Coating process and composition for same

• US 7,297,372 B2
• Filed: 06/27/2003
• Issued: 11/20/2007
• Est. Priority Date: 12/26/2001
• Status: Expired due to Fees

• Current Assignee: Dow Global Technologies, Inc. (Dow, Inc.)
• Original Assignee: Dow Global Technologies, Inc. (Dow, Inc.)
• Inventors: Li, Zhicheng, Hsu, Gloria S., Anater, Mark T.
• Primary Examiner(s): CHEN, BRET P
• Application Number:
  US10/609,086
• Publication Number:
  US 20040005413A1
• Time in Patent Office: 1,607 Days
• Field of Search: 427/421, 427/426
• US Class Current: 427/421.1
• CPC Class Codes: B05D 1/02 performed by spraying
• CPC Class Codes: B05D 1/34 Applying different liquids or other fluent materials simultaneously
• CPC Class Codes: B05D 5/00 Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
• CPC Class Codes: B05D 7/16 using synthetic lacquers or varnishes
• CPC Class Codes: C08G 18/3821 Carboxylic acids; Esters thereof with monohydroxyl compounds
• CPC Class Codes: C08G 2150/90 Compositions for anticorrosive coatings
• CPC Class Codes: C09D 175/02 Polyureas

Abstract

There is disclosed a composition for forming a protective coating upon a substrate. The composition has been found particularly useful for forming a protective coating upon components of automotive vehicles, such as a bedliner for a pick-up truck. The composition may include, without limitation, an isocyanate component and an amine component and optionally includes one or more of a catalyst, stabilizer, pigment, fire retardant or other additives.

Claims

1. A process for coating a surface of an automotive vehicle, comprising:

a) providing a surface of an automotive vehicle, the surface being part of a bedliner of the automotive vehicle;

b) contacting the surface to form a coating with a composition comprising;

i) a first component that includes an isocyanate component including an aliphatic isocyanate as a major portion of the isocyanate component; and

ii) a second component that is maintained separate from the first component until mixed in a dispenser for application to the surface, the second component including an amine comprised of an amount of at least one aliphatic primary amine and an amount of at least one secondary amine wherein the second component includes at least 40% of an aspartic acid ester by weight;

wherein upon two weeks of water immersion at 32°

C., or exposure to 100% relative humidity at 38°

C., the coating exhibits substantially no blistering, dulling or softening or loss of adhesion, and wherein the coating exhibits substantially no blistering, cracking or charring when sag panel tested for two weeks at about 70°

C.; and

wherein the amount of the at least one secondary amine is between about 40% and about 80% by volume of the second component and the at least one primary amine is between about 10% and about 40% of the second component; and

wherein the coating has a thickness of 1 mm to 10 mm.

2. A process as in claim 1 wherein the isocyanate component is present in the composition from about 30% to about 70% by volume and is at least 90% aliphatic by weight and wherein the step of contacting the surface with the composition includes spraying the composition upon the surface and

wherein the surface is part of a bedliner of an automotive vehicle.

3. A process as in claim 2 wherein the composition is contacted with the surface using an apparatus having a first metering container for receiving the second component, a second metering container for receiving the first component and a nozzle in fluid communication with the first and second containers for spraying the resulting composition.

4. A process as in claim 2 further comprising adding into the composition an effective amount of an agent for controlling static.

5. A process as in claim 2 wherein the at least one primary amine present has a molecular weight greater than about 200 and the at least one secondary has a molecular weight of at least about 190.

6. A process as in claim 5 wherein the isocyanate component has a residual monomer level that is less than about 1% by weight.

7. A process as in claim 6 wherein the composition includes an agent for controlling static that is a metal salt.

8. A process as in claim 1 further comprising adding into the composition a light stabilizer for assisting the coating in resisting degradation due to exposure to light.

9. A process as in claim 1 further comprising adding into the composition a thixotropic agent.

10. A process as in claim 1 wherein at least a portion of the isocyanate component is selected from the group consisting of dicyclohexylmethane 4,4′

-diisocyanate, isophorone diisocyanate, tetramethyl-1,3-xylylene diisocyanate, and hexamethylene diisocyanate.

11. A process as in claim 1 wherein the composition includes conductive carbon black.

12. A process as in claim 1 wherein the second amine is an ester-based amine functional reactive resin having a mole ratio of amine functionality to ester of no more than 1:

1.

