Method for measuring localized corrosion rate with a multi-electrode array sensor

• US 7,309,414 B2
• Filed: 04/08/2005
• Issued: 12/18/2007
• Est. Priority Date: 04/09/2004
• Status: Active Grant

• Current Assignee: Southwest Research Institute
• Original Assignee: Southwest Research Institute
• Inventors: Yang, Lietai
• Primary Examiner(s): Nguyen, Nam
• Assistant Examiner(s): Vathyam, Surekha
• Application Number:
  US11/102,106
• Publication Number:
  US 20050274628A1
• Time in Patent Office: 984 Days
• Field of Search: 2057755-777, 204/404, 204/412, 324/700, 324/693, 324/71.1
• US Class Current: 205/775.5
• CPC Class Codes: G01N 17/02 Electrochemical measuring systems for weathering, corrosion or corrosion-protection measurement

Abstract

A method of measuring localized corrosion, using a multi-electrode array sensor. The method eliminates the effect of internal current in corroded electrodes, and thus provides a more accurate corrosion measurement. In one embodiment, the potential of a common node of the sensor is adjusted so that the sensor'"'"'s most cathodic current is close to zero.

Claims

1. A method of eliminating the effect of internal current in a multi-electrode array sensor at a corrosion site of interest, the sensor being capable of providing current measurement values from multiple electrodes, comprising:

exposing the sensor to the corrosion at the site of interest;

wherein the sensor has an array of substantially similar metallic electrodes arranged such that each electrode has a surface area operable to be exposed to the corrosion site, and such that each electrode is electrically insulated from other electrodes;

wherein each electrode is operable as an anode or cathode depending on the extent of corrosion at that electrode;

wherein each electrode is electrically connected to a common node, such that the sensor simulates a one-piece electrode surface;

determining an electrical potential value, E_s, for the common node;

wherein E_s is substantially the minimum potential value at which the current measurement values from all electrodes are equal to or less than zero.

2. The method of claim 1, wherein the electrodes are each connected to the common node through a resistor.

3. The method of claim 1, wherein the determining step is performed by determining the voltage at the common node at which the current associated with the most cathodic electrode is substantially zero.

4. The method of claim 1, wherein the determining step is performed by incrementally raising the potential at the common node from open circuit potential to E_s, and measuring currents from the electrodes at each increment.

5. A method of eliminating the effect of internal current in a multi-electrode array sensor when measuring corrosion at a corrosion site of interest, the sensor being capable of providing current measurement values from multiple electrodes, comprising:

exposing the sensor to the corrosion at the site of interest;

wherein the sensor has an array of substantially similar metallic electrodes arranged such that each electrode has a surface area operable to be exposed to the corrosion site, and such that each electrode is electrically insulated from other electrodes;

wherein each electrode is operable as an anode or cathode depending on the extent of corrosion at that electrode;

wherein each electrode is electrically connected to a common node, such that the sensor simulates a one-piece electrode surface;

raising the potential at the common node from open circuit;

measuring currents from the electrodes;

repeating the raising and measuring steps to determine the minimum potential value at which the currents measure zero or less than zero; and

applying the minimum potential value to the common node.