Hydrogel for use in downhole seal applications

• US 7,304,098 B2
• Filed: 07/28/2006
• Issued: 12/04/2007
• Est. Priority Date: 02/02/2004
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Zhou, Jian, Li, Yanmei
• Primary Examiner(s): SZEKELY, PETER A
• Application Number:
  US11/460,785
• Publication Number:
  US 20060278391A1
• Time in Patent Office: 494 Days
• Field of Search: 166294-295, 166/270, 523130-131
• US Class Current: 523/130
• CPC Class Codes: C08L 1/28 Alkyl ethers
• CPC Class Codes: C08L 101/00 Compositions of unspecified macromolecular compounds
• CPC Class Codes: C08L 101/14 the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 5/14 Hemicellulose; Derivatives thereof
• CPC Class Codes: C09K 2200/06 Macromolecular organic compounds, e.g. prepolymers
• CPC Class Codes: C09K 2200/0617 Polyalkenes
• CPC Class Codes: C09K 2200/0627 Nitrogen-containing polymers, e.g. polyacrylamide
• CPC Class Codes: C09K 2200/0632 Polystyrenes
• CPC Class Codes: C09K 2200/0657 Polyethers
• CPC Class Codes: C09K 2200/0685 Containing silicon
• CPC Class Codes: C09K 3/10 Materials in mouldable or extrudable form for sealing or packing joints or covers filling pastes C09D5/34
• CPC Class Codes: E21B 33/12 Packers; Plugs used for cementing E21B33/134, E21B33/16

Abstract

The present invention is a composition for forming seals. The composition includes a base material and a hydrogel. The base materials is preferably an elastomer or a thermoplastic. Seals formed with the composition are particularly suited for use in a wellbore environment. The inclusion of hydrogel in the seals allows the seals to be manipulated or altered through certain environmental factors. For instance, temperature, oil/water ratio, pH and the electronic field may all be used to alter the characteristics of the hydrogel. In this way, the seal may be caused to swell in response to a specific stimulus, thereby preventing or sealing a leak without requiring additional work or input from the operator.

Claims

1. A method for forming a seal in a wellbore comprising:

a. providing a composition comprising;

(a) a hydrogel and (b) a base material;

b. deploying the composition into a wellbore; and

,

c. exposing the composition to a first environmental parameter, thereby forming a seal in the wellbore, the seal in a first configuration;

whereby the seal isolates a particular wellbore zone from another wellbore zone or region of a subterranean formation and wherein the seal formed is an o-ring, a t-seal body, a chevron seal body, a spring seal body, a packer element, a gasket, or a bridge plug.

2. The method of claim 1 further comprising exposing the seal to a second environmental parameter causing the seal to form a second configuration.

3. The method of claim 2 further comprising removing the certain environmental parameter thus causing the seal to return the first configuration.

4. The method of claim 1, wherein the base material is a polymer.

5. The method of claim 4, wherein the polymer is an elastomer.

6. The method of claim 5, wherein the elastomer is selected from the group consisting of nitrile rubber, hydrogenated nitrile rubber, carboxyl nitrile rubber, silicon rubber, ethylene-propylene-diene copolymers, fluoroelastomers and perfluoroelastomers.

7. The method of claim 4 wherein the polymer is a thermoplastic.

8. The method of claim 7, wherein the thermoplastic is selected from the group consisting of polytetrafluorethylene, polyetheretherketone, polypropylene, polystyrene and polyphenylene sulfide.

9. The method of claim 1 wherein the hydrogel is selected from the group consisting of:

methylcellulose, cellulose acetate pthalate and hydroxypropyl methylcellulose polymers, poly (ethylene oxide) polymers, guar, derivatized guar, polyacrylamide, silicon-based polymers and fluorosilicone-based polymers.

10. The composition of claim 1 wherein said hydrogel is a metal complex of a polymer selected from the group consisting of:

methylcellulose, cellulose acetate pthalate and hydroxypropyl methylcellulose polymers, poly (ethylene oxide) polymers, guar, derivatized guar, polyacrylamide, silicon-based polymers and fluorosilicone-based polymers.

11. The method of claim 1 wherein the first environmental parameter is selected from the group consisting of water concentration, water/oil concentration, differential pressure, temperature, pH, and electronic field.

12. The method of claim 1 wherein the first environmental parameter is presence of water, and wherein the seal is formed by swelling of the hydrogel.

13. The method of claim 1 wherein the hydrogel is embedded with the base material.

14. The method of claim 1 wherein the hydrogel is coated upon the base material.

15. The method of claim 1 wherein the hydrogel is attached to the base material.

16. The method of claim 1 wherein a blend of the hydrogel and the base material is prepared before the deployment into the wellbore.

17. The method of claim 16 wherein the blend is prepared using techniques selected from the group consisting of:

a solution process;

a mesophase mediated process;

physical mixing/compounding;

injection;

extrusion;

in-situ polymerization; and

melt processing.

18. The method of claim 16 wherein the blend is cured using techniques selected from the group consisting of:

thermal curing;

microwave radiation;

electronic beam radiation.

19. The method of claim 16 wherein the hydrogel is chemically modified to achieve optimum dispersion of the hydrogel polymer.

20. A method for forming a seal in a wellbore comprising:

a. providing a composition comprising;

(a) a hydrogel and (b) a base material;

b. deploying the composition into a wellbore; and

,

c. exposing the composition to a first environmental parameter, thereby forming a seal in the wellbore, the seal in a first configuration;

whereby the seal isolates a particular wellbore zone from another wellbore zone or region of a subterranean formation and wherein the hydrogel is a metal complex of a polymer selected from the group consisting of;

methylcellulose, cellulose acetate pthalate and hydroxypropyl methylcellulose polymers, poly (ethylene oxide) polymers, guar, derivatized guar, polyacrylamide, silicon-based polymers and fluorosilicone-based polymers.