FCC process with improved yield of light olefins

• US 7,312,370 B2
• Filed: 12/10/2002
• Issued: 12/25/2007
• Est. Priority Date: 11/13/2000
• Status: Expired due to Term

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Pittman, Rusty M., Upson, Lawrence L.
• Primary Examiner(s): DANG, THUAN D
• Application Number:
  US10/316,222
• Publication Number:
  US 20030121825A1
• Time in Patent Office: 1,841 Days
• Field of Search: 585/648, 585/649, 585/650, 585/651, 585/653, 208/118, 208/119, 208/120.1
• US Class Current: 585/648
• CPC Class Codes: C07C 4/06 Catalytic processes C07C4/025 takes precedence
• CPC Class Codes: C10G 11/05 Crystalline alumino-silicates, e.g. molecular sieves
• CPC Class Codes: C10G 11/18 according to the "fluidised-bed" technique

Abstract

An FCC process for obtaining light olefins comprises contacting a hydrocarbon feed stream with blended catalyst comprising regenerated catalyst and coked catalyst. The catalyst has a composition including a first component and a second component. The second component comprises a zeolite with no greater than medium pore size wherein the zeolite comprises at least 1 wt-% of the catalyst composition. The contacting occurs in a riser to crack hydrocarbons in the feed stream and obtain a cracked stream containing hydrocarbon products including light olefins and coked catalyst. The cracked stream is passed out of an end of the riser such that the hydrocarbon feed stream is in contact with the blended catalyst in the riser for less than or equal to 2 seconds on average. The hydrocarbon products including light olefins are separated from the coked catalyst. The first portion of the coked catalyst is passed to a regeneration zone in which coke is combusted from the catalyst to produce a regenerated catalyst. A second portion of the coked catalyst is blended with the regenerated catalyst and introduced to the riser. The regenerated catalyst has substantially the same relative proportions of the first component and the second component as the blended catalyst that contact the hydrocarbon feed stream.

Claims

1. A process for fluidized catalytic cracking of a hydrocarbon feed stream to obtain light olefins, the process comprising contacting said hydrocarbon feed stream with a catalyst having a composition including at least 1.0 wt-% of a zeolite having no greater than medium average pore size and said catalyst including at least 0.1 wt-% coke, said contacting occurring in a single reactor for no more than 2 seconds at a hydrocarbon partial pressure of no more than 172 kPa (25 psia).

2. The process of claim 1 wherein said single reactor is a riser.

3. The process of claim 1 wherein said catalyst is at a temperature of about 621°

to 677°

C. (1150°

to 1250°

F.) before contacting the feed stream.

4. The process of claim 1 further comprising regenerating only a portion of said catalyst.

5. The process of claim 1 further comprising recovering a vapor product from said single reactor comprising at least 20 wt-% propylene.

6. The process of claim 1 further comprising recovering a vapor product from said single reactor comprising less than or equal to 4 wt-% dry gas.

7. The process of claim 1 wherein said contacting yields at least 60 wt-% conversion.

8. The process of claim 1 wherein the ratio of catalyst to feed in the reactor is greater than or equal to 10.

9. A process for fluidized catalytic cracking of a hydrocarbon feed stream to obtain light olefins, the process comprising:

contacting said hydrocarbon feed stream with a mixture of coked and regenerated catalyst having a composition including at least 1.0 wt-% of a zeolite having no greater than medium average pore size, said contacting occurring in a single reactor for no more than 2 seconds at a hydrocarbon partial pressure of no more than 172 kPa (25 psia) to obtain coked catalyst;

separating hydrocarbon products from said coked catalyst;

regenerating a portion of said coked catalyst to obtain regenerated catalyst;

passing said regenerated catalyst back to said reactor; and

passing another portion of said coked catalyst back to said reactor.

10. The process of claim 9 wherein said single reactor is a riser.

11. The process of claim 9 wherein said catalyst is at a temperature of about 621°

to 677°

C. (1150°

to 1250°

F.) before contacting the feed stream.

12. The process of claim 9 further comprising recovering a vapor product from said single reactor comprising at least 20 wt-% propylene.

13. The process of claim 9 further comprising recovering a vapor product from said single reactor comprising less than or equal to 4 wt-% dry gas.

14. The process of claim 9 wherein said contacting yields at least 60 wt-% conversion.

15. A process for fluidized catalytic cracking of a hydrocarbon feed stream to obtain light olefins, the process comprising contacting said hydrocarbon feed stream with a catalyst having a composition including at least 1.0 wt-% of a zeolite having no greater than medium average pore size and said catalyst including at least 0.1 wt-% coke, said contacting occurring in a single reactor for no more than 2 seconds at a hydrocarbon partial pressure of no more than 172 kPa (25 psia) and a ratio of catalyst to feed in the reactor of greater than or equal to 10.

16. The process of claim 15 wherein said catalyst is at a temperature of about 621°

to 677°

C. (1150°

to 1250°

F.) before contacting the feed stream.

17. The process of claim 15 further comprising regenerating only a portion of said catalyst.

18. The process of claim 15 further comprising recovering a vapor product from said single reactor comprising at least 20 wt-% propylene.

19. The process of claim 15 further comprising recovering a vapor product from said single reactor comprising less than or equal to 4 wt-% dry gas.

20. The process of claim 15 wherein said contacting yields at least 60 wt-% conversion.