Organic light emitting devices having carrier blocking layers comprising metal complexes

• US 7,261,954 B2
• Filed: 02/13/2006
• Issued: 08/28/2007
• Est. Priority Date: 08/29/2001
• Status: Expired due to Term

• Current Assignee: The Trustees of Princeton University (Princeton University), University of Southern California
• Original Assignee: The Trustees of Princeton University (Princeton University), University of Southern California
• Inventors: Forrest, Stephen R., Thompson, Mark E., Adamovich, Vadim, Ren, Xiaofan, Alleyne, Bert, D'Andrade, Brian Wendell, Cordero, Steven R
• Primary Examiner(s): Garrett; Dawn L.
• Application Number:
  US11/353,338
• Publication Number:
  US 20060134465A1
• Time in Patent Office: 561 Days
• Field of Search: 428/690, 428/917, 257/E51.044, 313/504, 313/506
• US Class Current: 428/690
• CPC Class Codes: H10K 2101/10 Triplet emission
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/14 Carrier transporting layers
• CPC Class Codes: H10K 50/18 Carrier blocking layers
• CPC Class Codes: H10K 50/181 Electron blocking layers
• CPC Class Codes: H10K 85/10 Organic polymers or oligomers
• CPC Class Codes: H10K 85/111 comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
• CPC Class Codes: H10K 85/1135 Polyethylene dioxythiophene [PEDOT]; Derivatives thereof
• CPC Class Codes: H10K 85/30 Coordination compounds
• CPC Class Codes: H10K 85/321 Metal complexes comprising a group IIIA element, e.g. Tris (8-hydroxyquinoline) gallium [Gaq3]
• CPC Class Codes: H10K 85/324 comprising aluminium, e.g. Alq3
• CPC Class Codes: H10K 85/326 comprising gallium
• CPC Class Codes: H10K 85/341 Transition metal complexes, e.g. Ru(II)polypyridine complexes H10K85/331 takes precedence
• CPC Class Codes: H10K 85/342 comprising iridium
• CPC Class Codes: H10K 85/60 Organic compounds having low molecular weight H10K85/10 - H10K85/50 take precedence
• CPC Class Codes: H10K 85/631 Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine
• CPC Class Codes: H10K 85/649 Aromatic compounds comprising a hetero atom
• CPC Class Codes: H10K 85/6565 Oxadiazole compounds
• CPC Class Codes: Y10S 428/917 Electroluminescent
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

Light emitting devices having blocking layers comprising one or more metal complexes are provided. The blocking layers may serve to block electrons, holes, and/or excitons. Preferably, the devices further comprise a separate emissive layer in which charge and/or excitons are confined. Metal complexes suitable for blocking layers can be selected by comparison of HOMO and LUMO energy levels of materials comprising adjacent layers in devices of the present invention.

Claims

1. A light emitting device, comprising an emissive layer and at least one blocking layer, wherein said blocking layer comprises at least one transition metal complex, and wherein said at least one transition metal complex is an organometallic complex having a coordinating carbon.

2. The light emitting device of claim 1, wherein said blocking layer does not electroluminesce in said device.

3. The light emitting device of claim 1, wherein said blocking layer is a hole blocking layer.

4. The light emitting device of claim 1, wherein said blocking layer is an exciton blocking layer.

5. The light emitting device of claim 1, wherein said blocking layer consists essentially of said metal complex.

6. The light emitting device of claim 1, wherein said transition metal is a second or third row transition metal.

7. The light emitting device of claim 1, wherein said transition metal is iridium.

8. The light emitting device of claim 1, wherein said metal complex is bis(2-(4,6-difluorophenyl)pyridyl-N,C2 ′

)iridium(III) picolinate.

37. A method of fabricating a light emitting device, said method comprising depositing a blocking layer onto a preexisting layer, wherein said blocking layer comprises at least one transition metal complex, and wherein said at least one transition metal complex is an organometallic complex having a coordinating carbon, and wherein said device is a device according to claim 1.

38. The method of claim 37, wherein said metal complex is Flrpic.

39. A pixel, comprising the light emitting device of claim 1.

43. An electronic display, comprising the light emitting device of claim 1.

47. The light emitting device of claim 1, wherein said at least one transition metal complex comprises a nitrogen containing ligand selected from the group consisting of amines, nitrenes, azide, diazenes, triazenes, nitric oxide, polypyrazolylborates, 2,2′

-bipyridine, 1,10-phenanthroline, terpyridine pyridazine, pyrimidine, purine, pyrazine, pyridine, 1,8-napthyridine, pyrazolate and imidazolate.

9. A light emitting device, comprising an emissive layer and at least one blocking layer, wherein said blocking layer comprises at least one metal complex, comprising a main group metal atom having an atomic number greater than 13, and wherein said at least one metal complex is an organometallic complex having a coordinating carbon.

