Preform and method of repairing nickel-base superalloys and components repaired thereby

• US 7,335,427 B2
• Filed: 12/17/2004
• Issued: 02/26/2008
• Est. Priority Date: 12/17/2004
• Status: Expired due to Fees

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Sathian, Sujith
• Primary Examiner(s): McNeil; Jennifer C.
• Assistant Examiner(s): Savage; Jason L.
• Application Number:
  US10/905,143
• Publication Number:
  US 20060134454A1
• Time in Patent Office: 1,166 Days
• Field of Search: None
• US Class Current: 428/668
• CPC Class Codes: B22F 1/09 Mixtures of metallic powders
• CPC Class Codes: B22F 7/062 involving the connection or repairing of preformed parts
• CPC Class Codes: B23P 6/005 using only replacement pieces of a particular form
• CPC Class Codes: C23C 10/28 using solids, e.g. powders, pastes
• CPC Class Codes: C23C 10/52 more than one element being diffused in one step
• CPC Class Codes: C23C 26/00 Coating not provided for in groups C23C2/00 - C23C24/00
• CPC Class Codes: F01D 5/005 Repairing methods or devices
• CPC Class Codes: F05D 2230/232 by welding
• CPC Class Codes: F05D 2230/236 Diffusion bonding
• CPC Class Codes: Y10T 428/12042 Porous component
• CPC Class Codes: Y10T 428/12063 Nonparticulate metal component
• CPC Class Codes: Y10T 428/12181 Composite powder [e.g., coated, etc.]
• CPC Class Codes: Y10T 428/12861 Group VIII or IB metal-base component
• CPC Class Codes: Y10T 428/12931 Co-, Fe-, or Ni-base components, alternative to each other
• CPC Class Codes: Y10T 428/12944 Ni-base component

Abstract

A process for repairing a turbine component of a turbomachine, as well as a sintered preform used in the process and a high gamma-prime nickel-base superalloy component repaired thereby. The sintered preform contains a sintered mixture of powders of a cobalt-base braze alloy and a cobalt-base wear-resistant alloy. The braze alloy constitutes at least about 10 up to about 35 weight percent of the sintered preform and contains a melting point depressant such as boron. The preform is formed by mixing powders of the braze and wear-resistant alloys to form a powder mixture, and then sintering the powder mixture. To use the preform, a surface portion of the turbine component is removed to expose a subsurface portion, followed by diffusion bonding of the preform to the subsurface portion to form a wear-resistant repair material containing the braze alloy dispersed in a matrix of the wear-resistant alloy.

Claims

1. A sintered preform consisting essentially of a sintered mixture of powders comprising a cobalt-base braze alloy and a cobalt-base wear-resistant alloy, the cobalt-base braze alloy constituting about 10 to about 35 weight percent or the sintered preform and containing a sufficient amount of boron so that the cobalt-base braze alloy has a melting temperature of about 1090°

C. to about 1230°

C., wherein;

the cobalt-base braze alloy consists of, by weight, about 22.00 to about 24.75% chromium, about 9.0 to about 11.0% nickel, about 6.5 to about 7.6% tungsten, about 3.0 to 4.0% tantalum, about 2.60 to 3.16% boron, about 0.55 to about 0.65% carbon, about 0.15 to 0.30% titanium, about 0.30 to 0.60% zirconium, up to 1.3% iron, up to 0.4% silicon, up to 0.10% manganese, up to 0.015% sulfur, and the balance cobalt and incidental impurities;

the cobalt-base wear-resistant alloy consists of, by weight,

about 26.0 to about 30.0% chromium, about 18.0 to about 21.0% tungsten, about 4.0 to about 6.0% nickel, about 0.75 to about 1.25% vanadium, about 0.7 to about 1.0% carbon, up to 3.0% iron, up to 1.0% manganese, up to 0.5% molybdenum, up to 1.0% silicon, up to 0.05% boron, and the balance cobalt and incidental impurities; and

the sintered preform has a porosity of less than 2 volume percent as a result of being subjected to compression to promote fusion and reduce porosity during sintering.

2. The sintered preform according to claim 1, wherein the sintered preform is attached to a gas turbine engine component formed of a nickel-base superalloy having a gamma-prime content of about 55 to about 59 volume percent.

3. The sintered preform according to claim 2, wherein the nickel-base superalloy consists of, by weight, about 9.5 to about 10 chromium, about 7 to about 8 cobalt, about 3.35 to about 3.65 titanium, about 4.1 to about 4.3 aluminum, about 5.75 to about 6.25 tungsten, about 1.30 to about 1.70 molybdenum, about 4.60 to about 5.0 tantalum, about 0.06 to about 0.1 carbon, about 0.0080 to about 0.010 zirconium, about 0.008 to about 0.0105 boron, and the balance being nickel and incidental impurities.

4. The sintered preform according to claim 1, wherein the cobalt-base braze alloy consists of, by weight, about 24% chromium, about 10.8% nickel, about 7.5% tungsten, about 4.0% tantalum, about 2.7% boron, about 0.6% carbon, about 0.25% titanium, and the balance cobalt and incidental impurities.

5. The sintered preform according to claim 1, wherein the cobalt-base wear-resistant alloy consists of, by weight, about 28% chromium, about 19.5% tungsten, about 5% nickel, about 1% vanadium, about 0.85% carbon, and the balance cobalt and incidental impurities.