Apparatus and method for measuring steam quality

• US 7,381,954 B2
• Filed: 09/29/2005
• Issued: 06/03/2008
• Est. Priority Date: 09/29/2005
• Status: Active Grant

• Current Assignee: GE Infrastructure Technology, LLC (General Electric Company)
• Original Assignee: General Electric Company
• Inventors: Mitra, Chayan, Woodmansee, Mark A., Banerjee, Ayan
• Primary Examiner(s): Sung; Christine
• Application Number:
  US11/162,967
• Publication Number:
  US 20070069131A1
• Time in Patent Office: 978 Days
• Field of Search: 250/339.1
• US Class Current: 250/339.1
• CPC Class Codes: G01N 2021/158 Eliminating condensation
• CPC Class Codes: G01N 2021/354 Hygrometry of gases
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 21/3554 for determining moisture content
• CPC Class Codes: G01N 21/39 using tunable lasers

Abstract

Determination of steam quality by passing one or more laser beams through steam in a steam chamber and directly determining a total number of vapor molecules and a total number of water molecules based on absorption of radiation in the one or more laser beams by the water vapor phase and the liquid water phase in the steam. Specific volumes of water vapor phase and liquid water phase in the steam using the total numbers of water vapor and liquid water molecules are determined and the quality of the steam is calculated based on the specific volumes of the water vapor phase and the liquid water phase in steam. One embodiment comprises a narrow linewidth laser for measuring steam quality and another embodiment comprises multiple broadband lasers for measuring steam quality.

Claims

1. Method for determining steam quality comprising the steps of:

frequency-scanning a laser beam emitted from a narrow linewidth laser along a path through steam in a steam chamber to excite a molecular transition in the steam, the steam having a water vapor phase and a liquid water phase;

determining a total number of water vapor molecules in the path of the laser beam based on a normalized peak absorption amplitude of the water vapor phase as the laser beam passes through the steam;

determining a total number of liquid water molecules in the laser beam path based on a shift in dc level of a peak absorption amplitude of the water vapor phase from a dc level of a reference peak absorption amplitude;

determining specific volumes of the water vapor phase and the liquid water phase in the steam using the total numbers of water vapor and liquid water molecules; and

calculating quality of the steam based on the specific volumes of water vapor phase and liquid water phase in the steam.

2. Method as in claim 1 wherein the narrow linewidth laser is coupled with optic fibers for laser beam transmission and conditioning.

3. Method for determining steam quality comprising the steps of:

frequency-scanning a laser beam emitted from a narrow linewidth laser along a path through steam in a steam chamber to excite a molecular transition in the steam, the steam having a water vapor phase and a liquid water phase;

measuring peak absorption amplitude of the water vapor phase as the laser beam passes through the steam;

normalizing the peak absorption amplitude of the water vapor phase using a reference peak absorption amplitude to determine a normalized peak absorption amplitude;

determining a total number of water vapor molecules in the path of the laser beam based on the normalized peak absorption amplitude;

determining a dc level of the peak absorption amplitude of the water vapor phase;

determining a dc level of the reference peak absorption amplitude;

normalizing the dc level of the peak absorption amplitude of the water vapor phase with the de level of the reference peak absorption amplitude to determine a shift in the dc level of the peak absorption amplitude of the water vapor phase from the dc level of the reference peak absorption amplitude;

determining a total number of water molecules in the laser beam path based on the shift in the de level of the peak absorption amplitude of the water vapor phase using Beer Lambert'"'"'s law;

determining specific volumes of the water vapor phase and liquid water phase in the steam using the total numbers of water vapor and liquid water molecules; and

calculating quality of the steam based on the specific volumes of the water vapor phase and the liquid water phase in the steam.

4. Method as in claim 3 wherein the narrow linewidth laser is a narrow linewidth single mode tunable diode laser.

5. Method as in claim 4 wherein the narrow linewidth single mode tunable diode laser is an external cavity tunable diode laser.

6. Method as in claim 3 wherein the narrow linewidth single mode tunable diode laser has a tuning range wavelength of 1366 to 1440 nm.

