Radiation stable aromatic carbonate polymer compositions

• US 7,374,718 B2
• Filed: 10/06/2005
• Issued: 05/20/2008
• Est. Priority Date: 10/06/2005
• Status: Expired due to Fees

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Glasgow, Katherine C., Dhara, Dibakar, Kumar, Vikram
• Primary Examiner(s): Buttner; David J.
• Application Number:
  US11/244,600
• Publication Number:
  US 20070081918A1
• Time in Patent Office: 957 Days
• Field of Search: None
• US Class Current: 422/22
• CPC Class Codes: C08K 5/005 Stabilisers against oxidation, heat, light, ozone
• CPC Class Codes: C08K 5/05 Alcohols; Metal alcoholates
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates

Abstract

A composition comprising an aromatic carbonate polymer and an amount of at least one solid cyclic aliphatic alcohol stabilizing compound sufficient to inhibit yellowing of the composition upon exposure to a sterilizing radiation, wherein said stabilizing compound is selected from the group consisting of 2,2,4,4-tetramethylcyclobutane-1,3-diol, 1,4-cyclohexanediol, and wherein said stabilizing compound is present in said composition in an amount of at least about 0.2 parts by weight per 100 parts by weight of said aromatic carbonate polymers.

Claims

1. An aromatic carbonate polymer composition, comprising:

an aromatic carbonate polymer; and

a solid phase cyclic aliphatic alcohol compound in an amount effective to inhibit color formation upon exposure to sterilizing radiation, wherein said solid phase cyclic aliphatic alcohol compound is 2,2,4,4-tetramethylcyclobutane-1,3-diol, wherein the solid phase cyclic aliphatic alcohol compound is in an amount of at least 0.1 parts by weight per 100 parts by weight of said aromatic carbonate polymer.

2. The aromatic carbonate polymer composition of claim 1, wherein the solid phase cyclic aliphatic alcohol compound is in an amount of at least 0.1 parts to 0.4 parts by weight per 100 parts by weight of said aromatic carbonate polymer.

3. The aromatic carbonate polymer composition of claim 1, further comprising at least one linear aliphatic diol selected from the group consisting of ethylene glycol, propylene glycol, 1,3-propane diol, 1,2-butanediol, 1,4-butanediol, meso-2,3-butanediol, 1,2-pentanediol, 2,3-pentane diol, 1,4-pentane diol, 1,4-hexanediol and 2-methyl-2,4-pentanediol.

4. The aromatic carbonate polymer composition of claim 1, wherein said aromatic carbonate resin is an aromatic polycarbonate resin.

5. The aromatic carbonate polymer composition of claim 1, wherein said aromatic carbonate resin is an aromatic copolyester-carbonate resin.

6. The aromatic carbonate polymer composition of claim 1, further comprising at least one of a colorant, a filler, a fire retardant, a UV stabilizer, an antistatic agent, an acid scavenger, or a visual effects enhancer.

7. An article comprising the aromatic carbonate polymer composition of claim 1.

8. A method of color stabilizing an aromatic carbonate polymer composition, the method comprising:

mixing an aromatic carbonate polymer and a solid phase cyclic aliphatic alcohol compound to form a homogeneous mixture, wherein the solid phase cyclic aliphatic alcohol compound is 2,2,4,4-tetramethylcyclobutane-1,3-diol, wherein the solid phase cyclic aliphatic alcohol compound is in an amount of at least 0.1 parts by weight per 100 parts by weight of said aromatic carbonate polymer;

molding the composition into an article; and

exposing the article to radiation in an amount effective to sterilize the article and produce a sterilized article.

9. The method of claim 8, wherein the sterilized article has a yellowness index as measured in accordance with ASTM E 313-00 less than the yellowness index that would be obtained by similarly treating an article comprising the aromatic carbonate polymer without the solid phase cyclic aliphatic alcohol compound.

10. The method of claim 8, wherein the solid phase cyclic aliphatic alcohol compound is in an amount of at least about 0.1 parts by weight per 100 parts by weight of said aromatic carbonate polymers.

11. The method of claim 8, further comprising adding at least one of a colorant, a filler, a fire retardant, a UV stabilizer, an antistatic agent, an acid scavenger, a visual effects enhancer during the mixing of the aromatic carbonate polymer and the solid phase cyclic aliphatic alcohol compound.

12. The method of claim 8, wherein exposing the article to radiation comprises 25 kGy to 75 kGy of gamma radiation.