Enhancing thermal conductivity of fluids with graphite nanoparticles and carbon nanotube

• US 7,348,298 B2
• Filed: 12/08/2003
• Issued: 03/25/2008
• Est. Priority Date: 05/30/2002
• Status: Expired due to Term

• Current Assignee: VGP IPCO LLC
• Original Assignee: Ashland Licensing and Intellectual Property Llc
• Inventors: Lockwood, Frances E., Zhang, Zhiqiang
• Primary Examiner(s): Caldarola; Glenn
• Assistant Examiner(s): GOLOBOY, JAMES C
• Application Number:
  US10/730,762
• Publication Number:
  US 20040209782A1
• Time in Patent Office: 1,569 Days
• Field of Search: 508/113, 977/742, 977/745
• US Class Current: 508/113
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C10M 125/02 Carbon; Graphite
• CPC Class Codes: C10M 141/06 at least one of them being an organic nitrogen-containing compound
• CPC Class Codes: C10M 169/04 Mixtures of base-materials and additives
• CPC Class Codes: C10M 2201/041 Carbon; Graphite; Carbon black
• CPC Class Codes: C10M 2205/0285 used as base material
• CPC Class Codes: C10M 2215/28 Amides; Imides
• CPC Class Codes: C10N 2020/06 Particles of special shape or size
• CPC Class Codes: C10N 2020/063 Fibrous forms
• CPC Class Codes: C10N 2070/00 Specific manufacturing methods for lubricant compositions
• CPC Class Codes: Y10S 977/742 Carbon nanotubes, CNTs
• CPC Class Codes: Y10S 977/745 having a modified surface

Abstract

A fluid media such as oil or water, and a selected effective amount of carbon nanomaterials necessary to enhance the thermal conductivity of the fluid. One of the preferred carbon nanomaterials is a high thermal conductivity graphite, exceeding that of the neat fluid to be dispersed therein in thermal conductivity, and ground, milled, or naturally prepared with mean particle size less than 500 nm, and preferably less than 200 nm, and most preferably less than 100 nm. The graphite is dispersed in the fluid by one or more of various methods, including ultrasonication, milling, and chemical dispersion. Carbon nanotubes with graphitic structure is another preferred source of carbon nanomaterial, although other carbon nanomaterials are acceptable. To confer long term stability, the use of one or more chemical dispersants is preferred. The thermal conductivity enhancement, compared to the fluid without carbon nanomaterial, is proportional to the amount of carbon nanomaterials (carbon nanotubes and/or graphite) added.

Claims

1. A thermally enhanced fluid composition, comprising:

an effective amount of a selected neat fluid having a selected thermal conductivity;

an effective amount of from 0.001 to 10 percent by weight of a selected carbon nanomaterial having an aspect ratio of from 500 to 5000 dispersed into said selected neat fluid, said selected carbon nanomaterial having a thermal conductivity greater than the thermal conductivity of said selected neat fluid in which the carbon nanomaterial is dispersed; and

an effective amount of at least one chemical dispersing agent having a low hydrophile-lipophile balance (HLB) value of 8 or less.

2. The thermally enhanced composition of claim 1 wherein said carbon nanomaterial is surface treated to be hydrophilic at surface for ease of dispersing into the aqueous medium.

3. The thermally enhanced composition of claim 1 wherein the said dispersing agent is soluble in the said neat fluid.

4. The thermally enhanced composition of claim 1 wherein said neat fluid is selected from the group consisting of a petroleum distillate and a synthetic petroleum oil.

5. The thermally enhanced composition of claim 1, wherein said chemical dispersing agent is a surfactant.

6. The thermally enhanced composition of claim 5, wherein said surfactant is selected from the group consisting of a ionic surfactant and a mixture of a nonionic and ionic surfactant.

7. The thermally enhanced composition of claim 1, wherein said dispersing agent is a dispersant-detergent (DI) additive package.

8. The thermally enhanced composition of claim 1 wherein said neat fluid is a uniform dispersion in a form as a gel or paste.

9. The thermally enhanced composition of claim 1, wherein said neat fluid is a grease.

10. The composition of claim 1, wherein said carbon nanomaterial comprises carbon nanotubes and graphite nanoparticles.

11. The thermally enhanced composition of claim 1, wherein said carbon nanomaterial is selected from the group consisting of carbon nanotubes, graphite nanoparticles, and combinations thereof.

13. The thermally enhanced fluid composition of claim 1, wherein an effective amount of a selected carbon nanomaterial to obtain the desired thermal enhancement is from 0.01 to 5 percent by weight.

14. The thermally enhanced fluid composition of claim 1, including a selected amount of oil.

15. The thermally enhanced fluid composition of claim 1, wherein said effective amount of a selected carbon nanomaterial is from 0.001 to 2.0 percent by weight.