7. Method as in claim 3 wherein the laser beam has a linewidth of less than or equal to 0.0075 nm.

8. Method as in claim 3 wherein the laser beam has a linewidth of less than or equal to 0.005 nm.

9. Method as in claim 3 wherein the laser beam has a linewidth of less than or equal to 0.0001 nm.

10. Method as in claim 3 wherein the step of frequency-scanning comprises splitting the laser beam into a first part which passes through the steam and a second part which is diverted along a path through ambient air outside of the chamber and the method further comprises the step of measuring peak absorption amplitude of water vapor in the ambient air as the second pan of the laser beam passes through the ambient air to determine the reference peak absorption amplitude.

11. Method as in claim 3 wherein the step of frequency-scanning comprises frequency-scanning a laser beam at a wavelength of 1383.8 nm to 1384.2 nm.

12. Method as in claim 3 wherein the chamber comprises glass windows for transmission of the laser beam through the steam and the method further comprises heating the glass windows to reduce steam condensation on the windows.

13. Method as in claim 12 wherein the glass windows are high-transmission quartz glass windows.

14. Method as in claim 3 wherein the chamber is part of a steam turbine system.

15. System for determining steam quality comprising:

a chamber for containing steam, the steam having a water vapor phase and a liquid water phase;

a narrow linewidth laser operatively associated with the chamber for frequency-scanning a laser beam along a path through the steam to excite a molecular transition in the steam; and

a device for measuring peak absorption amplitude of the water vapor phase as the laser beam passes through the steam and a shift in de level of a peak absorption amplitude of the water vapor phase from a dc level of a reference peak absorption amplitude.

16. System as in claim 15 wherein the chamber comprises glass windows for transmission of the laser beam through the steam and the system further comprises a heater for heating the glass windows to reduce steam condensation on the windows.

17. System as in claim 16 wherein the glass windows are high-transmission quartz glass windows.

18. System as in claim 15 wherein the narrow linewidth laser is a narrow linewidth single mode unable diode laser.

19. System as in claim 18 wherein the narrow linewidth single mode tunable diode laser is an external cavity tunable diode laser.

20. System as in claim 18 wherein the narrow linewidth single mode tunable diode laser has a tuning range wavelength of 1366 to 1440 nm.

21. System as in claim 15 wherein the narrow linewidth laser is capable of emitting a laser beam having a linewidth of less than or equal to 0.0075 nm.

22. System as in claim 15 wherein the narrow linewidth laser is capable of emitting a laser beam having linewidth of less than or equal to 0.005 nm.

23. System as in claim 15 wherein the narrow linewidth laser is capable of emitting a laser beam having linewidth of less than or equal to 0.0001 nm.

24. System as in claim 15 further comprising a beam splitter for splitting the laser beam into a first pad which passes through the steam and a second part which is diverted along a path through ambient air outside of the chamber and a device for measuring peak absorption amplitude of water vapor in the ambient air as the second part of the laser beam passes through the ambient air.

25. System as in claim 24 wherein the device for measuring peak absorption amplitude of the water vapor phase as the laser beam passes through the steam comprises a first photodetector for measuring the intensity of the laser beam after the laser beam passes through the steam, a device for measuring peak absorption amplitude of water vapor in the ambient air as the second part of the laser beam passes through the ambient air for measuring the intensity of the laser beam after the laser beam passes through the ambient air, and an oscilloscope for determining the peak absorption amplitude of the water vapor phase in the steam based on the intensity of first pad of the laser beam and the peak absorption amplitude of water vapor in the second part of the laser beam.

26. System as in claim 15 wherein the narrow linewidth laser is capable of frequency-scanning a laser beam at a wavelength of 1383.8 nm to 1384.2 nm.

27. System as in claim 15 wherein the device for measuring peak absorption amplitude comprises a photodetector for measuring the intensity of the laser beam after the laser beam passes through the steam and an oscilloscope for determining the peak absorption amplitude of the water vapor phase based on the intensity of the laser beam.

28. System as in claim 15 wherein the narrow linewidth laser is coupled with optic fibers for laser beam transmission and conditioning.

29. A steam turbine comprising the steam quality measurement system of claim 15.