13. A process as in claim 1 wherein the composition includes potassium salt as a static controlling agent.

14. A process as in claim 1 wherein the composition includes a thixotropic filler that includes fumed silica.

15. A process for coating a surface of an automotive vehicle bed liner, comprising:

a) providing a surface of an automotive vehicle bed liner;

b) robotically spraying the surface with a composition consisting essentially of;

i) a first component that includes an isocyanate including an aliphatic isocyanate as a major portion of the isocyanate component;

ii) a second component that is maintained separate from the first component until mixed in a dispenser for application to the surface, the second component including an amine in an amount so that the amine and the isocyanate are present in an amount of about 1;

10 to about 10;

1 parts by volume, the amine being comprised of an amount of at least one aliphatic primary amine and an amount of at least one secondary amine; and

iii) a static controlling agent that includes a potassium salt;

wherein the amount of the at least one secondary amine is between about 40% and about 80% by volume of the second component and the at least one primary amine is between about 10% and about 40% of the second component; and

wherein the isocyanate has a residual monomer level that is less than about 1% by weight; and

wherein the coating has a thickness of 1 mm to 10 mm.

16. A process as in claim 15 wherein the resulting coating exhibits substantially no blistering, cracking or charring when sag panel tested for two weeks at about 70°

C.

17. A process as in claim 15 wherein upon two weeks of water immersion at 32°

C., or exposure to 100% relative humidity at 380°

C., the coating exhibits substantially no blistering, dulling or softening or loss of adhesion, and

wherein the coating exhibits substantially no blistering, cracking or charring when sag panel tested for two weeks at about 70°

C.

18. A process as in claim 15 wherein the second component includes at least 40% of an aspartic acid ester by weight.

19. A process as in claim 18 wherein at least a portion of the isocyanate component is selected from the group consisting of dicyclohexylmethane 4,4′

-diisocyanate, isophorone diisocyanate, tetramethyl-1,3-xylylene diisocyanate, hexamethylene diisocyanate.

20. A process as in claim 19, wherein the composition further includes a polyoxyalkylenamine.

21. A process as in claim 15 wherein the composition includes conductive carbon black.

22. A process as in claim 15 wherein the at least one primary amine present has a molecular weight greater than about 200 and the at least one secondary has a molecular weight of at least about 190.

23. A process as in claim 15 wherein:

i) the amount of the at least one secondary amine is between about 40% and about 80% by volume of the second component and the at least one primary amine is between about 10% and about 40% of the second component;

ii) the isocyanate has a residual monomer level that is less than about 1% by weight; and

iii) the second component includes at least 40% of an aspartic acid ester by weight.

24. A process as in claim 15 wherein:

i) the second amine is an ester-based amine functional reactive resin having a mole ratio of amine functionality to ester of no more than 1;

1; and

ii) the composition includes a thixotropic filler that includes fumed silica.

25. A process for coating a surface of an automotive vehicle bed liner, comprising:

a) providing a surface of an automotive vehicle bed liner;

b) robotically spraying the surface with a composition comprising;

i) a first component that includes an isocyanate component including an aliphatic isocyanate as a major portion of the isocyanate component; and

ii) a second component that is maintained separate from the first component until mixed in a dispenser for application to the surface, the second component including a secondary amine that is a aspartic acid ester in an amount so that the amine and the isocyanate are present in an amount of about 1;

10 to about 10;

1 parts by volume, the amine being comprised of an amount of at least one aliphatic primary amine and an amount of at least one secondary amine;

wherein upon two weeks of water immersion at 32°

C., or exposure to 100% relative humidity at 38°

C., the coating exhibits substantially no blistering, dulling or softening or loss of adhesion, and wherein the coating exhibits substantially no blistering, cracking or charring when sag panel tested for two weeks at about 70°

C.; and

wherein the composition forms a polyurea coating; and

wherein the coating has a thickness of 1 mm to 10 mm.

26. A process as in claim 25 wherein at least a portion of the isocyanate component is selected from the group consisting of dicyclohexylmethane 4,4′

-diisocyanate, isophorone diisocyanate, tetramethyl-1,3-xylylene diisocyanate, hexamethylene diisocyanate.

27. A process as in claim 25 further comprising adding into the composition an effective amount of an agent for controlling static.

28. A process as in claim 25 wherein the automotive vehicle is a pick-up truck,

the composition further includes an agent for controlling static, and

the composition is contacted with the surface using an apparatus having a first metering container for receiving the second component, a second metering container for receiving the first component and a nozzle in fluid communication with the first and second containers for spraying the resulting composition.

29. A process as in claim 25 wherein the composition further includes a polyoxyalkylenamine, and one or more additional ingredients for functioning as a catalyst, stabilizer, pigment, fire retardant or other performance or property modifier.

30. A process as in claim 25 wherein the at least one primary amine is present in an amount up to about 50 parts by volume of the second component.

31. A process as in claim 25 wherein the at least one primary amine present has a molecular weight greater than about 200 and the at least one secondary has a molecular weight of at least about 190.

32. A process as in claim 25 wherein the amount of the at least one secondary amine is between about 40% and about 80% by volume of the second component and the at least one primary amine is between about 10% and about 40% of the second component.