photocatalytic coating oxidizes contaminants in an air flow that are adsorbed onto said tungsten oxide/titanium dioxide photocatalytic coating when activated by said light source.

15. An air purification system comprising:

a container having an inlet and an outlet;

a porous substrate inside said container;

a device for drawing a fluid into said container through said inlet, flowing said fluid through said porous substrate, and expelling said fluid out of said container through said outlet;

a tungsten oxide/titanium dioxide photocatalytic coating including a monolayer of tungsten oxide on titanium dioxide, the monolayer of tungsten oxide having a thickness no greater than one molecular unit, and said tungsten oxide/titanium dioxide photocatalytic coating is applied on said porous substrate; and

an ultraviolet light source to activate said photocatalytic coating, and photons from said ultraviolet light source are absorbed by said tungsten oxide/titanium dioxide photocatalytic coating to form a reactive hydroxyl radical, and said reactive hydroxyl radical oxidizes contaminants in said fluid that are adsorbed onto said tungsten oxide/titanium dioxide photocatalytic coating when activated by said light ultraviolet light source to water and carbon dioxide in the presence of water and oxygen.

16. A method of purifying air comprising the steps of;

applying a monolayer of tungsten oxide on titanium dioxide to produce a photocatalytic coating on a substrate, the monolayer of tungsten oxide having a thickness no greater than one molecular unit;

activating said tungsten oxide/titanium dioxide photocatalytic coating;

forming a reactive hydroxyl radical;

adsorbing contaminants in an air flow onto said tungsten oxide/titanium dioxide photocatalytic coating; and

oxidizing said contaminants with said hydroxyl radical.

17. The method as recited in claim 16 wherein said contaminants are at least one of an oxidizable species and a reducible species.

18. The method as recited in claim 16 wherein said oxidizable species is carbon monoxide and said reducible species is ozone.

19. The method as recited in claim 17 wherein said contaminants are at least one of toluene, propanal, butene, acetaldehyde, and mixtures thereof.

20. The method as recited in claim 17 wherein said contaminants are one of volatile organic compounds and semi-volatile organic including at least one of aldehyde, ketone, alcohol, aromatic, alkene, and alkane.

21. The method as recited in claim 16 wherein said step of activating said photocatalytic coating includes illuminating an ultraviolet light source.

22. The method as recited in claim 16 wherein the step of oxidizing said contaminants includes oxidizing said contaminants to water and carbon dioxide.