Presence indicator for removable transparent film

• US 7,267,880 B2
• Filed: 06/14/2004
• Issued: 09/11/2007
• Est. Priority Date: 06/17/2003
• Status: Active Grant

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Inventors: Hartig, Klaus, Pfaff, Gary, Krisko, Annette, Miller, Leah, O'Shaughnessy, Roger
• Primary Examiner(s): Zimmerman; John J.
• Assistant Examiner(s): BLACKWELL, GWENDOLYN
• Application Number:
  US10/866,936
• Publication Number:
  US 20040258890A1
• Time in Patent Office: 1,184 Days
• Field of Search: None
• US Class Current: 428/432
• CPC Class Codes: C03C 17/34 with at least two coatings having different compositions C03C17/44 takes precedence
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 17/3423 at least one of the coatings comprising a suboxide
• CPC Class Codes: C03C 2218/355 Temporary coating
• CPC Class Codes: C23C 14/0005 Separation of the coating from the substrate
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Abstract

A substrate having a surface carrying a removable transparent film that can be removed by the surface by a desired washing process, and removable presence indicator associated with the removable transparent film, the presence indicator being removable by the same desired washing process as the removable transparent film. A method of producing a substrate having a presence indicator in contact with a removable transparent film a method of washing a substrate having a presence indicator in contact with a removable transparent film are also disclosed.

Claims

1. A panel comprising a substrate having a surface carrying a removable transparent film that can be removed from said surface by a desired washing process, the panel including a removable presence indicator provided in between said surface and the removable transparent film, the presence indicator being separate from the removable transparent film and removable by the same desired washing process as the removable transparent film.

2. The panel of claim 1 wherein the substrate surface is provided with a hydrophilic coating.

3. The panel of claim 1 wherein the substrate surface is provided with a photocatalytic coating.

4. The panel of claim 1 wherein the substrate surface is provided with a reflective coating.

5. The panel of claim 1 wherein the substrate surface is resistant to the presence of a weak acid or a weak base.

6. The panel of claim 1 wherein the removable transparent film is a sputtered film.

7. The panel of claim 1 wherein the removable transparent film has a thickness of less than 100 Å

.

8. The panel of claim 1 wherein both the removable transparent film and the presence indicator are durable at glass tempering temperatures.

9. The panel of claim 1 wherein both the removable transparent film and the presence indicator are stable in the presence of water but break down in the presence of a weak acid or a weak base.

10. The panel of claim 1 wherein the removable film is sufficiently transparent so that it cannot be readily detected by visual inspection with the naked eye.

11. The panel of claim 10 wherein the presence indicator has visible characteristics enabling it to be readily detected by visual inspection with the naked eye.

12. The panel of claim 1 wherein the removable transparent film comprises an oxide of a metal selected from the group consisting of zinc, bismuth, cadmium, iron, and nickel.

13. The panel of claim 12 wherein the removable transparent film comprises zinc oxide.

14. The panel of claim 13 wherein the zinc oxide has a thickness of between about 25 Å

and about 60 Å

.

15. The panel of claim 1 wherein the presence indicator comprises a continuous thin film.

16. The panel of claim 15 wherein the continuous thin film comprises a colored film.

17. The panel of claim 15 wherein the continuous thin film comprises a film of substoichiometric or supersubstoichiometric metal oxide.

18. The panel of claim 15 wherein the continuous thin film comprises a film of substoichiometric or superstoichiometric zinc oxide.

19. The panel of claim 1 wherein the presence indicator comprises a plurality of visible material deposits.

20. The panel of claim 19 wherein the visible material deposits are provided at spaced-apart locations in contact with the removable transparent film.

21. The panel of claim 20 wherein the visible material deposits are provided at spaced-apart locations so that if the panel is cut into smaller panels, each smaller panel comprises at least one visible material deposit.

22. The panel of claim 19 wherein the plurality of visible material deposits includes one or more colorants.

23. The panel of claim 19 wherein the plurality of visible material deposits comprises deposits of a substoichiometric or superstoichiometric metal oxide.

24. The panel of claim 19 wherein the plurality of visible material deposits comprises deposits of a substoichiometric or superstoichiometric zinc oxide.

25. The panel of claim 19 wherein the plurality of visible material deposits comprises water-soluble ink.

26. The panel of claim 25 wherein the water soluble ink comprises ink that is stable in the presence of water but breaks down in the presence of a weak acid or a weak base.

27. A panel comprising a substrate having a surface carrying a removable transparent film that can be removed from said surface by a desired washing process, the panel including a removable presence indicator so associated with the removable transparent film, the presence indicator being removable by the same desired washing process as the removable transparent film, wherein the presence indicator comprises a substoichiometric or superstoichiometric compound.

