Process for producing olefins
First Claim
1. A process for producing olefins comprising:
- (a) providing a vapor product stream from an oxygenate to olefin reaction comprising C2 to C4 olefins, C5+ hydrocarbons, at least one oxygenate and water;
(b) cooling the vapor product stream to remove water therefrom and produce a first vapor effluent stream;
(c) compressing and cooling the first vapor effluent stream to produce a second effluent stream that is at least partially in the vapor state;
(d) washing at least part of the second effluent stream with a liquid alcohol-containing stream to remove at least a portion of at least one oxygenate from the second effluent stream in a wash liquid effluent stream, and produce a wash vapor effluent stream comprising C2 to C4 olefins, the wash liquid effluent stream further comprising C5+ hydrocarbons and alcohol contained in the liquid alcohol-containing stream;
(e) contacting at least a portion of the wash liquid effluent stream with a liquid water-containing stream in a liquid-liquid contacting device to at least partially separate said wash liquid effluent stream, or portion thereof, into an aqueous phase rich in said at least one oxygenate and alcohol from the liquid alcohol-containing stream, and an organic phase rich in said C5+ hydrocarbons;
(f) washing the wash vapor effluent stream with a stream containing predominantly water to form a water-washed vapor effluent stream and a water-washed liquid effluent stream;
(g) treating the water-washed vapor effluent stream with a basic component to remove carbon dioxide therefrom, thus forming a CO2-depleted, water-washed vapor effluent stream; and
(h) cooling the CO2-depleted, water-washed vapor effluent stream to a temperature below 90°
F. (32°
C.) and separating the cooled, CO2-depleted, water-washed vapor effluent stream into a partially dried vapor stream containing light olefins and a wet liquid stream.
1 Assignment
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Accused Products
Abstract
A process is described for producing olefins from a vapor product stream from an oxygenate to olefin conversion reaction, the vapor product stream comprising C2 to C4 olefins, C5+ hydrocarbons, at least one oxygenate and water. In the process, the vapor product stream is cooled to remove water therefrom and produce a first vapor effluent stream. The first vapor effluent stream is then cooled and compressed to produce a condensed liquid effluent stream comprising C5+ hydrocarbons and at least one oxygenate, and a residual vapor effluent stream comprising C2 to C4 olefins. At least part of the condensed liquid effluent stream is contacted with a liquid water-containing stream in a liquid-liquid contacting device to at least partly separate said condensed liquid effluent stream, or portion thereof, into an aqueous phase rich in said at least one oxygenate and an organic phase rich in said C5+ hydrocarbons.
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Citations
27 Claims
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1. A process for producing olefins comprising:
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(a) providing a vapor product stream from an oxygenate to olefin reaction comprising C2 to C4 olefins, C5+ hydrocarbons, at least one oxygenate and water; (b) cooling the vapor product stream to remove water therefrom and produce a first vapor effluent stream; (c) compressing and cooling the first vapor effluent stream to produce a second effluent stream that is at least partially in the vapor state; (d) washing at least part of the second effluent stream with a liquid alcohol-containing stream to remove at least a portion of at least one oxygenate from the second effluent stream in a wash liquid effluent stream, and produce a wash vapor effluent stream comprising C2 to C4 olefins, the wash liquid effluent stream further comprising C5+ hydrocarbons and alcohol contained in the liquid alcohol-containing stream; (e) contacting at least a portion of the wash liquid effluent stream with a liquid water-containing stream in a liquid-liquid contacting device to at least partially separate said wash liquid effluent stream, or portion thereof, into an aqueous phase rich in said at least one oxygenate and alcohol from the liquid alcohol-containing stream, and an organic phase rich in said C5+ hydrocarbons; (f) washing the wash vapor effluent stream with a stream containing predominantly water to form a water-washed vapor effluent stream and a water-washed liquid effluent stream; (g) treating the water-washed vapor effluent stream with a basic component to remove carbon dioxide therefrom, thus forming a CO2-depleted, water-washed vapor effluent stream; and (h) cooling the CO2-depleted, water-washed vapor effluent stream to a temperature below 90°
F. (32°
C.) and separating the cooled, CO2-depleted, water-washed vapor effluent stream into a partially dried vapor stream containing light olefins and a wet liquid stream. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12)
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13. A process for producing olefins comprising:
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(a) providing a vapor product stream from an oxygenate to olefin reaction comprising C2 to C4 olefins, C5+ hydrocarbons, at least one oxygenate and water; (b) cooling the vapor product stream to remove water therefrom and produce a first vapor effluent stream; (c) compressing and cooling the first vapor effluent stream to produce a condensed liquid effluent stream comprising C5+ hydrocarbons and at least one oxygenate, and a residual vapor effluent stream comprising C2 to C4 olefins, and; (d) washing at least part of the residual vapor effluent stream with a liquid alcohol-containing stream to produce a wash vapor effluent stream comprising C2 to C4 olefins, and a wash liquid effluent stream comprising said at least one oxygenated hydrocarbon and said C5+ hydrocarbons; (e) contacting at least a portion of the condensed liquid effluent stream produced in (c) and at least a portion of the wash liquid effluent stream produced in (d) with a liquid water-containing stream in a liquid-liquid contacting device to at least partially separate said condensed liquid effluent stream produced in (c) and the wash liquid effluent stream produced in (d), or portions thereof, into an aqueous phase rich in said at least one oxygenate and alcohol contained in the liquid alcohol containing stream, and an organic phase rich in said C5+ hydrocarbons; (f) washing the wash vapor effluent stream with a stream containing predominantly water to form a water-washed vapor effluent stream and a water-washed liquid effluent stream; (g) treating the water-washed vapor effluent stream with a basic component to remove carbon dioxide therefrom, thus forming a CO2-depleted, water-washed vapor effluent stream; and (h) cooling the CO2-depleted, water-washed vapor effluent stream to a temperature below 90°
F. (32°
C.) and separating the cooled, CO2-depleted, water-washed vapor effluent stream into a partially dried vapor stream containing light olefins and a wet liquid stream. - View Dependent Claims (14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27)
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Specification