Optical fiber with quantum dots

• US 7,362,938 B1
• Filed: 08/31/2006
• Issued: 04/22/2008
• Est. Priority Date: 06/09/2003
• Status: Expired due to Fees

• Current Assignee: Virginia Tech Intellectual Properties, Inc.
• Original Assignee: Lambda Instruments Company, Virginia Tech Intellectual Properties, Inc.
• Inventors: Herz, Erik, Paye, Corey, Holton, Carvel, Meissner, Kenith
• Primary Examiner(s): PAK, SUNG H
• Application Number:
  US11/469,043
• Publication Number:
  US 20080085086A1
• Time in Patent Office: 600 Days
• Field of Search: None
• US Class Current: 385/123
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: C03C 13/046 Multicomponent glass compositions
• CPC Class Codes: C03C 14/004 the non-glass component being in the form of particles or flakes
• CPC Class Codes: C03C 14/006 the non-glass component being in the form of microcrystallites, e.g. of optically or electrically active material
• CPC Class Codes: C03C 3/097 containing phosphorus, niobium or tantalum
• CPC Class Codes: C03C 3/102 containing lead
• CPC Class Codes: C03C 3/321 Chalcogenide glasses, e.g. containing S, Se, Te
• CPC Class Codes: C03C 4/0071 for laserable glass
• CPC Class Codes: C03C 4/12 for luminescent glass; for fluorescent glass
• CPC Class Codes: G02B 2006/0325 Fluid core or cladding
• CPC Class Codes: G02B 6/0229 characterised by nanostructures, i.e. structures of size less than 100 nm, e.g. quantum dots
• CPC Class Codes: G02B 6/02347 Longitudinal structures arranged to form a regular periodic lattice, e.g. triangular, square, honeycomb unit cell repeated throughout cladding
• CPC Class Codes: G02B 6/02357 Property of longitudinal structures or background material varies radially and/or azimuthally in the cladding, e.g. size, spacing, periodicity, shape, refractive index, graded index, quasiperiodic, quasicrystals
• CPC Class Codes: G02B 6/02366 Single ring of structures, e.g. "air clad"
• CPC Class Codes: G02B 6/02371 Cross section of longitudinal structures is non-circular
• CPC Class Codes: G02B 6/02385 Comprising liquid, e.g. fluid filled holes
• CPC Class Codes: G02B 6/032 with non solid core or cladding G02B6/02295 takes precedence
• CPC Class Codes: G02B 6/1225 comprising photonic band-gap structures or photonic lattices
• CPC Class Codes: H01S 3/06708 Constructional details of the fibre, e.g. compositions, cross-section, shape or tapering optical fibres as passive waveguides G02B6/02
• CPC Class Codes: H01S 3/06741 Photonic crystal fibre, i.e. the fibre having a photonic bandgap
• CPC Class Codes: H01S 3/169 : Nanoparticles, e.g. doped nanoparticles acting as a gain material

Abstract

Holey optical fibers (e.g. photonic fibers, random-hole fibers) are fabricated with quantum dots disposed in the holes. The quantum dots can provide light amplification and sensing functions, for example. When used for sensing, the dots will experience altered optical properties (e.g. altered fluorescence or absorption wavelength) in response to certain chemicals, biological elements, radiation, high energy particles, electrical or magnetic fields, or thermal/mechanical deformations. Since the dots are disposed in the holes, the dots interact with the evanescent field of core-confined light. Quantum dots can be damaged by high heat, and so typically cannot be embedded within conventional silica optical fibers. In the present invention, dots can be carried into the holes by a solvent at room temperature. The present invention also includes solid glass fibers made of low melting point materials (e.g. phosphate glass, lead oxide glass) with embedded quantum dots.

Claims

1. An optical fiber made of a glass having a drawing temperature less than 700 Celsius, and comprising quantum dots embedded within the glass, and wherein said glass in which said quantum dots are embedded comprises at least 35% by weight lead oxide.

2. The optical fiber of claim 1 wherein the quantum dots are made of a material selected from the group consisting of tellurides and antimonides.

3. The optical fiber of claim 1 wherein the fiber comprises a core and a cladding, and wherein the quantum dots are disposed in the core.

4. The optical fiber of claim 1 wherein the fiber comprises a core and a cladding, and wherein the quantum dots are disposed in the cladding.