Aqueous polymer composition

• US 7,265,166 B2
• Filed: 07/02/2004
• Issued: 09/04/2007
• Est. Priority Date: 07/08/2003
• Status: Active Grant

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Brown, Ward Thomas, Gebhard, Matthew Stewart
• Primary Examiner(s): Cain; Edward J.
• Application Number:
  US10/884,586
• Publication Number:
  US 20050009954A1
• Time in Patent Office: 1,159 Days
• Field of Search: 523/205, 523/210, 523/206, 524/504, 524/505, 524/804
• US Class Current: 523/205
• CPC Class Codes: C08F 2/22 Emulsion polymerisation
• CPC Class Codes: C08F 220/1804 C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
• CPC Class Codes: C08F 230/02 containing phosphorus
• CPC Class Codes: C08F 265/04 on to polymers of esters
• CPC Class Codes: C08F 265/06 Polymerisation of acrylate or methacrylate esters on to polymers thereof
• CPC Class Codes: C08F 290/04 Polymers provided for in subclasses C08C or C08F
• CPC Class Codes: C08F 290/06 Polymers provided for in subclass C08G
• CPC Class Codes: C08F 291/00 Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 33/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof
• CPC Class Codes: C08L 43/02 Homopolymers or copolymers of monomers containing phosphorus
• CPC Class Codes: C08L 51/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C08L51/04, C08L51/06 take precedence
• CPC Class Codes: C09D 133/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof
• CPC Class Codes: C09D 143/02 Homopolymers or copolymers of monomers containing phosphorus
• CPC Class Codes: C09D 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09D151/04, C09D151/06 take precedence

Abstract

An aqueous polymer composition is provided containing select levels of hard polymer and soft polymer, wherein the hard polymer and the soft polymer are contained as dispersed particles. Portions of the hard polymer and optionally, the soft polymer, have select chemical groups. The aqueous polymer composition also contains composite particles formed from pigment particles and a plurality of polymer particles having the select chemical groups. The aqueous polymer composition is useful for preparing coatings having a combination of improved hiding, low temperature film formation, and hardness properties, such as dirt pickup resistance. Methods to prepare and to use the aqueous polymer composition are also provided.

Claims

1. An aqueous polymer composition comprising:

a) first polymer particles comprising at least one pendant group selected from the group consisting of phosphorus acid groups, phosphorus acid full-ester groups, polyacid sidechain groups, and mixtures thereof;

wherein said first polymer particles comprise, based on weight of said first polymer particles;

i) from 40 to 100 weight % first hard polymer particles having a glass transition temperature of at least 20°

C.,

ii) from 0 to 60 weight % first soft polymer particles having a glass transition temperature in the range of from −

20°

C. to 5°

C.; and

iii) from 0 to 60 weight % first hard-soft polymer particles comprising first soft polymer phase having a glass transition temperature in the range of from −

20°

C. to 5°

C., and first hard polymer phase having a glass transition temperature of at least 20°

C.;

b) optionally, second polymer particles comprising;

i) second soft polymer particles having a glass transition temperature in the range of from −

20°

C. to 5°

C.,

ii) second hard polymer particles having a glass transition temperature of at least 20°

C.;

or

iii) second hard-soft polymer particles comprising second soft polymer phase having a glass transition temperature in the range of from −

20°

C. to 5°

C., and second hard polymer phase having a glass transition temperature of at least 20°

C.; and

c) composite particles, wherein each of said composite particles comprises a pigment particle and a plurality of said first polymer particles attached to said pigment particle;

wherein said aqueous polymer composition comprises, based on total weight of said first polymer particles and said second polymer particles;

a total weight % of said first soft polymer particles, said first soft polymer phase, said second soft polymer particles, and said second soft polymer phase in the range of from 60 to 98 weight %, and

a total weight % of said first hard polymer particles, said first hard polymer phase, said second hard polymer particles, and said second hard polymer phase in the range of from 2 to 40 weight %.

2. The aqueous polymer composition according to claim 1 comprising a volatile organic compound level of less than 5 weight %, based on weight of said aqueous polymer composition.

