Composite particle with a carbodiimide resin layer and a process for producing the same
First Claim
1. A composite particle made from a base particle (A) and a carbodiimide resin (B), whereinsaid base particle (A) has a functional group reactable with a carbodiimide group and said carbodiimide resin (B) contains a carbodiimide group andsaid base particle (A) and said carbodiimide resin (B) are bonded together by the functional group of the base particle (A) and the carbodiimide group of the carbodiimide resin (B) to form a shell layer comprised of the carbodiimide resin (B) having average thickness diameter (L), represented by the following numerical equation [1], in the range of 0.01 to 20 μ
- m;
L=(L2−
L1)/2
[1]wherein L1 represents average particle diameter of the base particle and L2 represents average particle diameter of the composite particle.
1 Assignment
0 Petitions
Accused Products
Abstract
A composite particle that can be easily converted to cured particle or half cured particle by the use of carbodiimide resin without changing of the configuration of matrix particle of, for example a thermoplastic resin, excelling in mechanical and functional characteristics by virtue of the reaction capability inherently possessed by a carbodiimide group. In particular, a composite particle comprising matrix particle (A) having a functional group capable of reacting with a carbodiimide group and carbodiimide resin (B), characterized in that the functional group of the matrix particle (A) couples with the carbodiimide group of the carbodiimide resin (B) and that the composite particle is provided with an outer shell layer of carbodiimide resin (B) having an average thickness diameter (L), defined by the following formula [1], ranging from 0.01 to 20 μm: L=(L2−L1)/2 [1] wherein L1 represents the average diameter of matrix particle, and L2 represents the average diameter of composite particle.
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Citations
11 Claims
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1. A composite particle made from a base particle (A) and a carbodiimide resin (B), wherein
said base particle (A) has a functional group reactable with a carbodiimide group and said carbodiimide resin (B) contains a carbodiimide group and said base particle (A) and said carbodiimide resin (B) are bonded together by the functional group of the base particle (A) and the carbodiimide group of the carbodiimide resin (B) to form a shell layer comprised of the carbodiimide resin (B) having average thickness diameter (L), represented by the following numerical equation [1], in the range of 0.01 to 20 μ - m;
L=(L2−
L1)/2
[1]wherein L1 represents average particle diameter of the base particle and L2 represents average particle diameter of the composite particle. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11)
wherein R1 and R3 represent hydrogen or an organic residue having a carbon number of 1 to 40, which is obtained from a compound having a functional group reactable with an isocyanate group left by the functional group, and may be the same or different, and R2 represents an organic residue which is a diisocyanate left by the isocyanate group, wherein said diisocyanate may be a different type;
Y represents a bond formed by the isocyanate group and the functional group reactable with the isocyanate group, and “
n”
is average degree of polymerization, being in the range of 1 to 100;
R1—
Y and Y—
R3 may be an isocyanate group itself on the way to carbodiimidation.
- m;
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8. The composite particle according to claim 7, characterized in that the carbodiimide resin (B) has at least one kind of a hydrophilic segment, and is water-soluble.
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9. A method for producing the composite particle according to any one of claims 1 to 8, comprising
a first step wherein a base particle (A) having a functional group reactable with a carbodiimide group and a carbodiimide resin (B) are mixed or immersed in the presence of at least one kind of a solvent selected from an organic solvent or water which is a non-solvent of the base particle (A) but a solvent of the carbodiimide resin (B), to sufficient degree that the carbodiimide resin (B) is impregnated at a surface layer part of the base particle (A), and consecutively a second step wherein at the surface of the base particle (A), a shell layer which is comprised of the carbodiimide resin (B) is formed so as to cover the base particle (A), by a reaction of a functional group of the base particle (A) with a carbodiimide group of the carbodiimide resin (B). -
10. The method for producing the composite particle according to claim 9, further comprising a preliminary step of forming said base particle (A) by suspension polymerization, emulsion polymerization, dispersion polymerization or seed polymerization.
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11. The method for producing the composite particle according to claim 9, wherein in the first step the base particle (A) is immersed in a solution which is obtained by dissolving the carbodiimide resin (B) in at least one kind of a solvent selected from an organic solvent or water.
Specification