Hydrophilic surfaces carrying temporary protective covers

• US 7,309,527 B2
• Filed: 02/11/2005
• Issued: 12/18/2007
• Est. Priority Date: 09/11/2001
• Status: Expired due to Term

• Current Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Original Assignee: Cardinal CG Company (Cardinal Glass Industries Incorporated)
• Inventors: O'Shaughnessy, Roger D., Krisko, Annette J., Hartig, Klaus
• Primary Examiner(s): Blackwell, G.
• Application Number:
  US11/056,714
• Publication Number:
  US 20050196621A1
• Time in Patent Office: 1,040 Days
• Field of Search: 428/426, 428/432, 428/701, 428/702, 428/699, 428/41.7
• US Class Current: 428/432
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/75 Hydrophilic and oleophilic coatings
• CPC Class Codes: C03C 2218/355 Temporary coating
• CPC Class Codes: Y10T 428/1259 Oxide
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12792 Zn-base component
• CPC Class Codes: Y10T 428/1471 Protective layer

Abstract

A substrate carrying a temporary protective cover and related methods of producing and processing substrates are described. In one embodiment, a substrate bears a hydrophilic coating carrying a temporary protective cover that protects the hydrophilic coating against contamination but that can readily be readily removed from the hydrophilic coating by washing with a given washing fluid.

Claims

1. An insulating glass unit comprising spaced-apart panes having confronting interior surfaces that bound a between-pane space, a desired one of the panes having an exterior surface bearing a hydrophilic coating that is durable to a given washing fluid, the hydrophilic coating carrying a temporary protective cover comprising a sputtered film that is durable to glass tempering and protects the hydrophilic coating against contamination but that can readily be removed from the hydrophilic coating by washing with said washing fluid, wherein the desired pane has an interior surface bearing a low-emissivity coating comprising a metal layer sandwiched between a pair of dielectric layers.

2. The insulating glass unit of claim 1 wherein said panes have been tempered.

3. The insulating glass unit of claim 1 wherein the hydrophilic coating has a contact angle with water of less than about 25 degrees when the cover is removed.

4. The insulating glass unit of claim 1 wherein the sputtered film is stable in the presence of water.

5. The insulating glass unit of claim 4 wherein said washing fluid is a mild acid or a mild base.

6. The insulating glass unit of claim 5 wherein said washing fluid is vinegar.

7. The insulating glass unit of claim 1 wherein the sputtered film comprises an oxide of a metal.

8. The insulating glass unit of claim 7 wherein the sputtered film comprises an oxide of a metal selected from the group consisting of zinc, bismuth, cadmium, iron, and nickel.

9. The insulating glass unit of claim 8 wherein the sputtered film comprises zinc oxide.

10. The insulating glass unit of claim 1 wherein the sputtered film has a thickness of less than about 100 angstroms.

11. The insulating glass unit of claim 10 wherein the sputtered film has a thickness of between about 25 angstroms and about 60 angstroms.

12. The insulating glass unit of claim 1 wherein the sputtered film is formed directly upon the hydrophilic coating.

13. The insulating glass unit of claim 12 wherein the hydrophilic coating is an oxide.

14. An insulating glass unit comprising spaced-apart panes having confronting interior surfaces that bound a between-pane space, a desired one of the panes having an exterior surface bearing a hydrophilic coating, the hydrophilic coating canying a temporary protective cover comprising a sputtered film that is durable to glass tempering and protects the hydrophilic coating against contamination but that can readily be removed from the hydrophilic coating by washing with a weak acid or weak base, wherein the desired pane has an interior surface bearing a low-emissivity coating comprising a metal layer sandwiched between a pair of dielectric layers, wherein the sputtered film comprises an oxide of a metal selected from the group consisting of zinc, bismuth, cadmium, iron and nickel and has a thickness of between about 25 angstroms and about 60 angstroms, wherein the hydrophilic film comprises silicon dioxide and has a thickness of between about 15 angstroms and about 150 angstroms.