Electrically conductive compositions and method of manufacture thereof

• US 7,354,988 B2
• Filed: 11/11/2005
• Issued: 04/08/2008
• Est. Priority Date: 08/12/2003
• Status: Expired due to Fees

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Rajagopalan, Srinivasan, Elkovitch, Mark D., Mutha, Nitin, Shaikh, Abbas Alli, Charati, Sanjay Gurbasappa, Dhara, Dibakar, Ghosh, Soumyadeb
• Primary Examiner(s): BOYKIN, TERRESSA M
• Application Number:
  US11/270,953
• Publication Number:
  US 20060069199A1
• Time in Patent Office: 879 Days
• Field of Search: 423/447.1, 423/447.2, 428/36.9, 428/67, 428/36.91, 428/408, 524/496, 528/271, 528/272
• US Class Current: 528/271
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C08G 63/00 Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule polyester-amides C08G69/44; polyester-imides C08G73/16
• CPC Class Codes: C08G 63/199 Acids or hydroxy compounds containing cycloaliphatic rings
• CPC Class Codes: C08K 2201/011 Nanostructured additives
• CPC Class Codes: C08K 7/24 inorganic
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: Y10T 428/139 Open-ended, self-supporting conduit, cylinder, or tube-type article
• CPC Class Codes: Y10T 428/1393 Multilayer [continuous layer]
• CPC Class Codes: Y10T 428/22 Nonparticulate element embedded or inlaid in substrate and visible
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A method for manufacturing a conductive composition comprises blending a polymer precursor with a single wall carbon nanotube composition; and polymerizing the polymer precursor to form an organic polymer. The method may be advantageously used for manufacturing automotive components, computer components, and other components where electrical conductivity properties are desirable.

Claims

1. A method for manufacturing a conductive composition comprising:

blending a polymer precursor with a single wall carbon nanotube composition, the single wall nanotube composition comprising carbon nanotubes that have a single wall; and

polymerizing the polymer precursor to form an organic polymer; and

wherein the composition has an electrical bulk volume resistivity less than or equal to about 10¹² ohm-cm, and a notched Izod impact strength greater than or equal to about 5 kilojoules/square meter.

2. The method of claim 1 wherein the composition has an electrical surface resistivity less than or equal to about 10¹² ohm/square.

3. The method of claim 1, wherein the organic polymer is a polyacetal, a polyacrylic, a polyalkyd, a polyacrylate, a polycarbonate, a polystyrene, a polyester, a polyamide, a polyaramid, a polyamideimide, a polyarylate, a polyarylsulfone, a polyethersulfone, a polyphenylene sulfide, a polysulfone, a polyimide, a polyetherimide, a polytetrafluoroethylene, a polyetherketone, a polyether etherketone, a polyether ketone ketone, a polybenzoxazole, a polyoxadiazole, a polybenzothiazinophenothiazine, a polybenzothiazole, a polypyrazinoquinoxaline, a polypyromellitimide, a polyquinoxaline, a polybenzimidazole, a polyoxindole, a polyoxoisoindoline, a polydioxoisoindoline, a polytriazine, a polypyridazine, a polypiperazine, a polypyridine, a polypiperidine, a polytriazole, a polypyrazole, a polycarborane, a polyoxabicyclononane, a polydibenzofuran, a polyphthalide, a polyacetal, a polyanhydride, a polyvinyl ether, a polyvinyl thioether, a polyvinyl alcohol, a polyvinyl ketone, a polyvinyl halide, a polyvinyl nitrile, a polyvinyl ester, a polysulfonate, a polysulfide, a polythioester, a polysulfone, a polysulfonamide, a polyurea, a polyphosphazene, a polysilazane, or a combination comprising at least one of the foregoing thermoplastic polymers.

4. T he method of claim 1, further comprising carbon nanotubes, wherein the carbon nanotubes are multiwall carbon nanotubes, vapor grown carbon fibers, or a combination comprising at least one of the foregoing types of carbon nanotubes;

the multiwall carbon nanotubes and the vapor grown carbon fibers comprise carbon nanotubes that have at least two graphene layers.

