Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
First Claim
Patent Images
1. A composition suitable for use in elastic films and laminates comprising at least one ethylene/α
- -olefin interpolymer, wherein the ethylene/α
-olefin interpolymer;
(a) has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship;
Tm>
−
2002.9+4538.5(d)−
2422.2(d)2;
or(b) has a Mw/Mn from about 1.7 to about 3.5, and is characterized by a heat of fusion, Δ
H in J/g, and a delta quantity, Δ
T, in degrees Celsius defined as the temperature difference between the tallest DSC peak and the tallest CRYSTAF peak, wherein the numerical values of Δ
T and Δ
H have the following relationships;
Δ
T>
−
0.1299(Δ
H)+62.81 for Δ
H greater than zero and up to 130 J/g,
Δ
T≧
48°
C. for Δ
H greater than 130 J/g,wherein the CRYSTAF peak is determined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30°
C.;
or(c) is characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/α
-olefin interpolymer, and has a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when ethylene/α
-olefin interpolymer is substantially free of a cross-linked phase;
Re>
1481−
1629(d);
or(d) has a molecular fraction which elutes between 40°
C. and 130°
C. when fractionated using TREF, characterized in that the fraction has a molar comonomer content of at least 5 percent higher than that of a comparable random ethylene interpolymer fraction eluting between the same temperatures, wherein said comparable random ethylene interpolymer has the same comonomer(s) and has a melt index, density, and molar comonomer content (based on the whole polymer) within 10 percent of that of the ethylene/α
-olefin interpolymer;
or(e) has a storage modulus at 25°
C., G′
(25°
C.), and a storage modulus at 100°
C., G′
(100°
C.), wherein the ratio of G′
(25°
C.) to G′
(100°
C.) is in the range of about 1;
1 to about 9;
1;
wherein the ethylene/α
-olefin interpolymer has a density of from about 0.85 to about 0.89 g/cc and a melt index (I2) of from about 0.5 g/10 min. to about 20 g/10 min and wherein the ethylene/α
-olefin interpolymer is made using a shuttling agent.
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Abstract
This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention preferably comprise an elastomeric polyolefin resin and a high pressure low density type resin.
226 Citations
26 Claims
-
1. A composition suitable for use in elastic films and laminates comprising at least one ethylene/α
- -olefin interpolymer, wherein the ethylene/α
-olefin interpolymer;(a) has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship;
Tm>
−
2002.9+4538.5(d)−
2422.2(d)2;
or(b) has a Mw/Mn from about 1.7 to about 3.5, and is characterized by a heat of fusion, Δ
H in J/g, and a delta quantity, Δ
T, in degrees Celsius defined as the temperature difference between the tallest DSC peak and the tallest CRYSTAF peak, wherein the numerical values of Δ
T and Δ
H have the following relationships;
Δ
T>
−
0.1299(Δ
H)+62.81 for Δ
H greater than zero and up to 130 J/g,
Δ
T≧
48°
C. for Δ
H greater than 130 J/g,wherein the CRYSTAF peak is determined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30°
C.;
or(c) is characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/α
-olefin interpolymer, and has a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when ethylene/α
-olefin interpolymer is substantially free of a cross-linked phase;
Re>
1481−
1629(d);
or(d) has a molecular fraction which elutes between 40°
C. and 130°
C. when fractionated using TREF, characterized in that the fraction has a molar comonomer content of at least 5 percent higher than that of a comparable random ethylene interpolymer fraction eluting between the same temperatures, wherein said comparable random ethylene interpolymer has the same comonomer(s) and has a melt index, density, and molar comonomer content (based on the whole polymer) within 10 percent of that of the ethylene/α
-olefin interpolymer;
or(e) has a storage modulus at 25°
C., G′
(25°
C.), and a storage modulus at 100°
C., G′
(100°
C.), wherein the ratio of G′
(25°
C.) to G′
(100°
C.) is in the range of about 1;
1 to about 9;
1;wherein the ethylene/α
-olefin interpolymer has a density of from about 0.85 to about 0.89 g/cc and a melt index (I2) of from about 0.5 g/10 min. to about 20 g/10 min and wherein the ethylene/α
-olefin interpolymer is made using a shuttling agent.- View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 12, 13, 16, 17, 18, 19, 20, 21, 26)
- -olefin interpolymer, wherein the ethylene/α
-
11. An elastic film layer comprising at least one ethylene/α
- -olefin interpolymer, wherein the ethylene/α
-olefin interpolymer;(a) has a Mw/Mn from about 1.7 to about 3.5, at least one melting point, Tm, in degrees Celsius, and a density, d, in grams/cubic centimeter, wherein the numerical values of Tm and d correspond to the relationship;
Tm>
−
2002.9+4538.5(d)−
2422.2(d)2;
or(b) has a Mw/Mn from about 1.7 to about 3.5, and is characterized by a heat of fusion, Δ
H in J/g, and a delta quantity, Δ
T, in degrees Celsius defined as the temperature difference between the tallest DSC peak and the tallest CRYSTAF peak, wherein the numerical values of Δ
T and Δ
H have the following relationships;
Δ
T>
−
0.1299(Δ
H)+62.81 for Δ
H greater than zero and up to 130 J/g,
Δ
T≧
48°
C. for Δ
H greater than 130 J/g,wherein the CRYSTAF peak is determined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30°
C.;
or(c) is characterized by an elastic recovery, Re, in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/α
-olefin interpolymer, and has a density, d, in grams/cubic centimeter, wherein the numerical values of Re and d satisfy the following relationship when ethylene/α
-olefin interpolymer is substantially free of a cross-linked phase;
Re>
1481−
1629(d);
or(d) has a molecular fraction which elutes between 40°
C. and 130°
C. when fractionated using TREF, characterized in that the fraction has a molar comonomer content of at least 5 percent higher than that of a comparable random ethylene interpolymer fraction eluting between the same temperatures, wherein said comparable random ethylene interpolymer has the same comonomer(s) and has a melt index, density, and molar comonomer content (based on the whole polymer) within 10 percent of that of the ethylene/α
-olefin interpolymer;
or(e) has a storage modulus at 25°
C., G′
(25°
C.), and a storage modulus at 100°
C., G′
(100°
C.), wherein the ratio of G′
(25°
C.) to G′
(100°
C.) is in the range of about 1;
1 to about 9;
1;wherein the ethylene/α
-olefin interpolymer has a density of from about 0.85 to about 0.89 g/cc and a melt index (I2) of from about 0.5 g/10 min. to about 20 g/10 min. and wherein the ethylene/α
-olefin interpolymer is made using a shuttling agent, and wherein a compression molded film layer is capable of stress relaxation of at most about 60% at 75% strain at 100°
F. for at least 10 hours.- View Dependent Claims (14, 15)
- -olefin interpolymer, wherein the ethylene/α
-
22. A composition suitable for use in elastic films and laminates comprising at least one ethylene/α
- -olefin interpolymer, wherein the ethylene/α
-olefin interpolymer;(a) has a molecular fraction which elutes between 40°
C. and 130°
C. when fractionated using TREF, characterized in that the fraction has a block index of at least 0.5 and up to about 1 and a molecular weight distribution, Mw/Mn, greater than about 1.3;
or(b) has an average block index greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3; wherein the ethylene/α
-olefin interpolymer has a density of from about 0.85 to about 0.89 g/cc and a melt index (I2) of from about 0.5 g/10 min. to about 20 g/10 min and wherein the ethylene/α
-olefin interpolymer is made using a shuttling agent. - View Dependent Claims (23, 24, 25)
- -olefin interpolymer, wherein the ethylene/α
Specification