Low-cost on-line and in-line spectral sensors based on solid-state source and detectors combinations for monitoring lubricants and functional fluids

• US 7,339,657 B2
• Filed: 10/11/2002
• Issued: 03/04/2008
• Est. Priority Date: 10/11/2001
• Status: Active Grant

• Current Assignee: Sentelligence, Inc.
• Original Assignee: Sentelligence, Inc.
• Inventors: Coates, John
• Primary Examiner(s): EVANS, FANNIE L
• Application Number:
  US10/492,660
• Publication Number:
  US 20040201835A1
• Time in Patent Office: 1,971 Days
• Field of Search: 356/73, 356/417, 356/436
• US Class Current: 356/73
• CPC Class Codes: G01N 2021/3129 Determining multicomponents by multiwavelength light
• CPC Class Codes: G01N 2021/3155 Measuring in two spectral ranges, e.g. UV and visible
• CPC Class Codes: G01N 21/0303 Optical path conditioning in cuvettes, e.g. windows; adapted optical elements or systems; path modifying or adjustment G01N21/031 - G01N21/15 take precedence
• CPC Class Codes: G01N 21/31 Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry G01N21/72 takes precedence
• CPC Class Codes: G01N 21/33 using ultraviolet light G01N21/39 takes precedence
• CPC Class Codes: G01N 21/359 using near infrared light
• CPC Class Codes: G01N 21/53 within a flowing fluid, e.g. smoke
• CPC Class Codes: G01N 21/552 Attenuated total reflection
• CPC Class Codes: G01N 21/64 Fluorescence; Phosphorescence
• CPC Class Codes: G01N 21/8507 Probe photometers, i.e. with optical measuring part dipped into fluid sample
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

A series of optical spectral sensors is based on a combination of solid-state sources (illumination) and detectors housed within an integrated package that includes the interfacing optics and acquisition and processing electronics. The focus is on low cost and the fabrication of the sensor is based on techniques that favor mass production. Materials and components are selected to support low-cost, high volume manufacturing of the sensors. Spectral selectivity is provided by the solid-state source(s) thereby eliminating the need for expensive spectral selection components. The spectral response covers the range from the visible (400 nm) to the mid-infrared (25,000 nm/25.0 μm), as defined by the availability of suitable low-cost solid-state source devices. A refractive optical system is employed, primarily in an internal reflection mode, allowing a selection of sample handling tools, including, but not restricted to internal reflectance and transmittance. A secondary channel allowing for light scattering or fluorescence methods is an option. The targeted applications of the sensing devices are for lubricants and functional fluids in the heavy equipment, automotive and transportation industries. A source reference channel is included to provide measurement stability and temperature compensation.

Claims

1. An optical spectral sensing device, for determining properties of a sample, said device comprising:

an integrated solid-state source and solid-state detector package,

an optical structure with a substantially conical cross-section, for contacting said sample material;

coupling apparatus for coupling said integrated solid-state source and solid-state detector to said optical structure; and

integrated electronics for providing energy for said source and for receiving a signal generated by said detector in response to energy coupled to said detector by said coupling apparatus, said integrated electronics providing direct output of sample properties of said sample.

2. The device of claim 1, wherein said optical structure is formed in configurations that allow for at least one of internal reflectance when a sample is in contact with an external surface of the structure, or transmittance, or fluorescence or light scattering measurements of a sample in a channel in the structure.

3. The device of claim 1, wherein said optical structure is fabricated from a glass or plastic that can be machined, polished or molded to provide a circular base with either a conical cross-section in the form of a cone with an apex, or a truncated cone.

4. The device of claim 1, further comprising opposing flat facet surfaces between which energy is reflected.

5. The device of claim 4, wherein when a plurality of faceted surface pairs exists, the angles of the facets for the individual pairs may be different to facilitate angle tuning of the optical structure.

6. The device of claim 3, further comprising a cylindrical base, wherein the cylindrical base facilitates sealing, and wherein if said cylindrical base is formed as an extended base, said cylindrical base functions as said coupling apparatus.

7. The device of claim 1, wherein said optical structure has more than one set of tuned facet pairs between which light is reflected, thereby extending dynamic range for measurements of said sample.

8. The device of claim 1, wherein said optical structure is comprised of a glass or a plastic having a refractive index to match the measurement requirements of a selected application.

9. The device of claim 1, wherein said optical structure includes channels, slots or cavities that allow the sample to pass between two opposing optical faces formed in the optical structure, thereby enabling measurements by at least one of optical transmission or optical light scattering.

10. The device of claim 9, wherein in the optical transmission mode energy passes a first face of the optical structure and into the sample, traverses the sample and re-enters the optical structure at an opposing face.

11. The device of claim 9, wherein in an optical scattering mode, energy passes a first face of the optical structure into the sample, interacts with the sample, and any scattering that results from this interaction is observed through a base of a cavity in the optical structure, said energy propagating at 90°

with respect to normal passage of energy through the sample.

