Plasma dielectric etch process including ex-situ backside polymer removal for low-dielectric constant material

• US 7,276,447 B1
• Filed: 04/11/2006
• Issued: 10/02/2007
• Est. Priority Date: 04/11/2006
• Status: Expired due to Fees

• Current Assignee: Applied Materials Incorporated
• Original Assignee: Applied Materials Incorporated
• Inventors: Delgadino, Gerardo A., Lahiri, Indrajit, Su, Teh-Tien, Sinha, Ashok K., Sheih, Brian Sy-Yuan
• Primary Examiner(s): Fourson; George
• Assistant Examiner(s): Maldonado; Julio J
• Application Number:
  US11/402,074
• Publication Number:
  US 20070238305A1
• Time in Patent Office: 539 Days
• Field of Search: 438/694, 438/696, 438/700, 438/905, 438/906, 438/963, 438/908, 438/924, 257/E21.226, 134/1.2, 134/1.3
• US Class Current: 438/694
• CPC Class Codes: G03F 7/427 using plasma means only
• CPC Class Codes: H01J 37/32357 Generation remote from the workpiece, e.g. down-stream
• CPC Class Codes: H01L 21/0209 Cleaning of wafer backside
• CPC Class Codes: H01L 21/31138 by dry-etching

Abstract

A plasma etch process for etching a porous carbon-doped silicon oxide dielectric layer using a photoresist mask is carried out first in an etch reactor by performing a fluoro-carbon based etch process on the workpiece to etch exposed portions of the dielectric layer while depositing protective fluoro-carbon polymer on the photoresist mask. Then, in an ashing reactor, polymer and photoresist are removed by heating the workpiece to over 100 degrees C., exposing a peripheral portion of the backside of said workpiece, and providing products from a plasma of a hydrogen process gas to reduce carbon contained in polymer and photoresist on said workpiece until the polymer has been removed from a backside of said workpiece. The process gas preferably contains both hydrogen gas and water vapor, although the primary constituent is hydrogen gas. The wafer (workpiece) backside may be exposed by extending the wafer lift pins.

Claims

1. A plasma etch process, comprising:

providing a workpiece having a porous carbon-doped silicon oxide dielectric layer;

defining a photoresist mask on a surface of the workpiece;

in an etch reactor;

performing a fluoro-carbon based etch process on the workpiece to etch exposed portions of the dielectric layer while depositing protective fluoro-carbon polymer on the photoresist mask;

transferring said workpiece to an ashing reactor and in said ashing reactor;

heating the workpiece to over 100 degrees C.;

exposing a peripheral portion of the backside of said workpiece; and

providing products from a plasma of a hydrogen process gas to reduce polymer and photoresist on said workpiece until the polymer has been removed from a backside of said workpiece.

2. The process of claim 1 wherein said hydrogen process gas contains pure hydrogen.

3. The process of claim 1 wherein said hydrogen process gas contains both hydrogen gas and water vapor.

4. The process of claim 1 wherein the step of exposing a peripheral portion of the backside of the wafer comprises extending lift pins in a wafer support of said ashing reactor to lift the wafer and expose a backside of the wafer.

5. The process of claim 1 wherein the step of exposing a peripheral portion of the backside of the wafer comprises providing a wafer support in the ashing reactor having a diameter less than a diameter of the wafer.

6. The process of claim 1 wherein the step of providing products from a plasma of a hydrogen process gas to reduce polymer is carried out until all polymer has been removed from a backside of said workpiece.

7. The process of claim 1 wherein the step of providing products form a plasma of a hydrogen process gas to reduce polymer is carried out until all polymer and photoresist has been removed from the workpiece.

8. The process of claim 1 further comprising generating said plasma by flowing hydrogen gas at a first rate and water vapor at a second rate into a plasma generating region, wherein said first rate exceeds said second rate.

9. The process of claim 8 wherein said first rate is more than ten times said second rate.

10. The process of claim 8 wherein said first rate is more than 20 times said second rate.

11. The process of claim 8 wherein said plasma generating region comprises a remote plasma source coupled to said ashing reactor, and the step of flowing hydrogen gas and water vapor into a plasma generating region comprises flowing them into the remote plasma source.

12. The process of claim 1 further comprising:

after transferring said workpiece to said ashing reactor, performing a plasma cleaning step in said etch reactor to remove polymer from interior chamber surfaces of said etch reactor.

13. A plasma etch process, comprising:

providing plural workpieces each having a carbon-doped silicon oxide dielectric layer;

defining a photoresist mask on a surface of each workpiece;

in plural etch reactors;

performing a fluoro-carbon based etch process on the respective workpieces in respective etch reactors simultaneously to etch exposed portions of the respective dielectric layers while depositing protective fluoro-carbon polymer on the respective photoresist masks;

in an ashing reactor, performing the following steps on successive ones of the plural workpieces in a time window not exceeding that required to once perform said fluoro-carbon based etch process in each etch reactor;

heating the workpiece to over 100 degrees C.;

exposing a peripheral portion of the backside of said workpiece; and

providing products from a plasma of a hydrogen process gas to reduce polymer and photoresist on said workpiece until the polymer has been removed from a backside of said workpiece.

14. The process of claim 13 wherein the steps performed in said ashing reactor are carried out while simultaneously said etch process is repeated on a successive set of plural workpieces in the plural etch reactors simultaneously.

15. The process of claim 13 wherein said hydrogen process gas contains pure hydrogen.

16. The process of claim 13 wherein said hydrogen process gas contains both hydrogen gas and water vapor.

17. The process of claim 13 wherein the step of exposing a peripheral portion of the backside of the wafer comprises extending lift pins in a wafer support of said ashing reactor to lift the wafer and expose a backside of the wafer.

18. The process of claim 13 wherein the step of exposing a peripheral portion of the backside of the wafer comprises providing a wafer support in the ashing reactor having a diameter less than a diameter of the wafer.