5. The method of claim 1, wherein the single wall carbon nanotube composition comprises about 30 to about 99 wt % metallic carbon nanotubes.

6. The method of claim 1, wherein the single wall carbon nanotube composition comprises about 30 to about 99 wt % semi-conducting carbon nanotubes.

7. The method of claim 1, wherein at least a portion of the single wall carbon nanotube composition is derivatized with functional groups.

8. The method of claim 1, wherein the single wall carbon nanotube composition comprises at least a portion of single wall carbon nanotubes derivatized with functional groups either on a side-wall or on a hemispherical end.

9. The method of claim 1, wherein the single wall carbon nanotube composition comprises at least a portion of single wall carbon nanotubes having no hemispherical ends attached thereto or has a single hemispherical end attached thereto.

10. The method of claim 1, wherein the blending is accomplished through sonicating.

11. The method of claim 10, further comprising adding a solvent prior to sonication.

12. The method of claim 1, wherein the blending is accomplished in a solution comprising a solvent.

13. The method of claim 1, wherein the blending is accomplished in a melt.

14. The method of claim 1, wherein the composition is used as a masterbatch.

15. The method of claim 1, wherein the blending involves the use of shear force, extensional force, compressive force, ultrasonic energy, electromagnetic energy, thermal energy or combinations comprising at least one of the foregoing forces and energies and is conducted in processing equipment wherein the aforementioned forces or energies are exerted by a single screw, multiple screws, intermeshing co-rotating or counter rotating screws, non-intermeshing co-rotating or counter rotating screws, reciprocating screws, screws with pins, barrels with pins, screen packs, rolls, rams, helical rotors, baffles, ultrasonicator or combinations comprising at least one of the foregoing.

16. The method of claim 1, wherein the blending is conducted in a kettle, while the polymerization is conducted in a device having a single screw, multiple screws, intermeshing co-rotating or counter rotating screws, non-intermeshing co-rotating or counter rotating screws, reciprocating screws, screws with pins, screws with screens, barrels with pins, rolls, rams, helical rotors, baffles, or a combination comprising at least one of the foregoing.

17. An article manufactured by the method of claim 1.

18. A method for manufacturing a conductive composition comprising:

blending a polymer precursor with a single wall carbon nanotube composition, the single wall nanotube composition comprising carbon nanotubes that have a single wall; and

polymerizing the polymer precursor to form an organic polymer;

wherein the composition has an electrical bulk volume resistivity less than or equal to about 10¹² ohm-cm, and a notched Izod impact strength greater than or equal to about 5 kilojoules/square meter, and wherein the composition has a Class A surface finish.

19. The method of claim 18, wherein the single wall carbon nanotube composition comprises about 30 to about 99 wt % metallic carbon nanotubes.

20. The method of claim 18, wherein the single wall carbon nanotube composition comprises about 50 to about 99 wt % metallic carbon nanotubes.

21. The method of claim 18, wherein the single wall carbon nanotube composition comprises about 30 to about 99 wt % semi-conducting carbon nanotubes.

22. The method of claim 18, wherein the single wall carbon nanotube composition comprises about 50 to about 99 wt % semi-conducting carbon nanotubes.

23. The method of claim 18, wherein the blending is conducted at a shear rate of less than or equal to about 100 seconds₋

1.

24. The method of claim 18, wherein the blending is conducted at a shear rate of less than or equal to about 10 seconds₋

1.

25. The method of claim 18, further comprising leaving the conductive composition in an unperturbed state for up to 24 hours after blending.

26. The method of claim 18, further comprising leaving the conductive composition in an unperturbed state for up to 24 hours after polymerizing the polymer precursor.

27. The method of claim 18, further comprising annealing the conductive composition after polymerizing the polymer precursor.

28. The method of claim 18, further comprising annealing the conductive composition at a temperature above the glass transition temperature of the organic polymer.

29. An article manufactured by the method of claim 18.