Organometallic complexes as phosphorescent emitters in organic LEDS
First Claim
1. An organic light emitting device, comprising an anode, a cathode and an emissive layer, whereinthe emissive layer is located between the anode and the cathode, and the emissive layer comprises a host and a dopant, the dopant comprising:
- a phosphorescent organometallic compound of formula L2MX, LL′
MX, LL′
L″
M, L3M, or LMXX′
, wherein L, L′
, L″
, X, and X′
are inequivalent, bidentate ligands, and M is a metal that forms octahedral complexes, whereinL, L′
, and L″
are monoanionic bidentate ligands coordinated to M through an sp2 hybridized carbon and a heteroatom.
0 Assignments
0 Petitions
Accused Products
Abstract
Organic light emitting devices are described wherein the emissive layer comprises a host material containing an emissive molecule, which molecule is adapted to luminesce when a voltage is applied across the heterostructure, and the emissive molecule is selected from the group of phosphorescent organometallic complexes, including cyclometallated platinum, iridium and osmium complexes. The organic light emitting devices optionally contain an exciton blocking layer. Furthermore, improved electroluminescent efficiency in organic light emitting devices is obtained with an emitter layer comprising organometallic complexes of transition metals of formula L2MX, wherein L and X are distinct bidentate ligands. Compounds of this formula can be synthesized more facilely than in previous approaches and synthetic options allow insertion of fluorescent molecules into a phosphorescent complex, ligands to fine tune the color of emission, and ligands to trap carriers.
170 Citations
46 Claims
-
1. An organic light emitting device, comprising an anode, a cathode and an emissive layer, wherein
the emissive layer is located between the anode and the cathode, and the emissive layer comprises a host and a dopant, the dopant comprising: -
a phosphorescent organometallic compound of formula L2MX, LL′
MX, LL′
L″
M, L3M, or LMXX′
, wherein L, L′
, L″
, X, and X′
are inequivalent, bidentate ligands, and M is a metal that forms octahedral complexes, whereinL, L′
, and L″
are monoanionic bidentate ligands coordinated to M through an sp2 hybridized carbon and a heteroatom. - View Dependent Claims (2, 3, 4, 5, 6)
-
-
7. An organic light emitting device, comprising an anode, a cathode, and an emissive layer;
-
wherein the emissive layer is located between the anode and the cathode, and the emissive layer comprises a phosphorescent organometallic compound of formula L2MX, LL′
MX, LL′
L″
M, L3M, or LMXX′
, whereinL, L′
, L″
, X, and X′
are inequivalent, bidentate ligands, and M is a metal that forms octahedral complexes;
whereinL, L′
, and L″
are monoanionic bidentate ligands coordinated to M through an sp2 hybridized carbon and a heteroatom; andL, L′
, and L″
are selected from the group consisting of a 2-((1-naphthyl)benzoxazole), a (2-phenylbenzoxazole), a (2-phenylbenzothiazole), a (7,8-benzoquinoline), a coumarin, a phenylpyridine, a benzothienylpyridine, a 3-methoxy-2-phenylpyridine, a thienylpyridine, a tolylpyridine, a phenylimine, a vinylpyridine, an arylquinoline, a pyridylnaphthalene, a pyridylpyrrole, a pyridylimidazole and a phenylindole;
orthe X ligand is selected from the group consisting of an acetylacetonate, a hexafluoroacetylacetonate, a salicylidene, a picolinate, a 8-hydroxyquinolinate, and substituted or unsubstituted ligand selected from the group consisting of an aminoacid, a salicylaldehyde, an acetylacetonate, and a substituted or unsubstituted ligand derived from the structure; - View Dependent Claims (8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32)
-
-
33. An organic light emitting device comprising an anode, a cathode, and an emissive layer, wherein the emissive layer is located between the anode and the cathode, and the emissive layer comprises a phosphorescent organometallic compound of formula L2MX, LL′
- MX, LL′
L″
M, or LMXX′
, wherein L, L′
, L″
, X, and X′
are inequivalent, bidentate ligands and M is a metal that forms octahedral complexes, wherein L, L′
, L″
are monoanionic bidentate ligands coordinated to M through an sp2 hybridized carbon and a heteroatom, and the X ligand is emissive. - View Dependent Claims (45, 46)
- MX, LL′
-
34. An organic light emitting device comprising an anode, a cathode and an emissive layer, wherein the emissive layer is located between the anode and the cathode, the emissive layer consisting essentially of a phosphorescent organometallic compound of formula L2MX, LL′
- MX, LL′
L″
M, L3M, or LMXX′
, wherein L, L′
, L″
, X, and X′
are inequivalent, bidentate ligands and M is a metal that forms octahedral complexes, wherein L, L′
, and L″
are monoanionic bidentate ligands coordinated to M through an sp2 hybridized carbon and a heteroatom.
- MX, LL′
-
35. An organic light emitting device comprising an anode, a cathode, and an emissive layer, wherein the emissive layer is located between the anode and the cathode, the emissive layer comprises a phosphorescent organometallic compound of formula L2MX, LL′
- MX, LL′
L″
M, L3M, or LMXX′ and
, optionally, a host, wherein L, L′
, L″
,X, and X′
are inequivalent, bidentate ligands, and M is a metal that forms octahedral complexes, wherein L is a monoanionic bidentate ligand coordinated to M through an sp2 hybridized carbon and a heteroatom.
- MX, LL′
-
36. An organic light emitting device comprising:
-
an anode, a cathode, and an emissive layer, wherein the emissive layer is located between the anode and the cathode, and the emissive layer comprises a phosphorescent organometallic compound of formula L2MX, LL′
MX, LL′
L″
M, L3M, or LMXX′
, whereinL, L′
, L″
, X, and X′
are inequivalent, bidentate ligands, andM is a metal that forms octahedral complexes, wherein L, L′
, and L″
are monoanionic bidentate ligands coordinated to M through an sp2 hybridized carbon and a heteroatom, and whereinthe organic light emitting device emits light when a carrier injected into the emissive layer is trapped on a ligand of a molecule of the phosphorescent organometallic compound, and recombines with an opposite carrier from the molecule or from an adjacent molecule. - View Dependent Claims (37)
-
-
38. An organic light emitting device, comprising:
- an anode, a cathode, and an emissive layer, the emissive layer located between the anode and the cathode, wherein the emissive layer comprises a host and a dopant, wherein the dopant is a cyclometallated phosphorescent organometallic compound, comprising a cyclometallated ring, having a carbon-metal bond.
- View Dependent Claims (39, 40, 41, 42, 43, 44)
Specification