Substrate coated with a composite film, method for making same and uses thereof

• US 7,348,054 B2
• Filed: 07/25/2002
• Issued: 03/25/2008
• Est. Priority Date: 07/25/2001
• Status: Expired due to Fees

• Current Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Original Assignee: Saint-Gobain Glass France (Compagnie De Saint-Gobain)
• Inventors: Jacquiod, Catherine, Berquier, Jean-Marc, Boilot, Jean-Pierre, Besson, Sophie, Gacoin, Thierry, Ricolleau, Christian
• Primary Examiner(s): McNeil; Jennifer
• Assistant Examiner(s): Speer; Timothy M.
• Application Number:
  US10/484,721
• Publication Number:
  US 20040219348A1
• Time in Patent Office: 2,070 Days
• Field of Search: 428/304.4, 428/312.2, 428/312.6, 428/315.5, 428/315.7, 428/318.4, 428/319.1, 428/312.8, 428/446, 428/428, 428/688, 428/702, 977/773, 977/811
• US Class Current: 428/312.2
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 2217/425 consisting of a porous layer
• CPC Class Codes: C03C 2217/45 Inorganic continuous phases
• CPC Class Codes: C03C 2217/475 Inorganic materials
• CPC Class Codes: Y10S 977/811 Of specified metal oxide composition, e.g. conducting or semiconducting compositions such as ITO, ZnOx
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/249967 Inorganic matrix in void-containing component
• CPC Class Codes: Y10T 428/249969 Of silicon-containing material [e.g., glass, etc.]
• CPC Class Codes: Y10T 428/24997 Of metal-containing material
• CPC Class Codes: Y10T 428/24999 Inorganic

Abstract

This substrate is coated with a composite film based on a mesoporous mineral layer containing nanoparticles formed in situ inside the layer. The composite film has a periodic lattice structure over a major portion of the thickness in which the nanoparticles are present, in which structure the nanoparticles are arranged in a periodic manner on the scale of domains of at least 4 periods in the thickness of the film.

This structure can be obtained from a mesoporous mineral layer of periodic structure on the scale of domains of at least 4 periods of pores, forming a matrix on the substrate, by:

• • depositing at least one precursor in the pores of the matrix layer; and
  • growing particles derived from the precursor with the spatial distribution and the dimensions being controlled by the structure of the pores of the matrix.

Applications to materials for electronics, nonlinear optics and magnetism.

Claims

1. A substrate coated with a composite film based on a mesoporous mineral layer comprising nanoparticles formed in situ inside the layer, wherein the composite film has a periodic lattice structure over a major portion of the thickness in which the nanoparticles are present, in which structure the nanoparticles are arranged in a periodic manner on the scale of domains of at least 4 periods in the thickness of the film.

2. The coated substrate as claimed in claim 1, wherein the periodic lattice is at least two-dimensional.

3. The coated substrate as claimed in claim 1, wherein the periodic structure of the composite film is obtained from a mesoporous mineral layer of periodic structure on the scale of domains of at least 4 periods of pores, forming a matrix on the substrate, by:

depositing at least one precursor in the pores of the matrix layer; and

growing particles derived from the precursor with the spatial distribution and the dimensions being controlled by the structure of the pores of the matrix.

4. The coated substrate as claimed in claim 3, wherein the periodic structure of the composite film is obtained by impregnation of the matrix layer with a liquid composition comprising at least one precursor and a liquid vehicle, and controlled growth of particles derived from the precursor.

5. The coated substrate as claimed in claim 1, wherein the substrate is made up of a mineral material or an organic material.

6. The coated substrate as claimed in claim 5, wherein the substrate is made up of a mineral material selected from the group consisting of glass, silica, and ceramic.

7. The coated substrate as claimed in claim 5, wherein the substrate is made up of a plastic organic material.

8. The coated substrate as claimed in claim 1, wherein the composite film has a thickness of 10 nm to 10 μ

m.

9. The coated substrate as claimed in claim 8, wherein the composite film has a thickness of from 50 nm to 5 μ

m.

10. The coated substrate as claimed in claim 1, wherein the mesoporous mineral layer is based on at least one metal oxide.

11. The coated substrate as claimed in claim 10, wherein the mesoporous mineral layer is obtained by:

bringing the substrate into contact with a liquid composition comprising at least one oxide precursor and at least one organic agent; and

precipitating and polycondensing the oxide around the structuring agent.

12. The coated substrate as claimed in claim 10, wherein the mesoporous mineral layer has a pore lattice structure having three-dimensional symmetry.

13. The coated substrate as claimed in claim 1, wherein the nanoparticles comprise compounds chosen from metals, chalcogenides, oxides, halides, phosphides and organic compounds.

14. The coated substrate as claimed in claim 1, wherein the nanoparticles are composite particles, consisting of a core and a peripheral material.

15. The coated substrate as claimed in claim 1, wherein the volume fraction occupied by the nanoparticles in the domain or domains is around 10 to 70% of the volume of the domain.

16. A solar concentrator comprising the coated substrate according to claim 1.