Process to make synthetic leather and synthetic leather made therefrom

• US 7,306,825 B2
• Filed: 06/27/2003
• Issued: 12/11/2007
• Est. Priority Date: 12/20/2002
• Status: Active Grant

• Current Assignee: Dow Europe GmbH (Dow, Inc.)
• Original Assignee: Dow Global Technologies, Inc. (Dow, Inc.)
• Inventors: Mobley, Larry Wayne, Subramanian, Ramki, Skaggs, Kenneth W., Zhou, Weijun, Bhattacharjee, Debkumar, Moore, Roger
• Primary Examiner(s): Fletcher, III, William Phillip
• Assistant Examiner(s): Sellman, Cachet I
• Application Number:
  US10/609,179
• Publication Number:
  US 20040121113A1
• Time in Patent Office: 1,628 Days
• Field of Search: 427/246, 427/394, 427/341, 523/335
• US Class Current: 427/246
• CPC Class Codes: D06N 3/0052 obtained by leaching out of a compound, e.g. water soluble salts, fibres or fillers; obtained by freezing or sublimation; obtained by eliminating drops of sublimable fluid
• CPC Class Codes: D06N 3/14 with polyurethanes
• CPC Class Codes: Y10T 442/20 Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer

Abstract

A synthetic leather is made by a impregnating a non-woven or woven textile with an aqueous polyurethane dispersion comprised of a nonionizable polyurethane and an external stabilizing surfactant. The impregnated textile is then exposed to water containing a coagulant for a coagulation time sufficient to coagulate the dispersion. The method may be used to form a synthetic leather having excellent wet ply adhesion and may contain an insoluble multivalent cation organic acid.

Claims

1. A method for making an impregnated textile synthetic leather, the method comprising:

(a) impregnating a non-woven or woven textile with an externally stabilized dispersion of a nonionizable polyurethane and an external stabilizing surfactant, wherein the nonionizable polyurethane substantially fails to have ionic or nonionic hydrophilic pendant groups, and the polyurethane dispersion is not mixed with another dispersion or emulsion; and

(b) exposing the impregnated textile to water containing a coagulant for a coagulation time sufficient to coagulate the dispersion

wherein the coagulant is a multivalent cation neutral salt.

2. The method of claim 1, wherein the method is carried out in an environment containing less than about 2000 parts per million by weight of an organic solvent.

3. The method of claim 1, wherein the method is carried out essentially free of an organic solvent.

4. The method of claim 1, wherein the coagulant is an alkaline earth cation salt.

5. The method of claim 4, wherein the coagulant is calcium nitrate, magnesium nitrate, strontium nitrate and barium nitrate or mixture thereof.

6. The method of claim 1, wherein the coagulation time is at most 2 minutes.

7. The method of claim 6, wherein the coagulation time is at most 1 minute.

8. The method of claim 7, wherein the coagulation time is at most 30 seconds.

9. The method of claim 1, further comprising leaching the impregnated textile after step (b) by exposing the impregnated textile to water.

10. The method of claim 1, wherein the dispersion of the nonionizable polyurethane contains a thickener.

11. The method of claim 10 wherein the thickener is water soluble thickener that is not ionizable.

12. The method of claim 11 wherein the thickener is a methylcellulose ether.

13. The method of claim 1 further comprising applying a frothed polymeric dispersion after step (b) to form a synthetic leather having a poromeric layer thereon.

14. The method of claim 13 wherein the frothed polymeric dispersion is an aqueous externally stabilized polyurethane dispersion.

15. The method of claim 14 wherein the poromeric layer is heated sufficiently to dry and cure the poromeric layer and then is leached in water.