Bipolar battery and method for manufacturing the same

• US 7,320,846 B2
• Filed: 04/28/2004
• Issued: 01/22/2008
• Est. Priority Date: 06/12/2003
• Status: Active Grant

• Current Assignee: Nissan Motor Co., Ltd.
• Original Assignee: Nissan Motor Co., Ltd.
• Inventors: Nemoto, Kouichi, Hosaka, Kenji, Watanabe, Kyoichi
• Primary Examiner(s): Crepeau; Jonathan
• Assistant Examiner(s): Chuo; Tony
• Application Number:
  US10/833,058
• Publication Number:
  US 20040253512A1
• Time in Patent Office: 1,364 Days
• Field of Search: 429/210
• US Class Current: 429/210
• CPC Class Codes: H01M 10/0413 Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
• CPC Class Codes: H01M 10/0418 with bipolar electrodes
• CPC Class Codes: H01M 10/044 with bipolar electrodes
• CPC Class Codes: H01M 10/0472 Vertically superposed cells with vertically disposed plates
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/0565 Polymeric materials, e.g. gel-type or solid-type
• CPC Class Codes: H01M 10/0585 of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
• CPC Class Codes: H01M 2004/029 Bipolar electrodes
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 2300/0085 Immobilising or gelification of electrolyte
• CPC Class Codes: H01M 4/131 Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/133 Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/1391 of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/1393 of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/483 for non-aqueous cells H01M4/485 takes precedence
• CPC Class Codes: H01M 4/587 for inserting or intercalating light metals
• CPC Class Codes: H01M 4/667 in the form of layers, e.g. coatings
• CPC Class Codes: H01M 50/3425 in the form of rupturable membranes or weakened parts, e.g. pierced with the aid of a sharp member
• CPC Class Codes: H01M 6/48 with bipolar electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 : Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y02T 10/70 : Energy storage systems for electromobility, e.g. batteries
• CPC Class Codes: Y10T 29/4911 : including sealing
• CPC Class Codes: Y10T 29/49112 : including laminating of indefinite length material
• CPC Class Codes: Y10T 29/49114 : including adhesively bonding

Abstract

A bipolar battery includes a bipolar electrode and an electrolyte layer. The bipolar electrode includes a current collector, a positive electrode layer formed on one surface of the current collector, and a negative electrode layer formed on the other surface of the current collector. The bipolar electrode is sequentially laminated to provide connection in series via the electrolyte layer to form a stack structure. The positive electrode layer, the negative electrode layer and the electrolyte layer are potted with a resin portion.

Claims

1. A bipolar battery comprising:

a bipolar electrode provided with;

a current collector;

a positive electrode layer formed on one surface of the current collector; and

a negative electrode layer formed on the other surface of the current collector;

an electrolyte layer permitting the bipolar electrode to be sequentially laminated through the electrolyte layer so as to be connected in series to form a stack structure;

a resin portion with which the positive electrode layer, the negative electrode layer and the electrolyte layer are potted substantially entirely in a stacking direction;

a first outermost current collector outside the positive electrode layer that is disposed outermost in the series; and

a second outermost current collector outside the negative electrode layer that is oppositely disposed outermost in the series,

wherein each of the first outermost current collector and the second outermost current collector is 2 to 50 times greater in thickness than the current collector,

wherein at least a part of the current collector to be associated with the positive electrode layer, the negative electrode layer and the electrolyte layer is potted with the resin portion and a residual portion of the current collector is exposed from the resin portion to form an exposed portion, and

wherein the exposed portion of the current collector serves as a voltage detection tab and an output tab.

2. The bipolar battery according to claim 1, wherein the exposed portion of the current collector permits the detection tab to be extendable in any one of a first direction along which an electrode tab of the bipolar battery extends and a second direction different from the first direction.

3. The bipolar battery according to claim 1, wherein the resin portion includes resin with a hardness JIS A falling in a value ranging from 5 to 95.

4. The bipolar battery according to claim 1, wherein the resin portion includes resin with dielectric-tangent in a range equal to or greater than 1.0×

10<sup>−

3</sup> and equal to or less than 5.0×

10<sup>−

1</sup> under a temperature range equal to or greater than −

30°

C. and equal to or less than 80°

C. at a frequency equal to or greater than 10 Hz and equal to or less than 1 kHz.

5. The bipolar battery according to claim 1, wherein resin of the resin portion is selected from epoxy family resin, urethane family resin, nylon family resin, olefin family resin or combinations thereof.

6. The bipolar battery according to claim 1, wherein the resin portion includes a thinned portion with a thinned potting thickness.

7. The bipolar battery according to claim 6, wherein the thinned portion of the resin portion is formed in correspondence with the electrolyte layer.

8. The bipolar battery according to claim 1, wherein the positive electrode layer includes positive electrode material composed of Li—

Mn composite oxides.

9. The bipolar battery according to claim 1, wherein the negative electrode layer includes negative electrode material composed of any one of crystalline carbon material and amorphous carbon material.

10. The bipolar battery according to claim 1, wherein the bipolar battery is sequentially connected in any one of series, parallel and series and parallel in combination to form a battery module.

11. The bipolar battery according to claim 10, wherein the battery module (50) is installed on a vehicle as a power supply.

12. The bipolar battery according to claim 10, wherein the battery module is sequentially connected in any one of series, parallel and series and parallel in combination to form a combined battery.

13. The bipolar battery according to claim 12, wherein the combined battery is installed on a vehicle as a power supply.

14. A bipolar battery comprising:

a bipolar electrode provided with;

a current collector;

a positive electrode layer formed on one surface of the current collector; and

a negative electrode layer formed on the other surface of the current collector;

an electrolyte layer permitting the bipolar electrode to be sequentially laminated through the electrolyte layer so as to be connected in series to form a stack structure;

potting means for potting the positive electrode layer, the negative electrode layer and the electrolyte layer substantially entirely in a stacking direction;

a first outermost current collecting means outside the positive electrode layer that is disposed outermost in the series; and

a second outermost current collecting means outside the negative electrode layer that is oppositely disposed outermost in the series,

wherein each of the first outermost current collecting means and the second outermost current collecting means is 2 to 50 times greater in thickness than the current collector,

wherein at least a part of the current collector to be associated with the positive electrode layer, the negative electrode layer and the electrolyte layer is potted with the potting means and a residual portion of the current collector is exposed from the potting means to form an exposed portion, and

wherein the exposed portion of the current collector serves as a voltage detection tab and an output tab.

15. A method of manufacturing a bipolar battery, comprising:

preparing a bipolar electrode provided with;

a current collector;

a positive electrode layer formed on one surface of the current collector; and

a negative electrode layer formed on the other side surface of the current collector;

sequentially laminating the bipolar battery through an electrolyte layer so as to provide connection in series;

potting the positive electrode layer, the negative electrode layer and the electrolyte layer substantially entirely in a stacking direction;

preparing a first outermost current collector outside the positive electrode layer that is disposed outermost in the series; and

preparing a second outermost current collector outside the negative electrode layer that is oppositely disposed outermost in the series,

wherein each of the first outermost current collector and the second outermost current collector is 2 to 50 times greater in thickness than the current collector,

wherein at least a part of the current collector to be associated with the positive electrode layer, the negative electrode layer and the electrolyte layer is potted with a resin portion and a residual portion of the current collector is exposed from the resin portion to form an exposed portion, and

wherein the exposed portion of the current collector serves as a voltage detection tab and an output tab.