Articles prepared from hydrogenated controlled distribution block copolymers
First Claim
1. An article selected from the group consisting of personal hygiene films and fibers, blown films for medical devices, extruded films, extruded tubes, extruded profiles, overmolded grips, airbags, steering wheels, toys, cap seals, automotive skins, thermal spray coatings, trays, and gloves, consisting essentially of at least one hydrogenated block copolymer and at least one other component selected from the group consisting of olefin polymers, styrene polymers, tackifying resins, polymer extending oils and engineering thermoplastic resins, wherein said hydrogenated block copolymer has at least one block A and at least one block B, and wherein:
- a. prior to hydrogenation each A block is a mono alkenyl arene homopolymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene;
b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced;
c. each A block having a number average molecular weight between about 3,000 and about 60,000 and each B block having a number average molecular weight between about 30,000 and about 300,000;
d. each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and a region not adjacent to the A blocks that is rich in mono alkenyl arene units;
e. the total amount of mono alkenyl arene in the hydrogenated block copolymer is about 20 percent weight to about 80 percent weight; and
f. the weight percent of mono alkenyl arene in each B block is between about 10 percent and about 75 percent.
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Accused Products
Abstract
The present invention relates to articles prepared from novel anionic block copolymers of mono alkenyl arenes and conjugated dienes, and to blends of such block copolymers with other polymers. The block copolymers are selectively hydrogenated and have mono alkenyl arene end blocks and controlled distribution blocks of mono alkenyl arenes and conjugated dienes. The block copolymer may be blended with at least one other polymer selected from the group consisting of olefin polymers, styrene polymers, amorphous resins and engineering thermoplastic resins.
98 Citations
55 Claims
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1. An article selected from the group consisting of personal hygiene films and fibers, blown films for medical devices, extruded films, extruded tubes, extruded profiles, overmolded grips, airbags, steering wheels, toys, cap seals, automotive skins, thermal spray coatings, trays, and gloves, consisting essentially of at least one hydrogenated block copolymer and at least one other component selected from the group consisting of olefin polymers, styrene polymers, tackifying resins, polymer extending oils and engineering thermoplastic resins, wherein said hydrogenated block copolymer has at least one block A and at least one block B, and wherein:
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a. prior to hydrogenation each A block is a mono alkenyl arene homopolymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene; b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced; c. each A block having a number average molecular weight between about 3,000 and about 60,000 and each B block having a number average molecular weight between about 30,000 and about 300,000; d. each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and a region not adjacent to the A blocks that is rich in mono alkenyl arene units; e. the total amount of mono alkenyl arene in the hydrogenated block copolymer is about 20 percent weight to about 80 percent weight; and f. the weight percent of mono alkenyl arene in each B block is between about 10 percent and about 75 percent. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47)
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48. An article selected from the group consisting of personal hygiene films and fibers, blown films for medical devices, extruded films, extruded tubes, extruded profiles, overmolded grips, airbags, steering wheels, toys, cap seals, automotive skins, trays, and gloves consisting essentially of at least one hydrogenated block copolymer and at least one other component selected from the group consisting of olef in polymers, styrene polymers, tackifying resins, polymer extending oils and engineering thermoplastic resins, wherein said hydrogenated block copolymer has at least one block A and at least one block B, and wherein:
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a. prior to hydrogenation each A block is a mono alkenyl arene homopolymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene; b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced; c. each A block having a number average molecular weight between about 3,000 and about 60,000 and each B block having a number average molecular weight between about 30,000 and about 300,000; d. each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and a region not adjacent to the A blocks that is rich in mono alkenyl arene units; e. the total amount of mono alkenyl arene in the hydrogenated block copolymer is about 20 percent weight to about 80 percent weight f. the weight ratio of conjugated diene to mono alkenyl arene in the B block is between about 5;
1 and about 1;
2. - View Dependent Claims (49, 50, 51, 52, 53, 54, 55)
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Specification