Apparatus, system, and method for generating hydrogen

• US 7,393,369 B2
• Filed: 06/11/2003
• Issued: 07/01/2008
• Est. Priority Date: 06/11/2002
• Status: Expired due to Fees

• Current Assignee: Molly Alonso
• Original Assignee: Trulife Incorporated (Trulife)
• Inventors: Shurtleff, James Kevin
• Primary Examiner(s): BHAT, NINA NMN
• Application Number:
  US10/459,991
• Publication Number:
  US 20030228252A1
• Time in Patent Office: 1,847 Days
• Field of Search: 422/239, 48/61, 482/04, 429/17, 429/19
• US Class Current: 48/61
• CPC Class Codes: B01J 19/2475 Membrane reactors
• CPC Class Codes: B01J 19/2485 Monolithic reactors
• CPC Class Codes: B01J 2219/00164 controlling the flow
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

An apparatus, system, and method generate hydrogen through a controlled chemical reaction between water and a chemical hydride. The invention includes a chemical hydride isolated from water by a water-selective membrane. A fluid containing water is brought into contact with the water-selective membrane. The water diffuses through the water-selective membrane and reacts with the chemical hydride. The water diffuses through the membrane at a predetermined rate based on a water concentration gradient across the water-selective membrane. The water-selective membrane is substantially impermeable to elements and molecules other than water. Hydrogen generated within the chemical hydride is collected and used in various applications.

Claims

1. A hydrogen generator, comprising:

a chemical hydride disposed within a nonporous water-selective membrane;

an outlet port connected to the nonporous water-selective membrane and configured to allow hydrogen to exit the nonporous water-selective membrane; and

wherein the nonporous water-selective membrane selectively diffuses water from a fluid to the chemical hydride, the fluid comprising a gas that includes water in a gas state, and

wherein a rate of diffusion of the water through the water-selective membrane is determined by a water concentration gradient across the water-selective membrane.

2. The hydrogen generator of claim 1, wherein the nonporous water-selective membrane is substantially impermeable to hydrogen, nitrogen, oxygen, and metallic oxides.

3. The hydrogen generator of claim 1, wherein the outlet port comprises a filter configured to retain chemical hydride within the nonporous water-selective membrane.

4. The hydrogen generator of claim 1, wherein the outlet port comprises a check valve configured to prevent fluid from flowing into the nonporous water-selective membrane.

5. The hydrogen generator of claim 1, further comprising a collection conduit connected to the outlet port configured to transport hydrogen from the outlet port.

6. The hydrogen generator of claim 1, wherein the nonporous water-selective membrane is formed of a unitary polymer-based material.

7. The hydrogen generator of claim 1, wherein the nonporous water-selective membrane is formed of Nafion.

8. A hydrogen generator, comprising:

a chemical hydride disposed within a housing;

a check valve connected to the housing and configured to allow hydrogen to exit the housing;

a water-selective membrane configured to separate a fluid comprising water from the chemical hydride, the water-selective membrane selectively diffusing water from the fluid into the chemical hydride to react with the chemical hydride, the fluid comprising a gas that includes water in a gas state;

wherein a rate of diffusion of the water through the water-selective membrane is determined by a water concentration gradient across the water-selective membrane; and

passages formed in the housing that extend longitudinally from one end of the housing to the other, the passages configured to receive an input stream of fluid and having support tubes that support the water-selective membrane.

9. The hydrogen generator of claim 8, wherein the water-selective membrane is tubular and the support tubes are perforated and connected to the water-selective membrane.

10. The hydrogen generator of claim 8, further comprising a filter connected to the check valve to retain chemical hydride within the housing.

11. The hydrogen generator of claim 8, wherein the water-selective membrane is tubular with a cross-section diameter of at least 0.025 inches.

12. The hydrogen generator of claim 8, further comprising a collection conduit connected to the check valve configured to transport hydrogen inside the housing to the check valve.

13. The hydrogen generator of claim 8, wherein a PEM fuel cell is connected to said hydrogen generator and said fluid comprising water originates from a gas mixture by-product of said PEM fuel cell.

14. The hydrogen generator of claim 8, wherein the water-selective membrane is formed of a unitary nonporous polymer-based material.

15. The hydrogen generator of claim 8, wherein the water-selective membrane is formed of Nafion.