Scanning a band of frequencies using an array of high temperature superconductor sensors tuned to the same frequency

• US 7,265,549 B2
• Filed: 04/29/2005
• Issued: 09/04/2007
• Est. Priority Date: 04/30/2004
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Alvarez, Robby L., McCambridge, James D.
• Primary Examiner(s): Shrivastav; Brij
• Assistant Examiner(s): Fetzner; Tiffany A.
• Application Number:
  US11/118,962
• Publication Number:
  US 20050248345A1
• Time in Patent Office: 858 Days
• Field of Search: None
• US Class Current: 324/310
• CPC Class Codes: G01N 24/084 Detection of potentially hazardous samples, e.g. toxic samples, explosives, drugs, firearms, weapons
• CPC Class Codes: G01R 33/34023 Superconducting RF coils
• CPC Class Codes: G01R 33/3415 comprising arrays of sub-coils , i.e. phased-array coils with flexible receiver channels
• CPC Class Codes: G01R 33/3635 Multi-frequency operation
• CPC Class Codes: G01R 33/441 Nuclear Quadrupole Resonance [NQR] Spectroscopy and Imaging

Abstract

The methods of the invention for scanning a band of frequencies using a nuclear quadrupole resonance detection system with an array of high temperature superconductor sensors to detect nuclear quadrupole resonance signals improve the nuclear quadrupole resonance detection system performance.

Claims

1. A method for detecting the presence of nuclear guadrapole resonance signals in a sample by scanning the sample with a band of frequencies Δ

F using a nuclear quadrupole resonance detection system comprising an array of n high temperature superconductor sensors, wherein n≧

2 and the bandwidth of each sensor is Δ

f, the method comprising the steps of;

a) determining r different frequencies that span the band of frequencies Δ

F when using sensors with bandwidths Δ

f, wherein r is the order of Δ

F/Δ

f;

b) tuning the resonance frequency of all the n sensors to the same frequency, wherein the frequency is selected from the group of the r different frequencies, and maintaining the resonance frequencies for a selected period of time;

c) retuning simultaneously the resonance frequency of all the n sensors to the same frequency, wherein the retuned frequency is another of the r different frequencies, and maintaining these retuned resonance frequencies for a selected period of time; and

d) repeating step (c) r-2 times, wherein after each retuning the retuned resonance frequencies of the n sensors are different from the resonance frequencies to which the sensors are tuned or retuned in any of the previous steps

whereby every one of the r frequencies is used by every one of the sensors to scan the sample for the presence of nuclear quadrapole resonance signals.

2. The method of claim 1, further comprising the step of repeating steps (b), (c) and (d) one or more times.

3. The method of claim 1, further comprising the step of combining the signals detected by all sensors that are tuned to a selected frequency.

4. The method of claim 1, wherein each resonance frequency is maintained for the same period of time.

5. The method of claim 1, wherein the n high temperature superconductor sensors solely detect the presence of nuclear quadrupole resonance signals.

6. The method of claim 5, wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

7. The method of claim 5, wherein each high temperature superconductor sensor is comprised of two or more coupled high temperature superconductor self-resonant planar coils.

8. A nuclear quadrupole resonance detection system configured for scanning a sample, comprising:

a) n high temperature superconductor sensors, each with bandwidth Δ

f, in order to scan a band of frequencies Δ

F and detect any nuclear quadrupole resonance signal within the band of frequencies Δ

F, wherein n≧

2;

b) means to tune the resonance frequencies of all the n sensors to the same resonance frequency, wherein the resonance frequency is selected from the group of r different frequencies that span the band of frequencies Δ

F using sensors with bandwidths Δ

f, and wherein r is of the order of Δ

F/Δ

f; and

c) means to simultaneously retune r-1 times the resonance frequencies of all the n sensors to the same frequency each time, wherein the frequency each time is another of the r different frequencies, and wherein after each retuning each of the n sensors has a retuned resonance frequency that is different from any resonance frequencies to which it has previously been retuned.

9. The nuclear quadrupole resonance detection system of claim 8, further comprising:

d) means to combine the signals detected by all sensors that are tuned to a selected frequency.

10. The nuclear quadrupole resonance detection system of claim 8, wherein the n high temperature superconductor sensors solely detect nuclear quadrupole resonance signals.

11. The nuclear quadrupole resonance detection system of claim 10, wherein each high temperature superconductor sensor is comprised of a high temperature superconductor self-resonant planar coil.

12. The nuclear quadrupole resonance detection system of claim 10, wherein each high temperature superconductor sensor is comprised of two or more coupled high temperature superconductor self-resonant planar coils.

13. The nuclear quadrupole resonance detection system of claim 10, further comprising one or more shielded-loop resonator coils In order to apply to the sample to be scanned for the presence of nuclear quadrupole resonance an RF signal capable of exciting quadrupolar nuclei in the sample.

14. The nuclear quadrupole resonance detection system of claim 10, wherein the means to tune and simultaneously retune the resonance frequency of each of the n sensors is comprised of n circuits, one for each of the n sensors, wherein each circuit is comprised of (a) a single loop or coil to inductively couple the circuit to the high temperature superconductor self-resonant sensor, (b) a variable reactance in series with the single loop or coil, and (c) means to connect the variable reactance to, and disconnect the variable reactance from, the single loop or coil.

15. The nuclear quadrupole resonance detection system of claim 10, wherein the means to tune and simultaneously retune the resonance frequency of each of the n sensors is comprised of one or more circuits that is comprised of a variable reactance.

16. The nuclear quadrupole resonance detection system of claim 8, wherein the sample comprises explosives, drugs or other contraband.

17. The nuclear quadrupole resonance detection system of claim 9, wherein the sample comprises explosives, drugs or other contraband.

18. A safety system, a security system, or a law enforcement screening system comprising the nuclear quadrupole resonance detection system of claim 9.