Methods for identity verification using transparent luminescent polymers

• US 7,279,234 B2
• Filed: 08/18/2004
• Issued: 10/09/2007
• Est. Priority Date: 08/22/2003
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Dean, David M.
• Primary Examiner(s): KOSLOW, CAROL M
• Application Number:
  US10/921,436
• Publication Number:
  US 20050042428A1
• Time in Patent Office: 1,147 Days
• Field of Search: 428/690, 253/011.6, 253/013.4, 528/278, 526/192, 534/16, 534/15, 525/191, 525/201, 525/221, 525/223, 525/227, 525/418
• US Class Current: 428/690
• CPC Class Codes: C08L 23/0869 Acids or derivatives thereof
• CPC Class Codes: C09K 11/025 non-luminescent particle coatings or suspension media
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: C09K 2211/14 Macromolecular compounds
• CPC Class Codes: C09K 2211/182 of the rare earth metals, i.e. Sc, Y or lanthanide
• CPC Class Codes: G09F 3/0291 Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Abstract

Disclosed are methods of using a transparent, luminescent polymer for transparent marking and/or labeling for identity verification purposes. Also disclosed are sheets, films, markers, labels and taggants comprising transparent, luminescent polymers. Also disclosed are articles labeled with a transparent, luminescent polymer. This invention particularly relates to use of transparent, luminescent polymer compositions comprising ethylene (meth)acrylic acid copolymers and rare earth ions and transparent, luminescent polymer compositions comprising methyl (meth)acrylate/(meth)acrylic acid copolymers, fatty acids and rare earth ions for these purposes.

Claims

1. A monolayer or multilayer sheet or film for use as a marker, label, taggant or packaging film comprising at least one layer of a transparent, luminescent polymer composition wherein

the composition comprises (1) at least one E/X/Y copolymer or copolymer of alkyl (meth)acrylate and (meth)acrylic acid and (2) one or more organic acids or salts thereof;

E is ethylene, X is a C₃ to C₈ α

,β

ethylenically unsaturated carboxylic acid, and Y is alkyl acrylate or alkyl methacrylate in which each the alkyl group has one to eight carbon atoms;

X is from about 2 to about 30 weight % of the E/X/Y copolymer and Y is from 0 to about 40 weight % of the E/X/Y copolymer;

The (meth)acrylate is acrylate or methacrylate and the (meth)acrylic acid is acrylic acid or methacrylic acid; and

the combined carboxylic acid functionalities in the composition are at least partially neutralized by a rare earth cation selected from europium or terbium and optionally one or more additional rare earth cations.

2. The sheet or film according to claim 1 wherein said transparent, luminescent polymer composition comprises at least one ethylene (meth)acrylic acid copolymer and (meth)acrylic acid refers to acrylic acid or methacrylic acid.

3. The sheet or film according to claim 1 wherein the organic acid or salt thereof is present in the composition said transparent, luminescent polymer

from about 1 weight % to about 30 weight % of one or more organic acids or salts.

4. The sheet or film according to claim 1 wherein said transparent, luminescent polymer composition comprises the copolymer of alkyl (meth)acrylate and (meth)acrylic acid.

5. The sheet or film according to claim 4 wherein said transparent, luminescent polymer composition comprises from about 1 weight % to about 30 weight % of one or more organic acids or salts thereof.

6. The sheet or film according to claim 1, 2, 3, 4, or 5 wherein the amount of raze earth ions in said transparent, luminescent polymer composition is less than about 9 weight % based on the total weight of the polymer composition.

7. The sheet or film according to claim 1, 2, 3, 4, or 5 wherein said transparent luminescent polymer composition further comprises at least one additive that can also complex with the rare earth cations therein.

8. The sheet or film according to claim 6 wherein said transparent, luminescent polymer composition further comprises at least one additive that can also complex with the rare earth cations therein.