Diaphragm for electrolytic cell

• US 7,329,332 B2
• Filed: 07/20/2005
• Issued: 02/12/2008
• Est. Priority Date: 08/25/2004
• Status: Active Grant

• Current Assignee: General Electric Company
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Schussler, Henry W.
• Primary Examiner(s): Bell; Bruce F.
• Application Number:
  US11/184,967
• Publication Number:
  US 20060042936A1
• Time in Patent Office: 937 Days
• Field of Search: 204/283, 204/252, 204/263, 204/266, 204/296, 205/350, 205/687, 427/243, 427/244, 427/245, 427/247
• US Class Current: 204/283
• CPC Class Codes: C25B 13/08 based on organic materials

Abstract

Describes a cathode assembly for electrolytic cells, e.g., chlor-alkali electrolytic cells, comprising a foraminous cathode substrate, a deposited erodible mat comprising synthetic (man-made) fibers, e.g., polyamide (nylon) fibers, on the foraminous surface of said cathode substrate, and a synthetic diaphragm on said erodible mat. Also described is a method for preparing the cathode assembly that comprises depositing a mat of erodible synthetic fibers on the active surface of the foraminous cathode, e.g., by drawing an aqueous slurry of the erodible synthetic fibers through the foraminous cathode, and subsequently forming, e.g., by vacuum deposition, a synthetic diaphragm on the erodible mat.

Claims

1. A cathode assembly for an electrolytic cell comprising a foraminous cathode substrate, a deposited liquid-permeable erodible mat comprising synthetic fibers on a surface of said cathode substrate, and a synthetic diaphragm on said synthetic fiber-containing erodible mat.

2. The cathode assembly of claim 1 wherein the synthetic fibers are chosen from aliphatic polyamide fibers, aromatic polyamide fibers, rayon fibers, acetate fibers, triacetate fibers, acrylic fibers, polyolefin fibers, polyester fibers, polyphenylene sulfide fibers, and mixtures of said fibers.

3. The cathode assembly of claim 2 wherein the aliphatic polyamide fibers are chosen from nylon 6, nylon 6-6, nylon 11, nylon 6-10 and mixtures of said nylon fibers;

the aromatic polyamide fibers are chosen from the polyamides prepared from isophthalic acid and m-phenylene diamine;

the acrylic fibers are chosen from fibers prepared from polyacrylonitrile;

the polyolefin fibers are chosen from polyethylene fibers, polypropylene fibers and mixtures of said polyolefin fibers; and

the polyester fibers are chosen from fibers prepared from ethylene glycol and dimethyl terephthalate or terephthalic acid.

4. The cathode assembly of claim 1 wherein the liquid-permeable erodible synthetic mat is superimposed on the electrolytically active surface of the cathode substrate, and the synthetic diaphragm is appended to the liquid-permeable erodible synthetic mat.

5. The cathode assembly of claim 1 wherein the electrolytic cell is a chlor-alkali electrolytic cell.

6. The cathode assembly of claim 5 wherein the synthetic fibers of the liquid-permeable erodible mat are chosen from aliphatic polyamide fibers, aromatic polyamide fibers and mixtures of said polyamide fibers.

7. The cathode assembly of claim 6 wherein the synthetic diaphragm is substantially free of asbestos, and the synthetic diaphragm has applied to it a top coat of water-insoluble, inorganic particulate material.

8. A cathode assembly for a chlor-alkali electrolytic cell comprising a foraminous metallic cathode substrate, a vacuum deposited liquid-permeable erodible mat comprising aliphatic polyamide fibers appended to an electrolytically active portion of the foraminous surface of said cathode substrate, and a synthetic non-asbestos-containing diaphragm appended to said mat.

9. The cathode assembly of claim 8 wherein the erodible mat has a thickness of from 0.1 to 3.3 millimeters.

10. The cathode assembly of claim 8 wherein the chlor-alkali electrolytic cell is an electrolytic cell for the electrolysis of aqueous solutions of sodium chloride.

11. The cathode assembly of claim 10 wherein the aliphatic polyamide fibers are chosen from nylon 6, nylon 6-6, nylon 6-10, nylon 11, and mixtures of said nylon fibers.