16. The thermally enhanced fluid composition of claim 1, wherein said selected carbon nanomaterial has a thermal conductivity exceeding 80 W/m-K.

17. The thermally enhanced fluid composition of claim 1, wherein said neat fluid comprises a petroleum liquid medium selected from the group consisting of a petroleum distillate, a synthetic petroleum oil, a grease, a gel, a oil-soluble polymer composition, and combinations thereof.

18. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from the group consisting of Group I (solvent refined mineral oils), Group II (hydrocracked mineral oils), Group III (severely hydrocracked hydrogenated oils), Group IV (polyalphaolefins), Group VI (esters, naphthenes, and polyalkylglycols), and combinations thereof.

19. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from the group of synthetic hydrocarbon oils, halo-substituted hydrocarbon oils, polymerized and interpolymerized olefins, polybutylenes, polypropylenes, propylene-isobutylene copolymers, chlorinated polybutylenes, poly(1-octenes), poly(1-decenes), alkylbenzenes, dodecylbenzenes, tetradecylbenzenes, dinonylbenzenes, di-(2-ethylhexyl)benzenes, polyphenyls, biphenyls, terphenyls, alkylated polyphenyls, alkylated diphenyl, ethers, alkylated diphenyl sulfides, and combinations thereof.

20. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from the group consisting of the esters of dicarboxylic acids selected from the group consisting of phtalic acid, succinic acid, alkyl succinic acids and alkenyl succinic acids, maleic acid, azelaic acid, suberic acid, sebacic acid, fumaric acid, adipic acid, alkenyl malonic acids, with an alcohols selected from the group consisting of butyl alcohol, hexyl alcohol, dodecyl alcohol, 2-ethylhexyl alcohol, ethylene glycol diethylene glycol monoether, propylene glycol, dibutyl adipate, di(2-ethylhexyl) sebacate, di-hexyl fumarate, dioctyl sebacate, diisooctyl azelate, diisodecyl azealate, dioctyl phthalate, didecyl phthalate, dicicosyl sebacate, the 2-ethylhexyl diester of linoleic acid dimer, the complex ester formed by reacting one mole of sebacic acid with two moles of tetraethylene glycol and two moles of 2-ethylhexanoic acid, and combinations thereof.

21. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from the group consisting of esters made from C₅ to C₁₂ monocarboxylic acids and polyols and polyol ethers such as neopentyl glycol, trimethylolpropane, pentaerythritol, dipentaerythritol, tripentaerythritol, and combinations thereof.

22. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from a polyalphaolefins having a viscosity of up to 100 centistoke at 100°

C.

23. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from the group of synthetic based oil ester additives consisting of polyolesters, diesters, di-aliphatic diesters of alkyl carboxylic acids, di-2-ethylhexylazelate, di-isodecyladipate, di-tridecyladipate, and combinations thereof.

24. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from the group of diesters consisting of an aliphatic diester of a dicarboxylic acid, a dialkyl aliphatic diester of an alkyl dicarboxylic acid, a di-2-ethyl hexyl azelate, a di-isodecyl azelate, a di-tridecyl azelate, a di-isodecyl adipate, a di-tridecyl adipate, and combinations thereof.

25. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from a hydrogenated oil having a sulfur level less than 0.03 with saturates greater than or equal to 90 and a viscosity index of greater than or equal to 120.

26. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is a hydrogenated oil having a viscosity of from 2 to 60 CST at 100 degrees centigrade.

27. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is a hydrogenated oil present in an amount of up to 99 percent by volume.

28. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from the water-based group consisting of an alcohol and its derivatives.

29. The thermally enhanced fluid composition of claim 1, wherein said neat fluid is selected from the water-based group consisting of an ethylene glycol, a propylene glycol, a methyl alcohol, an ethyl alcohol, a propyl alcohol, an isopropyl alcohol, and combinations thereof.

30. The thermally enhanced fluid composition of claim 1, wherein said dispersants are selected from the group consisting of an lipophilic hydrocarbon group, and a polar functional hydrophilic group.

31. The thermally enhanced fluid composition of claim 30, wherein said polar functional hydrophilic group is selected from the class of carboxylate, ester, amine, amide, imine, imide, hydroxyl, ether, epoxide, phosphorus, ester carboxyl, anhydride, or nitrile.

32. The thermally enhanced fluid composition of claim 1, wherein said dispersant is an ashless dispersant typically used in the petroleum industry selected from the group consisting of N-substituted polyisobutenyl succinimides and succinates, allkyl methacrylate-vinyl pyrrolidinone copolymers, alkyl methacrylate-dialkylaminoethyl methacrylate copolymers, alkylmethacrylate-polyethylene glycol methacrylate copolymers, and polystearamides.

33. The thermally enhanced fluid composition of claim 1, wherein an effective amount of said dispersant present in an amount of from 0.001 to 30 percent by weight.

