Process of preparation of block copolymers and the block copolymers prepared therefrom

• US 7,312,282 B2
• Filed: 07/23/2004
• Issued: 12/25/2007
• Est. Priority Date: 04/01/2004
• Status: Active Grant

• Current Assignee: Atulkumar Ramaniklal Raja, Mukesh Shambhubhai Jesani, Prakash Druman Trivedi
• Original Assignee: Atulkumar Ramaniklal Raja, Mukesh Shambhubhai Jesani, Prakash Druman Trivedi
• Inventors: Trivedi, Prakash Druman, Raja, Atulkumar Ramaniklal, Jesani, Mukesh Shambhubhai
• Primary Examiner(s): Peng, Kuo-Liang
• Application Number:
  US10/897,405
• Publication Number:
  US 20050228149A1
• Time in Patent Office: 1,250 Days
• Field of Search: 525/534, 525/535, 525/906, 528/86, 528/127
• US Class Current: 525/534
• CPC Class Codes: C08F 293/00 Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule on to polymers modified by introduction of unsaturated end groups C08F290/02
• CPC Class Codes: C08F 297/00 Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
• CPC Class Codes: C08G 2261/126 block
• CPC Class Codes: C08G 65/40 from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
• CPC Class Codes: C08G 75/20 Polysulfones
• CPC Class Codes: C08G 75/23 Polyethersulfones
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 53/005 Modified block copolymers
• CPC Class Codes: C08L 81/06 Polysulfones; Polyethersulfones
• CPC Class Codes: Y10S 525/906 Polysulfone

Abstract

Processes for preparing block copolymers and the block copolymers prepared therefrom comprising at least two types of homoblock, all belonging to the polysulfone family, wherein each of the said homoblocks has an identical or different molecular weight of at least 1000 and comprises at least 5% of the overall weight of the block copolymer, and wherein the block copolymer has a molecular weight of at least 2000, the process steps comprising preparing each of the aforesaid homoblocks by reacting at least one aromatic diol with at least one aromatic dihalo compound, one of which contains at least one sulfone group, in at least one aprotic solvent in the presence of at least one alkali, optionally in the presence of an azeotropic agent and then reacting the aforesaid homoblocks together in at least an aprotic solvent, optionally followed by end-capping said block copolymer. The invention also relates to the block copolymers themselves, which are useful for molding, extrusion and can also be used as compatibilizers for their high molecular weight homologues.

Claims

1. A process for preparing a block copolymer, comprising:

preparing at least one first polysulfone homoblock having a molecular weight of at least 1000, comprising heating at least one first aromatic diol compound with at least one first aromatic dihalo compound in the presence of at least one alkali, wherein at least one of the first aromatic diol compound and the first aromatic dihalo compound comprises at least one sulfone group, the first polysulfone homoblock comprising two first end groups;

preparing at least one second polysulfone homoblock having a molecular weight of at least 1000, comprising heating at least one second aromatic diol compound with at least one second aromatic dihalo compound in the presence of at least one alkali, wherein at least one of the second aromatic diol compound and the aromatic dihalo compound comprises at least one sulfone group, the second polysulfone homoblock comprising two second end groups;

reacting the at least one first polysulfone homoblock and the at least one second polysulfone homoblock to produce a reaction mass comprising the block copolymer having a molecular weight of at least 2000; and

recovering the block copolymer from the reaction mass,

wherein each of the two first end groups and the two second end groups comprises two end groups that are different from each other.

2. The process of claim 1, wherein at least one of the two first end groups is the same as or is different from at least one of the two second end groups.

3. The process of claim 2, wherein the two end groups that are different from each other comprise a halogen end group and a hydroxyl end group or a salt of a hydroxyl end group.

4. The process of claim 3, wherein the salt of the hydroxyl end group is selected from the group consisting of —

OK, —

ONa, and —

OLi.

5. The process of claim 3, wherein the halogen end group is selected from the group consisting of —

F, —

Cl, —

Br, and —

I.

6. The process of claim 3, wherein halogen end groups and hydroxyl end groups are present in a ratio of about 1:

1, halogen end groups;

hydroxyl end groups.

7. The process of claim 3, wherein the at least one first aromatic diol compound and the at least one first dihalo compound are present in near equal molar ratio, to produce the at least one first polysulfone homoblock having both a halogen end group and a hydroxyl end group on each homoblock.

8. The process of claim 3, wherein the at least one second aromatic diol compound and the at least one second dihalo compound are present in near equal molar ratio, to produce the at least one second polysulfone homoblock having both a halogen end group and a hydroxyl end group on each homoblock.