Phosphor composition and method for producing the same, and light-emitting device using the same
First Claim
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1. A light-emitting device comprising:
- a phosphor layer having a red phosphor and a green phosphor,the red phosphor being activated by Eu2+ and having an emission peak in a wavelength range from at least 600 nm to less than 660 nm andthe green phosphor being activated only by Eu2+ and having an emission peak in a wavelength range from at least 500 nm to less than 560 nm; and
a blue light-emitting element having an emission peak in a wavelength range from at least 440 nm to less than 500 nm;
the red phosphor and the green phosphor emitting light being excited by luminescence of the blue light-emitting element, andoutput light of the light-emitting device at least containing a light-emitting component of luminescence from the blue light-emitting element and a light-emitting component of luminescence from the red phosphor and the green phosphor,whereinthe red phosphor has a composition formula (M1-xEux)AlSiN3 where M is at least one element selected from the group consisting of Mg, Ca, Sr and Ba, and satisfies 0.005≦
x≦
0.3,the phosphor layer includes substantially no sulfide phosphor, and only the red phosphor includes a nitride phosphor or an oxynitride phosphor, andthe green phosphor is represented by a composition formula (Ba,Sr)2SiO4;
Eu2+ and its internal quantum efficiency is at least 85% in a wavelength range from at least 440 nm to less than 500 nm.
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Abstract
A light-emitting device is produced using a phosphor composition containing a phosphor host having as a main component a composition represented by a composition formula: aM3N2.bAlN.cSi3N4, where “M” is at least one element selected from the group consisting of Mg, Ca, Sr, Ba, and Zn, and “a”, “b”, and “c” are numerical values satisfying 0.2≦a/(a+b)≦0.95, 0.05≦b/(b+c)≦0.8, and 0.4≦c/(c+a)≦0.95. This enables a light-emitting device emitting white light and satisfying both a high color rendering property and a high luminous flux to be provided.
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1 Claim
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1. A light-emitting device comprising:
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a phosphor layer having a red phosphor and a green phosphor, the red phosphor being activated by Eu2+ and having an emission peak in a wavelength range from at least 600 nm to less than 660 nm and the green phosphor being activated only by Eu2+ and having an emission peak in a wavelength range from at least 500 nm to less than 560 nm; and a blue light-emitting element having an emission peak in a wavelength range from at least 440 nm to less than 500 nm; the red phosphor and the green phosphor emitting light being excited by luminescence of the blue light-emitting element, and output light of the light-emitting device at least containing a light-emitting component of luminescence from the blue light-emitting element and a light-emitting component of luminescence from the red phosphor and the green phosphor, wherein the red phosphor has a composition formula (M1-xEux)AlSiN3 where M is at least one element selected from the group consisting of Mg, Ca, Sr and Ba, and satisfies 0.005≦
x≦
0.3,the phosphor layer includes substantially no sulfide phosphor, and only the red phosphor includes a nitride phosphor or an oxynitride phosphor, and the green phosphor is represented by a composition formula (Ba,Sr)2SiO4;
Eu2+ and its internal quantum efficiency is at least 85% in a wavelength range from at least 440 nm to less than 500 nm.
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Specification