10. The light emitting device of claim 9, wherein said blocking layer does not electroluminesce in said device.

11. The light emitting device of claim 9, wherein said blocking layer is a hole blocking layer.

12. The light emitting device of claim 9, wherein said blocking layer is an exciton blocking layer.

13. The light emitting device of claim 9, wherein said blocking layer consists essentially of said metal complex.

14. The light emitting device of claim 9, wherein said main group metal atom is a third, fourth, or fifth main group metal atom.

15. The light emitting device of claim 9, wherein said main group metal atom is gallium.

40. A pixel, comprising the light emitting device of claim 9.

44. An electronic display, comprising the light emitting device of claim 9.

16. A light emitting device, comprising an emissive layer and at least one blocking layer, wherein said blocking layer comprises at least one metal complex comprising a main group metal atom, and wherein said at least one metal complex is a six-coordinate organometallic complex having a coordinating carbon.

41. A pixel, comprising the light emitting device of claim 16.

45. An electronic display, comprising the light emitting device of claim 16.

17. A light emitting device, comprising an emissive layer and a blocking layer, wherein said blocking layer comprises a wide band-gap organic matrix into which an organometallic complex having a metal-coordinating carbon is doped.

42. A pixel, comprising the light emitting device of claim 17.

46. An electronic display, comprising the light emitting device of claim 17.

18. A light emitting device, comprising an emissive layer and a hole blocking layer, each of said layers having an anode side and a cathode side, wherein said cathode side of said emissive layer is in contact with said anode side of said hole blocking layer, wherein said hole blocking layer has a lower HOMO energy level than the HOMO energy level of said emissive layer, and comprises at least one transition metal complex, wherein said at least one transition metal complex is an organometallic complex having a coordinating carbon.

19. The light emitting device of claim 18, wherein the magnitude of the difference between the LUMO energy levels of said hole blocking layer and said emissive layer is less than the magnitude of the difference between said HOMO energy levels of said hole blocking layer and said emissive layer.

20. The light emitting device of claim 18, wherein said hole blocking layer consists essentially of said metal complex.

21. The light emitting device of claim 18, wherein said emissive layer comprises a host material doped with an emitter.

22. The light emitting device of claim 21, wherein said hole blocking layer comprises a wide band-gap organic matrix doped with said metal complex.

23. The light emitting device of claim 22, wherein said metal complex has a smaller band-gap than said matrix.

24. The light emitting device of claim 23, wherein the LUMO energy level of said metal complex is less than about 200 meV from the LUMO energy level of said emissive layer.

25. The light emitting device of claim 21, wherein said emitter is a metal complex.

33. A method of confining holes to an emissive layer in a light emitting device, said method comprising providing a device according to claim 18, and applying a voltage across said device.

26. A light emitting device, comprising an emissive layer and a hole blocking layer, each of said layers having an anode side and a cathode side, wherein said cathode side of said emissive layer is in contact with said anode side of said hole blocking layer, wherein said hole blocking layer has a lower HOMO energy level than the HOMO energy level of said emissive layer and comprises at least one metal complex comprising a main group metal atom having an atomic number greater than 13, wherein said at least one transition metal complex is an organometallic complex having a coordinating carbon.

27. A light emitting device, comprising an emissive layer and a hole blocking layer, each of said layers having an anode side and a cathode side, wherein said cathode side of said emissive layer is in contact with said anode side of said hole blocking layer, wherein said hole blocking layer has a lower HOMO energy level than the HOMO energy level of said emissive layer and comprises at least one six-coordinate transition metal complex, wherein said at least one transition metal complex is an organometallic complex having a coordinating carbon.

28. A light emitting device, comprising an emissive layer and an exciton blocking layer, wherein said emissive layer is in contact with said exciton blocking layer, wherein said exciton blocking layer has a wider optical gap than the optical gap of said emissive layer, and wherein said exciton blocking layer comprises at least one organometallic complex having a coordinating carbon.

29. The light emitting device of claim 28, wherein said exciton blocking layer has a HOMO energy level that is less than about 200 meV from the HOMO energy level of said emissive layer.

30. The light emitting device of claim 28, wherein said exciton blocking layer has a LUMO energy level that is less than about 200 meV from the LUMO energy level of said emissive layer.

31. The light emitting device of claim 28, wherein said exciton blocking layer consists essentially of said metal complex.

34. A method of confining excitons to a emissive layer in a light emitting device, said method comprising providing a device according to claim 28, and applying a voltage across said device.

35. The method of claim 34, wherein said blocking layer consists essentially of said metal complex.

36. The method of claim 34, wherein said blocking layer comprises a matrix doped with said metal complex.

32. A light emitting device, having the structure anode/hole transporting layer/emissive layer/hole blocking layer/electron transporting layer/cathode, wherein said hole blocking layer comprises a wide band-gap organic matrix doped with an organometallic complex having a coordinating carbon.