Method for treating water by ballasted flocculation and decantation

• US 7,311,841 B2
• Filed: 12/19/2002
• Issued: 12/25/2007
• Est. Priority Date: 12/21/2001
• Status: Expired due to Fees

• Current Assignee: OTV SA SA
• Original Assignee: OTV SA SA
• Inventors: Binot, Patrick, Dahl, Claus Poulsen, Zuback, Joseph Edward
• Primary Examiner(s): Hruskoci, Peter A.
• Application Number:
  US10/499,108
• Publication Number:
  US 20050103719A1
• Time in Patent Office: 1,832 Days
• Field of Search: 210/713
• US Class Current: 210/666
• CPC Class Codes: C02F 1/283 using coal, charred products, or inorganic mixtures containing them
• CPC Class Codes: C02F 1/38 by centrifugal separation
• CPC Class Codes: C02F 1/52 by flocculation or precipitation of suspended impurities C02F1/463 takes precedence
• CPC Class Codes: C02F 1/5281 Installations for water purification using chemical agents
• CPC Class Codes: C02F 2305/12 Inert solids used as ballast for improving sedimentation C02F3/1226 takes precedence

Abstract

The invention concerns a water treatment method which consists in introducing coagulated water in a flocculation zone, to enable flocculation of microflocs in the presence and around a ballast; introducing the mixture in a decantation zone; separating the treated water in overflow and a mixture of sludge and the ballast in underflow; conveying at least part of said mixture to a sludge/ballast separating system and recycling into or upstream of the flocculation zone the ballast and part of the sludge introduced in said separation system. The invention is characterized in that it comprises steps which consists in conveying the mixture to the sludge/ballast separating system; in subjecting said mixture to a ballast concentration, extracting the ballast from the sludge extracted from the separation system; and more than 20% of the volume entering the sludge/ballast separating system is recycled into or upstream of the flocculation zone, after passing through at least part of the sludge/ballast separation system; and the ballast has an effective diameter greater than 60 micrometers, and the sludge extracted from the treatment system has a concentration higher than 5 g/L.

Claims

1. A ballasted flocculation process for purifying water comprising:

a. mixing a coagulant with the water;

b. selecting a ballast in the form of insoluble granular material where the insoluble granular material has an effective diameter between approximately 40 and 300 micrometers;

c. mixing the selected ballast with the water and mixing a flocculant with the water to form flocs and microflocs around the ballast;

d. introducing the mixture of water and flocs into a decantation zone;

e. in the decantation zone, separating purified water from a mix of sludge and ballast;

f. directing the mix of sludge and ballast from the decantation zone to a separator that is operative to separate the sludge and ballast;

g. separating the ballast from the mix of sludge and ballast and recycling the separated ballast to or upstream mixing step c. wherein the separated ballast recycled constitutes 20% or more by volume of the mix of sludge and ballast directed to the separator;

h. separating sludge from the mix of sludge;

i. concentrating the separated sludge, recycling at least a part of the sludge to or upstream mixing step c., and wasting a portion of the sludge wherein the concentration of the sludge wasted is at least 5 g/L; and

j. directing at least some of the mix of sludge and ballast from the decantation zone to an intermediary mixing zone;

directing at least some of the sludge separated by the separator to the intermediary zone and mixing the mix of sludge and ballast with at least a part of the separated sludge;

directing the mixture of the mix of sludge and ballast and the separated sludge from the intermediary mixing zone to the separator and continuing to return separated sludge from the separator to the intermediary mixing zone.

2. The method of claim 1 including directing the mix of sludge and ballast to two or more hydrocyclones that separate the ballast from the sludge.

3. The method of claim 1 including directing the mix of sludge and ballast to a first separator and producing an underflow and an overflow from the first separator, and directing the overflow of the first separator to a second separator and producing an overflow of sludge and an underflow of ballast from the second separator;

and wherein the underflow of the first separator includes a sludge having a volume that is equal to or greater than 10% of the volume of the mix of sludge and ballast directed to the first separator and wherein the underflow of the first separator includes a ballast that comprises by weight 60% or more of the ballast produced in the underflow of the second separator.

4. The method of claim 3 wherein the ratio of the ballast, by weight, in the underflow of the first separator to the weight of the ballast in the underflow of the second separator is at least 90%.

5. The method of claim 3 wherein the first separator includes a non-pressurized simple gravity decanter, and wherein the second separator comprises a hydrocyclone, and wherein there is provided a pump for pumping the overflow of the simple gravity decanter to the hydrocyclone.

6. The method of claim 3 wherein both first and second separators include a hydrocyclone.

7. The method of claim 1 including injecting powdered activated carbon into the water.

8. The method of claim 7 wherein the ballasted flocculation process is carried out in a ballasted flocculation system having a flocculation zone, and wherein the powdered activated carbon is injected into the flocculation zone and mixed with the water, flocculant and ballast.

9. The method of claim 1 including recycling directly a portion of the mix of sludge and ballast from the decantation zone directly into the water being treated without the mix of sludge and ballast being subjected to a separation process carried out by the separator.

10. The method of claim 1 wherein the ballasted flocculation process is carried out in a ballasted flocculation system including a flocculation zone and wherein the method includes injecting powdered activated carbon into the ballasted flocculation system upstream from the flocculation zone.

11. The method of claim 1 including injecting powdered activated carbon into the water and mixing the powdered activated carbon with the flocculant and the ballast, and wherein the method includes recycling at least a portion of the powdered activated carbon to or upstream mixing step c.