Flexible, formable conductive films

• US 7,261,950 B2
• Filed: 08/15/2003
• Issued: 08/28/2007
• Est. Priority Date: 08/17/2002
• Status: Expired due to Fees

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Fleming, Robert J., Condo, Peter D., Bright, Clark I., Anderson, Edward J.
• Primary Examiner(s): Lavilla; Michael E
• Application Number:
  US10/521,827
• Publication Number:
  US 20050247470A1
• Time in Patent Office: 1,474 Days
• Field of Search: 428/626, 428/673, 428/686, 428/457, 428/460, 428/929, 428/595, 428/601, 428/598, 428/625, 428/34.1, 428/409, 428/35.7, 428/461, 428/35.8, 428/332, 428/220, 428/215, 428/216, 428/336, 174/35.R, 174/51, 174/50, 359/585
• US Class Current: 428/626
• CPC Class Codes: H05K 9/0094 being light-transmitting, e.g. transparent, translucent
• CPC Class Codes: Y10T 428/12396 Discontinuous surface component
• CPC Class Codes: Y10T 428/12569 Synthetic resin
• CPC Class Codes: Y10T 428/12896 Ag-base component
• CPC Class Codes: Y10T 428/13 Hollow or container type article [e.g., tube, vase, etc.]
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/26 Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31688 Next to aldehyde or ketone condensation product
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers

Abstract

Electrically conductive films comprising a flexible support, an extensible metal or metal alloy layer, and a crosslinked polymeric protective layer have at least one permanently deformed curved region. The films can be light transmissive and can have regions of compound curvature, and the metal or metal alloy layer can be substantially continuous. The films have reduced susceptibility to fracture or corrosion compared to commercially available electromagnetic interference (EMI) shielding films.

Claims

1. A conductive film comprising:

a flexible support,

an extensible metal layer, wherein the metal layer has a physical thickness from about 3 nm to about 50 nm,

and a crossliniked polymeric protective layer,

wherein the extensible metal layer is disposed between the flexible support and the crosslinked polymeric protective layer, and the film has at least one permanently deformed curved region.

2. A film according to claim 1, wherein the metal layer is substantially continuous, and the at least one permanently deformed curved region is compound curved.

3. A film according to claim 2, wherein the film is light transmissive.

4. A film according to claim 1, wherein the metal layer comprises silver and the crosslinked polymeric layer comprises an acrylate polymer.

5. A film according to claim 1, further comprising at least a second metal layer, wherein said second metal layer is also disposed between the support and the crosslinked polymeric protective layer.

6. A film according to claim 5, wherein the metal layer and the second metal layer are separated by a crosslinked polymeric spacing layer and provide an infrared-rejecting Fabry-Perot stack.

7. A film according to claim 1, wherein the metal layer or the crosslinked polymeric protective layer has been subjected to an adhesion-enhancing treatment.

8. A film according to claim 1, having a length and an electromagnetic shielding capability that is retained when the film is strained in a tensile mode by 5% of its length.

9. A film according to claim 1, having a length and an electromagnetic shielding capability that is retained when the film is strained in a tensile mode by 10% of its length.

10. A film according to claim 1, having an electromagnetic shielding capability that is retained when the film is bent at a 45°

angle.

11. A film according to claim 1, that exhibits color-shifting behavior when viewed from different viewing angles.

12. A film according to claim 1, further comprising at least one planar region.

13. A film according to claim 1, further comprising a thermoplastic supplemental support.

14. An electrical device comprising the film of claim 1.

15. The device of claim 14, wherein the device is selected from the group consisting of a cell phone, a personal digital assistant, a computer and combinations thereof.

16. The device of claim 14, wherein the device comprises a heater.

17. A film according to claim 1, wherein the crosslinked polymeric protective layer further comprises an adhesion-enhancing additive.