34. The thermally enhanced fluid composition of claim 1, wherein an effective amount of said dispersant present in an amount of from between 0.5 percent to 20 percent weight.

35. The thermally enhanced fluid composition of claim 1, wherein an effective amount of said dispersant present in an amount of from between 2 to 6 weight percent by weight.

36. The thermally enhanced fluid composition of claim 1, including an effective amount of a viscosity improver selected from the group consisting of an olefin copolymers (OCP), a polymethacrylates (PMA), a hydrogenated styrene-diene (STD), a styrene-polyester (STPE) polymers, and an olefin copolymer.

37. The thermally enhanced fluid composition of claim 1, including an effective amount of at least one pour point depressant selected from the group consisting of an alkylnaphthalene, an acrylic copolymer, a polymethacrylate, a polyfumarates, a styrene ester, an oligomerized alkylphenol, a phthalic acid ester, an ethylenevinyl acetate copolymer, and other mixed hydrocarbon polymers.

38. The thermally enhanced fluid composition of claim 1, including an effective amount of a rust and oxidation inhibitor.

39. The thermally enhanced fluid composition of claim 1, including an effective amount of a demulsifier.

40. The thermally enhanced fluid composition of claim 1, including an effective amount of a foam inhibitor.

41. The thermally enhanced fluid composition of claim 1, including an effective amount of a seal swelling agent.

12. A thermally enhanced fluid composition, comprising:

an effective amount of a selected neat fluid having a selected thermal conductivity;

an effective amount of a selected carbon nanomaterial having a selected thermal conductivity up to 20 percent by weight having an aspect ratio of from 500 to 5000 dispersed into said selected neat fluid, said selected carbon nanomaterial having a thermal conductivity greater than the thermal conductivity of said selected neat fluid in which the carbon nanomaterial is dispersed; and

an effective amount of at least one chemical dispersing agent having a low hydrophile-lipophile balance (HLB) value of 8 or less.

42. A method of thermally enhancing the conductivity of a fluid composition, comprising the steps of:

selecting a neat fluid having a selected thermal conductivity;

selecting a carbon nanomaterial having an aspect ratio of from 500 to 5000 in an effective amount of from 0.001 to 10 percent by weight;

dispersing said selected carbon nanomaterial having a thermal conductivity greater than the thermal conductivity of said selected neat fluid in which the carbon nanomaterial is dispersed into said neat fluid; and

adding at least one chemical dispersing agent having a low hydrophile-lipophile balance (HLB) value of 8 or less thereto forming a thermally enhanced fluid.

43. The method of claim 42, including the step of shearing said thermally enhanced fluid containing dispersed nanomaterial.

44. The method of claim 43, wherein said shearing step is selected from the group of processing methods consisting of creating a turbulent flow through a nozzle, creating a turbulent flow thorough a high pressure fuel injector, an ultrasonic device, and combinations thereof to achieve a stable viscosity.

45. A method of thermally enhancing the conductivity of a fluid composition, comprising the steps of:

selecting a neat fluid having a selected thermal conductivity;

selecting a carbon nanomaterial having an aspect ratio of from 500 to 5000 in an effective amount of from 0.001 to 10 percent by weight;

selecting at least one chemical dispersing agent having a low hydrophile-lipophile balance (HLB) value of 8 or less;

dissolving said at least one chemical dispersing agent into said neat fluid forming a liquid medium dispersing fluid;

adding said carbon nanomaterial into said liquid medium dispersing fluid while being agitated or ultrasonicated forming a thermally enhanced fluid composition.

46. The method of thermally enhancing the conductivity of a fluid composition of claim 45, including the step of further shearing said thermally enhanced fluid composition containing nanomaterial.

47. The method of claim 46, wherein said shearing step is selected from the group of processing methods consisting of creating a turbulent flow through a nozzle, creating a turbulent flow thorough a high pressure fuel injector, an ultrasonic device, and combinations thereof to achieve a stable viscosity.

48. A method of thermally enhancing the conductivity of a fluid composition, comprising the steps of:

selecting a neat fluid having a selected thermal conductivity;

selecting a carbon nanomaterial having an aspect ratio of from 500 to 5000 in an effective amount of from 0.001 to 10 percent by weight;

selecting at least one chemical dispersing agent having a low hydrophile-lipophile balance (HLB) value of 8 or less;

dissolving said carbon nanomaterial into said neat fluid forming a liquid medium;

adding said chemical dispersing agent into said liquid medium simultaneously while being agitated or ultrasonicated.

49. The method of thermally enhancing the conductivity of a fluid composition of claim 48, including the step of further shearing said thermally enhanced fluid composition containing nanomaterial.

50. The method of claim 49, wherein said shearing step is selected from the group consisting of creating a turbulent flow through a nozzle, creating a turbulent flow thorough a high pressure fuel injector, an ultrasonic device, and combinations thereof to achieve a stable viscosity.