12. The cathode assembly of claim 11 wherein the aliphatic polyamide fibers have a length of from 1 to 12.7 millimeters and a denier of from 1 to 50.

13. The cathode assembly of claim 12 wherein the aliphatic polyamide fibers have a length of from 3 to 6.5 millimeters and a denier of from 10 to 20, and the erodible mat has a thickness of from 0.14 to 1.2 millimeters.

14. A method of preparing a cathode assembly for use in an electrolytic cell comprising:

(a) depositing a mat comprising synthetic erodible fibers on the surface of a foraminous cathode, thereby to form a liquid-permeable mat on the foraminous cathode, and

(b) forming a synthetic diaphragm on said mat.

15. The method of claim 14 wherein the synthetic erodible fibers are chosen from aliphatic polyamide fibers, aromatic polyamide fibers, rayon fibers, acetate fibers, triacetate fibers, acrylic fibers, polyolefin fibers, polyester fibers and polyphenylene sulfide fibers.

16. The method of claim 15 wherein the aliphatic polyamide fibers are chosen from nylon 6, nylon 6-6, nylon 11, nylon 6-10 and mixtures of said nylon fibers;

the aromatic polyamide fibers are chosen from the polyamides prepared from isophthalic acid and m-phenylene diamine;

the acrylic fibers are chosen from fibers prepared from polyacrylonitrile;

the polyolefin fibers are chosen from polyethylene fibers, polypropylene fibers and mixtures of said polyolefin fibers; and

the polyester fibers are chosen from fibers prepared from ethylene glycol and dimethyl terephthalate or terephthalic acid.

17. The method of claim 14 wherein the electrolytic cell is a chlor-alkali electrolytic cell.

18. The method of claim 17 wherein the synthetic fibers of the liquid-permeable erodible mat are chosen from aliphatic polyamide fibers and aromatic polyamide fibers, and the synthetic diaphragm is substantially free of asbestos.

19. The method of claim 18 wherein the chlor-alkali electrolytic cell is an electrolytic cell for the electrolysis of aqueous solutions of sodium chloride, and the aliphatic polyamide fibers are chosen from nylon 6, nylon 6-6, nylon 6-10, nylon 11, and mixtures of said nylon fibers.

20. The method of claim 19 wherein the aliphatic polyamide fibers have a length of from 3 to 6.5 millimeters and a denier of from 10 to 20, and the slurry has a viscosity of from 500 to 800 centipoises, said slurry containing from 0.1 to 3 percent by weight of the aliphatic polyamide fibers.

21. A method of preparing a cathode assembly for use in a chlor-alkali electrolytic cell comprising:

(a) depositing a liquid-permeable mat comprising synthetic erodible fibers on an electrolytically active surface of a foraminous metallic cathode, said mat having a thickness of from 0.1 to 3.3 millimeters, and

(b) appending a synthetic diaphragm to said erodible mat.

22. The method of claim 21 wherein the synthetic erodible fibers are chosen from aliphatic polyamide fibers, aromatic polyamide fibers, rayon fibers, acetate fibers, triacetate fibers, acrylic fibers, polyolefin fibers, polyester fibers and polyphenylene sulfide fibers.

23. The method of claim 22 wherein the electrolytic cell is an electrolytic cell for the electrolysis of aqueous solutions of sodium chloride, and the aliphatic polyamide fibers are chosen from nylon 6, nylon 6-6, nylon 11, nylon 6-10 and mixtures of said nylon fibers;

the aromatic polyamide fibers are chosen from the polyamides prepared from isophthalic acid and m-phenylene diamine;

the acrylic fibers are chosen from fibers prepared from polyacrylonitrile;

the polyolefin fibers are chosen from polyethylene fibers, polypropylene fibers and mixtures of said polyolefin fibers; and

the polyester fibers are chosen from fibers prepared from ethylene glycol and dimethyl terephthalate or terephthalic acid.

24. The method of claim 23 wherein the aliphatic polyamide fibers have a length of from 1 to 12.7 millimeters and denier of from 1 to 50.