3. The aqueous polymer composition according to claim 1 wherein at least one soft polymer component selected from the group consisting of said first soft polymer particles, said first soft polymer phase, said second soft polymer particles, said second soft polymer phase, or combinations thereof, is prepared by:

a) an aqueous polymerization process in which at least 40 weight % of said at least one soft polymer component, based on total weight of said at least one soft polymer component, is formed by redox polymerization;

b) an aqueous polymerization process in the presence of 0.01 to 1 weight %, based on the weight of said at least one soft polymer component, of an organic compound selected from the group consisting of t-alkyl hydroperoxides, t-alkyl peroxides, t-alkyl peresters, and mixtures thereof, wherein said t-alkyl group has at least five carbon atoms;

c) an aqueous redox polymerization process that is effected in the presence of 0.001 to 0.05 moles chain transfer agent per kilogram weight of said at least one soft polymer component;

or

d) an aqueous polymer process in which at least 40 weight % of said at least one soft polymer component is polymerized from ethylenically unsaturated monomers in the presence of at least 5 weight % of added monomer that remains unreacted, based on the accumulated weight of said added monomer.

4. An aqueous polymer composition comprising:

a) first polymer particles comprising reacted complementary functional groups;

wherein said first polymer particles comprise, based on weight of said first polymer particles;

i) from 40 to 100 weight % first hard polymer particles having a glass transition temperature of at least 20°

C.,

ii) from 0 to 60 weight % first soft polymer particles having a glass transition temperature in the range of from −

20°

C. to 5°

C.; and

iii) from 0 to 60 weight % first hard-soft polymer particles comprising first soft polymer phase having a glass transition temperature in the range of from −

20°

C. to 5°

C., and first hard polymer phase having a glass transition temperature of at least 20°

C.;

b) optionally, second polymer particles comprising;

i) second soft polymer particles having a glass transition temperature in the range of from −

20°

C. to 5°

C.,

ii) second hard polymer particles having a glass transition temperature of at least 20°

C.;

or

iii) second hard-soft polymer particles comprising second soft polymer phase having a glass transition temperature in the range of from −

20°

C. to 5°

C., and second hard polymer phase having a glass transition temperature of at least 20°

C.; and

c) composite particles, wherein each of said composite particles comprises;

i) a pigment particle,

ii) reacted coupling agents forming first covalent bonds to said pigment particle, and

iii) a plurality of first polymer particles in which said reacted complementary functional groups form second covalent bonds with said reacted coupling agents;

wherein said aqueous polymer composition comprises, based on total weight of said first polymer particles and said second polymer particles;

a total weight % of said first soft polymer particles, first soft polymer phase, said second soft polymer particles, and said second soft polymer phase in the range of from 60 to 98 weight %, and

a total weight % of said first hard polymer particles, said first hard polymer phase, said second hard polymer particles, and said second hard polymer phase in the range of from 2 to 40 weight %.

5. The aqueous polymer composition according to claim 4 comprising a volatile organic compound level of less than 5 weight %, based on weight of said aqueous polymer composition.

6. The aqueous polymer composition according to claim 4 wherein at least one soft polymer component selected from the group consisting of said first soft polymer particles, said first soft polymer phase, said second soft polymer particles, said second soft polymer phase, or combinations thereof, is prepared by:

a) an aqueous polymerization process in which at least 40 weight % of said at least one soft polymer component, based on total weight of said at least one soft polymer component, is formed by redox polymerization;

b) an aqueous polymerization process in the presence of 0.01 to 1 weight %, based on the weight of said at least one soft polymer component, of an organic compound selected from the group consisting of t-alkyl hydroperoxides, t-alkyl peroxides, t-alkyl peresters, and mixtures thereof, wherein said t-alkyl group has at least five carbon atoms;

c) an aqueous redox polymerization process that is effected in the presence of 0.001 to 0.05 moles chain transfer agent per kilogram weight of said at least one soft polymer component;

or

d) an aqueous polymer process in which at least 40 weight % of said at least one soft polymer component is polymerized from ethylenically unsaturated monomers in the presence of at least 5 weight % of added monomer that remains unreacted, based on the accumulated weight of said added monomer.