Ion-optical phase volume compression

• US 7,276,688 B2
• Filed: 03/24/2005
• Issued: 10/02/2007
• Est. Priority Date: 03/25/2004
• Status: Active Grant

• Current Assignee: Bruker Daltonics GmbH and Co KG (Bruker Corporation)
• Original Assignee: Bruker Daltonik GmbH (Bruker Corporation)
• Inventors: Weiss, Gerhard
• Primary Examiner(s): Kim; Robert
• Assistant Examiner(s): SMITH, JOHNNIE L
• Application Number:
  US11/088,682
• Publication Number:
  US 20050274902A1
• Time in Patent Office: 922 Days
• Field of Search: 250/292, 250/288, 250/281, 250/282, 250/287
• US Class Current: 250/288
• CPC Class Codes: H01J 49/0481 with means for collisional cooling
• CPC Class Codes: H01J 49/062 Ion guides linear ion traps performing mass selection H01J49/4225, mass filters H01J49/421
• CPC Class Codes: H01J 49/443 Dynamic spectrometers

Abstract

The invention relates to a method for damping the kinetic energy of ions in ion cells filled with collision gas and with an exit aperture to drain the ions out of the cell. The invention uses a conditioning cell with an adjustable DC potential which decreases towards the exit aperture to compress the phase volume of the ions by damping their kinetic energies, collecting the ions after thermalization in the spatial potential minimum thus created and letting them drain away relatively slowly through a central potential minimum in the exit aperture system. This facilitates the production of very fine, highly parallel ion beams which consist of almost monoenergetic ions. In particular, the method can also be coupled with a fragmentation of the ions.

Claims

1. Method to produce a fine monoenergetic ion beam comprising the steps:

(a) injecting ions into a gas-filled conditioning cell with a longitudinal axis and a terminal exit diaphragm system, whereby the ions thermalize,

(b) collecting the thermalized ions in a potential well that extends along the axis in front of the exit diaphragm system, and

(c) draining thermalized ions out of the conditioning cell via a central potential minimum in the exit diaphragm system, thus generating a fine beam whose ions have a high degree of energy homogeneity.

2. Method according to claim 1, wherein the steps (a) of introduction with thermalization, (b) of collection and (c) of draining of the ions take place over a predetermined period of time simultaneously and continuously.

3. Method according to claim 1, wherein

the step (a) of introduction with thermalization and the step (b) of collection form a first phase of the method, and

the step (c) of draining forms a second phase, whereby during the draining, the voltage drop along the conditioning cell is temporally changed to make it possible for the draining to continue until it is empty.

4. Method according to claim 1, wherein a conditioning cell is constructed of parallel ring electrodes.

5. Method according to claim 1, wherein a conditioning cell is used which consists of one or more helical, coiled pair of wires.

6. Method according to claim 1, wherein a conditioning cell is used which consists of parallel longitudinal electrodes which generate a multipole RF field.

7. Method according to claim 6, wherein a conditioning cell is used in which four longitudinal electrodes are used to generate a predominantly quadrupolar RF field and in which insulated resistance layers can be used to generate DC voltage potential gradients in the longitudinal direction.

8. Method according to claim 7, wherein the quadrupolar RF field is generated as free as possible from superimpositions with higher multipole fields by designing the longitudinal electrodes which generate the RF field so that they have a hyperbolic shape towards the interior.

9. Method according to claim 1, wherein the ions in the conditioning cell are fragmented by collisions by being injected into the collision-gas filled conditioning cell at step (a) of the method with energies of between 30 and 200 electron volts.