12. The device of claim 1, wherein said source and detector are located at matched positions to provide an optimum passage of energy through said optical structure utilizing at least one of internal reflection, light transmission and light scattering.

13. The device of claim 1, wherein in the case of scattering by the sample or fluorescence of the sample, the detector is mounted in a central position to receive scattered or fluorescent energy.

14. The device of claim 12, wherein the integration of the source and detector constitutes the formation of an integrated internal sensing module to complement the optical structure.

15. The device of claim 1, having an integrated internal sensing module containing said solid state source and said solid state detector package, wherein said source comprises a solid-state device, primarily designed to emit light or energy with a maximum energy at a center wavelength defined by the device.

16. The device of claim 1, wherein said optical structure, and said package are housed within an enclosure that protects internal components from the operating environment and the sample.

17. The device of claim 16, wherein said enclosure is fabricated from a single piece of material in the form of a molding or extrusion, or is fabricated from two or more parts to provide a device that can be disassembled for servicing.

18. The device of claim 17, wherein said device is disposable.

19. The device of claim 16, wherein said, enclosure is constructed of a thermally insulating material to reduce the internal heat within the sensor, or said enclosure is structured externally to include cooling fins or structures to dissipate heat from the device.

20. An integrated sensing module having a source and a principal detector comprising a solid-state device either matched directly in spectral response to said source, or capable of responding to wavelengths over a broad spectral range from one or more sources, sensitive in spectral regions of mid-to long wavelength near infrared (1100 nm to 2500 nm) and mid-infrared (2.5 μ

m to 25 μ

m, 2.500 nm to 25000 nm), wherein said detector is located in either a primary location in the module for the detection of source radiation from internal reflection or transmission measurements, or a secondary location at the center or close to the center of the module, for the detection of radiation from fluorescence or from energy scattered from a fluid from under study.

21. The sensing module of claim 20, further comprising an optical system including a reference detector arranged to accept energy directly from the source.

22. The sensing module of claim 20, further comprising an optical structure for coming into contact with a sample to be measured, and a base containing said source and said detector, said optical structure and said base being mechanically keyed to one another to assure alignment between said optical structure and said source and detector on said base.

23. The sensing module of claim 21, wherein said reference detector operates with balancing electronics to reduce or eliminate temperature dependent changes in performance of said optical system.

24. The sensing module of claim 22, further comprising an optical system including a reference detector arranged to accept energy directly from the source, wherein said reference detector provides a ratio of energy detected by said principal detector and energy obtained from the reference detector, thereby providing a direct measure of the energy absorbed by the sample and said optical structure.

25. The sensing module of claim 20, wherein said optical system includes more than one source-detector pair.

26. The sensing module of claim 25, wherein sources are adjacent to each other or share a common optical path through a main optical structure, whereby one or more detectors mounted in matched positions on the sensing module detects energy passing through the main optical structure.

27. The sensing module of claim 20, further comprising a conical optical stucture for coming into contact with a sample to be measured, including more than one source-detector pair, the sources in said source-detector pairs being in different locations and taking different paths through said conical optical structure, as defined by different locations on said conical optical structure or by different reflections between facet pairs on the conical optical structure, so that the sources utilize different detectors in locations matched to respective source location.

28. The sensing module of claim 26, wherein wavelengths emitted by the sources form a plurality of wavelengths thereby enabling more than one analysis to be performed, or where analysis can be performed in the event that a condition being monitored provides different independent responses at different wavelengths, said sensor module providing an output for either multiple components or measurement of a complex condition by use of modeling techniques.

29. The sensing module of claim 20, further comprising an optical structure;

and additional optics, in the form of small lenses or light conduits or optical fibers, to improve optical interfacing between the source and detector devices and the optical structure, thereby improving measurement efficiency and accuracy.

30. The sensing module of claim 29, wherein the sensing module is located away from the optical structure.

31. The sensing module of claim 30, further comprising supplemental thermal insulation to reduce impact of heat on the sensing module.

32. The sensing module of claim 20, wherein the source is a light emitting diode and output from the light emitting diode is modulated and regulated under thermal management to ensure an extended operational lifetime for the light emitting diode.

33. The sensing module of claim 20, further comprising a processor for processing the signal produced from the detector.

34. The sensing module of claim 33, further comprising built-in or downloaded calibration coefficients for said processor.

35. The sensing module of claim 33, wherein said processor further comprises at least one of:

a computation means for performing computations including concentration calculations;

processing of intelligent sensor outputs; and

support for standard data formats, standard protocols and standard forms of communications, including serial and bus-oriented communications formats.

36. The sensing module of claim 27 wherein the wavelengths emitted by the solid-state sources form a plurality of wavelengths thereby enabling more than one analysis to be performed, or where a more complex analysis can be performed in the event that a condition being monitored provides different independent responses at different wavelengths, said sensor module providing an output for either multiple components or the measurement of a complex condition by use of modeling techniques.