Synthesis of composite nanofibers for applications in lithium batteries

• US 7,323,218 B2
• Filed: 04/21/2003
• Issued: 01/29/2008
• Est. Priority Date: 12/30/2002
• Status: Expired due to Fees

• Current Assignee: Industrial Technology Research Institute
• Original Assignee: Industrial Technology Research Institute
• Inventors: Huang, Hsiu-Wen, Hsieh, Chien-Te, Lin, Hung-Hsiao, Huang, Yue-Hao, Shih, Han-Chang, Liao, Shih-Chieh, Liu, Mao-Huang, Chen, Jin-Ming
• Primary Examiner(s): FLETCHER III, WILLIAM P
• Application Number:
  US10/419,167
• Publication Number:
  US 20040126305A1
• Time in Patent Office: 1,744 Days
• Field of Search: 427/181, 427/206, 427/230, 427/237, 427/571, 427/574, 427/575, 427/576, 427/578, 427/248.1, 427/255.15, 427/255.7, 427/282, 427/430.1, 427/437, 427/443.1, 977890-893, 205/131, 205/135, 205/161
• US Class Current: 427/181
• CPC Class Codes: D01F 9/12 Carbon filaments; Apparatus specially adapted for the manufacture thereof
• CPC Class Codes: Y10S 977/89 Deposition of materials, e.g. coating, cvd, or ald
• CPC Class Codes: Y10S 977/891 Vapor phase deposition
• CPC Class Codes: Y10S 977/892 Liquid phase deposition
• CPC Class Codes: Y10S 977/893 Deposition in pores, molding, with subsequent removal of mold

Abstract

Methods of fabricating one-dimensional composite nanofiber on a template membrane with porous array by chemical or physical process are disclosed. The whole procedures are established under a base concept of “secondary template”. First of all, tubular first nanofibers are grown up in the pores of the template membrane. Next, by using the hollow first nanofibers as the secondary templates, second nanofibers are produced therein. Finally, the template membrane is removed to obtain composite nanofibers. Showing superior performance in weight energy density, current discharge efficiency and irreversible capacity, the composite nanofibers are applied to extensive scopes like thin-film battery, hydrogen storage, molecular sieving, biosensor and catalyst support in addition to applications in lithium batteries.

Claims

1. A method for fabricating composite nanofibers, comprising the steps of:

forming a plurality of tubular first nanofibers in a plurality of nano-scale pores of a template;

placing the template on a conductive current collector;

forming a plurality of second nanofibers on inner surfaces of the first nanofibers; and

removing the template and obtaining a plurality of composite nanofibers.

2. The method for fabricating composite nanofibers according to claim 1 wherein the template is polycarbonate membrane or anodic alumina membrane.

3. The method for fabricating composite nanofibers according to claim 1 wherein the first nanofibers are formed through a process selected from the group consisting of sol-gel method, chemical impregnation, electroless plating, electro-deposition and electron cyclotron resonance-chemical vapor deposition.

4. The method for fabricating composite nanofibers according to claim 1 wherein the second nanofibers are formed through a process selected from the group consisting of sol-gel method, chemical impregnation, electroless plating, electro deposition and election cyclotron resonance-chemical vapor deposition.

5. The method for fabricating composite nanofibers according to claim 1 wherein the step of forming the first nanofibers further comprises a previous step of embedding a fast precursor in the template.

6. The method for fabricating composite nanofibers according to claim 5 wherein thickness of the first nanofiber is controlled by concentration of the first precursor.

7. The method for fabricating composite nanofibers according to claim 5 wherein the first precursor is selected from the group consisting of polymers, inorganic matters, metal oxide and carbon.

8. The method for fabricating composite nanofibers according to claim 1 wherein the step of forming the second nanofibers further comprises a previous step or embedding a second precursor in the template.

9. The method for fabricating composite nanofibers according to claim 8 wherein the second precursor is selected from the group consisting of polymers, inorganic matters, metal oxide and carbon.

10. The method for fabricating composite nanofibers according to claim 1 wherein material of the first nanofibers is silicon or carbon.

11. The method for fabricating composite nanofibers according to claim 1 wherein material of the second nanofibers is selected from the group consisting or Si, Sn, Ni, Cu, AO_x and SnM_y, in which A=Si, Sn, Sb, Co, Cu, Fe, Ni, Zn;

0<

x<

2;

M=Sb, Cu, Mg, Si;

0<

y<

2.

12. The method for fabricating composite nanofibers according to claim 1 wherein the template is removed through a process of chemical etching or plasma etching.

13. The method for fabricating composite nanofibers according to claim 1 wherein aspect ratios of the composite nanofiber are within 10 to 1000.

14. The method for fabricating composite nanofibers according to claim 1 wherein inner diameters of the composite nanofiber are within 10 to 700 nanometers, and outer diameters are within 50 to 800 nanometers.