Reversible electro-optic device employing aprotic molten salts and method

• US 7,317,106 B2
• Filed: 04/22/2004
• Issued: 01/08/2008
• Est. Priority Date: 05/05/2003
• Status: Expired due to Fees

• Current Assignee: Los Alamos National Security LLC (Government of the United States of America)
• Original Assignee: Los Alamos National Security LLC (Government of the United States of America)
• Inventors: Burrell, Anthony K., Warner, Benjamin P., McCleskey, T. Mark, Hall, Simon B.
• Primary Examiner(s): Saeed; Kamal A.
• Application Number:
  US10/831,572
• Publication Number:
  US 20040227983A1
• Time in Patent Office: 1,356 Days
• Field of Search: 548/335.1
• US Class Current: 548/335.1
• CPC Class Codes: C07D 295/023 Preparation; Separation; Stabilisation; Use of additives
• CPC Class Codes: G02F 1/1506 caused by electrodeposition, e.g. electrolytic deposition of an inorganic material on or close to an electrode

Abstract

A single-compartment reversible mirror device having a solution of aprotic molten salt, at least one soluble metal-containing species comprising metal capable of being electrodeposited, and at least one anodic compound capable of being oxidized was prepared. The aprotic molten salt is liquid at room temperature and includes lithium and/or quaternary ammonium cations, and anions selected from trifluoromethylsulfonate (CF₃SO₃⁻), bis(trifluoromethylsulfonyl)imide ((CF₃SO₂)₂N⁻), bis(perfluoroethylsulfonyl)imide ((CF₃CF₂SO₂)₂N⁻) and tris(trifluoromethylsulfonyl)methide ((CF₃SO₂)₃C⁻). A method for preparing substantially pure molten salts is also described.

Claims

1. A method for preparing a substantially pure aprotic molten salt, comprising generating impure aprotic molten salt from cation precursor and anion precursor and passing the impure molten salt through alumina or silica, whereby substantially pure molten salt is prepared, wherein said impure molten salt is generated by preparing an aqueous mixture of cation precursor and decolorizing agent selected from the group consisting of charcoal and activated carbon, filtering the mixture, combining the filtrate with anion precursor to form an impure molten salt, and removing water from the impure molten salt.

2. A method for preparing a substantially pure aprotic molten salt, comprising generating impure aprotic molten salt from cation precursor and anion precursor and passing the impure molten salt through alumina or silica, whereby substantially pure molten salt is prepared, wherein said aprotic molten salt is liquid at room temperature and comprises at least one cation selected from group consisting of lithium cation and quatemary ammonium cations, and at least one anion selected from the group consisting of trifluoromethylsulfonate (CF₃SO₃⁻

), bis(trifluoromethylsulfonyl)imide ((CF₃SO₂)₂N⁻

), bis(perfluoroethylsulfonyl)imide ((CF₃CF₂SO₂)₂N⁻

) and tris(trifluoromethylsulfonyl)methide ((CF₃SO₂)₃C⁻

).

3. The method of claim 2, wherein said quaternary ammonium cations are selected from the group consisting of pyridinium, pyridazinium, pyrimidinium, pyrazinium, imidazolium, pyrazolium, thiazolium, oxazolium, triazolium, tetraalkylammonium, and N-methyl morpholinium cations.

4. The method of claim 2, wherein said quaternary ammonium cations comprise the formula [(CH₃CH₂)₃N(R₁)]⁺, wherein R₁ is alkyl having 2-10 carbons;

or comprise the formula [(CH₃)₂(CH₃CHCH₃)N(R₂)]⁺, wherein R₂ is alkyl having 2-10 carbons;

or comprise the structural formula