Method and apparatus for stand-off chemical detection

• US 7,298,475 B2
• Filed: 08/06/2003
• Issued: 11/20/2007
• Est. Priority Date: 08/22/2002
• Status: Expired due to Fees

• Current Assignee: Secretary of State For Defence
• Original Assignee: Secretary of State For Defence
• Inventors: Gandhi, Sunilkumar Babulal, McAnally, Gerard David, Jeffery, Paul Douglas
• Primary Examiner(s): Lauchman; Layla G.
• Assistant Examiner(s): GEISEL, KARA E
• Application Number:
  US10/524,467
• Publication Number:
  US 20060023211A1
• Time in Patent Office: 1,567 Days
• Field of Search: 356/318
• US Class Current: 356/318
• CPC Class Codes: G01N 2021/1793 Remote sensing
• CPC Class Codes: G01N 2021/3595 using FTIR
• CPC Class Codes: G01N 21/718 Laser microanalysis, i.e. with formation of sample plasma

Abstract

A method, suitable for stand off analysis of a sample (2), comprising: (i) using an excitation means (6) to vaporise the sample (2) thereby producing a vapour plume (10) of molecular species; and (ii) using an analytical means (12) to analyse molecular species within the vapour plume (10) wherein the analytical means (12) analyses the molecular emission spectra of the vapour plume (10). The invention also relates to a kit and an apparatus for use with the same.

Claims

1. A method, suitable for stand off analysis of a sample comprising one or more chemical and/or biological warfare agents of low volatility, said method comprising:

(i) using an excitation means to vaporise the sample thereby producing a vapour plume of molecular species; and

(ii) using an analytical means to analyse the molecular species within the vapour plume wherein the analytical means analyses the molecular emission spectra of the vapour plume and is provided with means to enable it to receive said spectra for stand off analysis.

2. A method according to claim 1 wherein the excitation means is a laser.

3. A method according to claim 2 wherein the laser is operated at a fixed wavelength.

4. A method according to claim 2 wherein the laser has a power of greater than 2 W.

5. A method according to claim 2 wherein the laser has a power of less than 150 W.

6. A method according to claim 2 wherein the laser is operated as continuous laser beam.

7. A method according to claim 2 wherein the laser is a carbon dioxide laser.

8. A method according to claim 1 wherein the method comprises the use of only a single excitation means.

9. A method according to claim 1 wherein the vapour plume is hotter than the surrounding atmosphere by at least 0.1K.

10. A method according to claim 9 wherein the vapour plume is hotter than the surrounding atmosphere by 1K.

11. A method according to claim 10 wherein the vapour plume is hotter than the surrounding atmosphere by 5K.

12. A method according to claim 9 wherein the analytical means is an infrared spectrometer.

13. A kit suitable for stand off analysis of a sample comprising one or more chemical and/or biological warfare agents of low volatility, said kit comprising:

(i) an excitation means arranged such that it can be used to vaporise the sample thereby producing a vapour plume of molecular species;

(ii) an analytical means arranged to analyse the emission spectra of the molecular species within the vapor plume; and

(iii) means associated with the analytical means to enable said analytical means to receive the emission spectra from the vapour plume.

14. An apparatus suitable for stand off analysis of a sample comprising one or more chemical and/or biological warfare agents of low volatility, said apparatus comprising:

(i) an excitation means arranged such that it can be used to vaporise the sample thereby producing a vapour plume of molecular species;

(ii) an analytical means arranged to analyse the emission spectra of the molecular species within the vapour plume; and

(iii) means associated with the analytical means to enable said analytical means to receive the emission spectra from the vapour plume.