28. The panel of claim 27 wherein the removable transparent film comprises zinc oxide.

29. The panel of claim 27 wherein the presence indicator comprises a substoichiometric or superstoichiometric zinc oxide.

30. The panel of claim 27 wherein the removable transparent film has an inner surface and an outer surface, the inner surface being closer to the substrate than the outer surface, wherein the presence indicator is provided in contact with the inner surface.

31. The panel of claim 27 wherein the presence indicator is incorporated in the removable transparent film.

32. The panel of claim 31 wherein the removable transparent film is a film of substoichiometric or superstoichiometric zinc oxide.

33. The panel of claim 27 wherein the presence indicator comprises a continuous thin film of substoichiometric or supersubstoichiometric metal oxide.

34. The panel of claim 27 wherein the presence indicator comprises a plurality of visible material deposits that include substoichiometric or superstoichiometric compound.

35. The panel of claim 34 wherein the plurality of visible material deposits include substoichiometric or superstoichiometric zinc oxide.

36. The panel of claim 27 further comprising a functional coating positioned between the substrate surface and the removable transparent film.

37. The panel of claim 36 wherein the functional coating is a hydrophilic coating, a photocatalytic coating, or a reflective coating.

38. The panel of claim 27 wherein both the removable transparent film and the presence indicator are durable at glass tempering temperatures.

39. The panel of claim 27 wherein both the removable transparent film and the presence indicator are stable in the presence of water but break down in the presence of a weak acid or a weak base.

40. A panel comprising a substrate having a surface carrying a removable transparent film that can be removed from said surface by a desired washing process, the panel including a removable presence indicator that is removable by the same desired washing process as the removable transparent film, wherein the presence indicator comprises a plurality of visible material deposits provided at spaced-apart locations in contact with the removable transparent film, wherein the plurality of visible material deposits comprise substoichiometric or superstoichiometric metal oxide.

41. The panel of claim 40 wherein the visible material deposits are provided at spaced-apart locations so that if the panel is cut into smaller panels, each smaller panel comprises at least one visible material deposit.

42. A panel comprising a substrate having a surface carrying a removable transparent film that can be removed from said surface by a desired washing process, the panel including a removable presence indicator that is removable by the same desired washing process as the removable transparent film, wherein the presence indicator comprises a plurality of visible material deposits provided in contact with the removable transparent film, wherein the removable transparent film comprises zinc oxide and the plurality of visible material deposits comprises deposits of a substoichiometric or superstoichiometric zinc oxide.

43. A panel comprising a substrate having a surface carrying a removable transparent film that can be removed from said surface by a desired removing process, the panel including a removable presence indicator that is removable by the same desired removing process as the removable transparent film, wherein the presence indicator comprises a plurality of visible material deposits provided in contact with the removable transparent film, wherein the plurality of visible material deposits comprises one or more decals.

44. The panel of claim 43 wherein the one or more decals are porous.

45. The panel of claim 43 wherein the one or more decals are made of an organic material.

46. The panel of claim 43 wherein the one or more decals contain machine readable information.

47. A panel comprising a substrate having a surface carrying a removable transparent film that can be removed from said surface by a desired removing process, the removable transparent film having an inner surface and an outer surface, the inner surface being closer to the substrate than the outer surface, wherein the panel includes, a first removable presence indicator provided in contact with the inner surface and a second removable presence indicator provided in contact with the outer surface or incorporated in the removable transparent film, wherein both the first and second presence indicators are removable by the same desired washing process as the removable transparent film.

48. The panel of claim 47 wherein one of or both of the first removable presence indicator and the second removable presence indicator comprises a continuous thin film.

49. The panel of claim 47 wherein one of or both of the first removable presence indicator and the second removable presence indicator comprises a plurality of visible material deposits.

50. The panel of claim 47 wherein the first removable presence indicator comprises a continuous thin film and the second removable presence indicator comprises a plurality of visible material deposits.

51. The panel of claim 47 wherein one of or both of the first removable presence indicator and the second removable presence indicator comprise substoichiometric or superstoichiometric metal oxide.

52. The panel of claim 47 wherein one of or both of the first removable presence indicator and the second removable presence indicator comprise one or more colorants.

53. The panel of claim 47 wherein one of or both of the first removable presence indicator and the second removable presence indicator comprise water-soluble ink.

54. The panel of claim 47 wherein each the removable transparent film, the first removable presence indicator, and the second removable presence indicator are durable at glass tempering temperatures.

55. The panel of claim 47 wherein each the removable transparent film, the first removable presence indicator, and the second removable presence indicator are stable in the presence of water but break down in the presence of a weak acid or a weak base.